|
Nuclear Resonance Vibrational Spectroscopy
Nuclear resonance vibrational spectroscopy is a synchrotron-based technique that probes vibrational energy levels. The technique, often called NRVS, is specific for samples that contain nuclei that respond to Mössbauer spectroscopy, most commonly iron. The method exploits the high resolution offered by synchrotron light sources, which enables the resolution of vibrational fine structure, especially those vibrations that are coupled to the position of the Fe centre(s). The method is popularly applied to problems in bioinorganic chemistry, materials science, and geophysics Geophysics () is a subject of natural science concerned with the physical processes and physical properties of the Earth and its surrounding space environment, and the use of quantitative methods for their analysis. The term ''geophysics'' som .... A novel aspect of the method is the ability to determine the 3D-trajectory of iron atoms within vibrational modes, providing a unique appraisal of DFT-predicti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Synchrotron
A synchrotron is a particular type of cyclic particle accelerator, descended from the cyclotron, in which the accelerating particle beam travels around a fixed closed-loop path. The magnetic field which bends the particle beam into its closed path increases with time during the accelerating process, being ''synchronized'' to the increasing kinetic energy of the particles. The synchrotron is one of the first accelerator concepts to enable the construction of large-scale facilities, since bending, beam focusing and acceleration can be separated into different components. The most powerful modern particle accelerators use versions of the synchrotron design. The largest synchrotron-type accelerator, also the largest particle accelerator in the world, is the Large Hadron Collider (LHC) near Geneva, Switzerland, built in 2008 by the European Organization for Nuclear Research (CERN). It can accelerate beams of protons to an energy of 6.5 tera electronvolts (TeV or 1012 eV). Th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Vibration
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 1013 Hz to approximately 1014 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm−1 and wavelengths of approximately 30 to 3 µm. For a diatomic molecule A−B, the vibrational frequency in s−1 is given by \nu = \frac \sqrt , where k is the force constant in dyne/cm or erg/cm2 and μ is the reduced mass given by \frac = \frac+\frac. The vibrational wavenumber in cm−1 is \tilde \;= \frac \sqrt, where c is the speed of light in cm/s. Vibrations of polyatomic molecules are described in terms of normal modes, which are independent of each other, but each normal mode involves simultaneous vibrations of different parts of the molecule. In general, a non-linear molecule with ''N'' atoms has 3''N'' – 6 normal modes of vibration, but a ''linear'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mössbauer Spectroscopy
Mössbauer spectroscopy is a spectroscopic technique based on the Mössbauer effect. This effect, discovered by Rudolf Mössbauer (sometimes written "Moessbauer", German: "Mößbauer") in 1958, consists of the nearly recoil-free emission and absorption of nuclear gamma rays in solids. The consequent nuclear spectroscopy method is exquisitely sensitive to small changes in the chemical environment of certain nuclei. Typically, three types of nuclear interactions may be observed: the isomer shift due to differences in nearby electron densities (also called the chemical shift in older literature), quadrupole splitting due to atomic-scale electric field gradients; and magnetic Zeeman splitting due to non-nuclear magnetic fields. Due to the high energy and extremely narrow line widths of nuclear gamma rays, Mössbauer spectroscopy is a highly sensitive technique in terms of energy (and hence frequency) resolution, capable of detecting changes of just a few parts in 1011. It is a me ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bioinorganic Chemistry
Bioinorganic chemistry is a field that examines the role of metals in biology. Bioinorganic chemistry includes the study of both natural phenomena such as the behavior of metalloproteins as well as artificially introduced metals, including those that are non-essential, in medicine and toxicology. Many biological processes such as respiration depend upon molecules that fall within the realm of inorganic chemistry. The discipline also includes the study of inorganic models or mimics that imitate the behaviour of metalloproteins. As a mix of biochemistry and inorganic chemistry, bioinorganic chemistry is important in elucidating the implications of electron-transfer proteins, substrate bindings and activation, atom and group transfer chemistry as well as metal properties in biological chemistry. The successful development of truly interdisciplinary work is necessary to advance bioinorganic chemistry. Composition of living organisms About 99% of mammals' mass are the elements carb ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Geophysics
Geophysics () is a subject of natural science concerned with the physical processes and physical properties of the Earth and its surrounding space environment, and the use of quantitative methods for their analysis. The term ''geophysics'' sometimes refers only to solid earth applications: Earth's shape; its gravitational and magnetic fields; its internal structure and composition; its dynamics and their surface expression in plate tectonics, the generation of magmas, volcanism and rock formation. However, modern geophysics organizations and pure scientists use a broader definition that includes the water cycle including snow and ice; fluid dynamics of the oceans and the atmosphere; electricity and magnetism in the ionosphere and magnetosphere and solar-terrestrial physics; and analogous problems associated with the Moon and other planets. Gutenberg, B., 1929, Lehrbuch der Geophysik. Leipzig. Berlin (Gebruder Borntraeger). Runcorn, S.K, (editor-in-chief), 1967, International ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mössbauer Effect
The Mössbauer effect, or recoilless nuclear resonance fluorescence, is a physical phenomenon discovered by Rudolf Mössbauer in 1958. It involves the resonant and recoil-free emission and absorption of gamma radiation by atomic nuclei bound in a solid. Its main application is in Mössbauer spectroscopy. In the Mössbauer effect, a narrow resonance for nuclear gamma emission and absorption results from the momentum of recoil being delivered to a surrounding crystal lattice rather than to the emitting or absorbing nucleus alone. When this occurs, no gamma energy is lost to the kinetic energy of recoiling nuclei at either the emitting or absorbing end of a gamma transition: emission and absorption occur at the same energy, resulting in strong, resonant absorption. History The emission and absorption of X-rays by gases had been observed previously, and it was expected that a similar phenomenon would be found for gamma rays, which are created by nuclear transitions (as opposed to X-r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Avalanche Diode
In electronics, an avalanche diode is a diode (made from silicon or other semiconductor) that is designed to experience avalanche breakdown at a specified reverse bias voltage. The junction of an avalanche diode is designed to prevent current concentration and resulting hot spots, so that the diode is undamaged by the breakdown. The avalanche breakdown is due to minority carriers accelerated enough to create ionization in the crystal lattice, producing more carriers, which in turn create more ionization. Because the avalanche breakdown is uniform across the whole junction, the breakdown voltage is nearly constant with changing current when compared to a non-avalanche diode. The Zener diode exhibits an apparently similar effect in addition to Zener breakdown. Both effects are present in any such diode, but one usually dominates the other. Avalanche diodes are optimized for avalanche effect, so they exhibit small but significant voltage drop under breakdown conditions, unlike Zener ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vibrational Spectroscopy
Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms. It can be used to characterize new materials or identify and verify known and unknown samples. The method or technique of infrared spectroscopy is conducted with an instrument called an infrared spectrometer (or spectrophotometer) which produces an infrared spectrum. An IR spectrum can be visualized in a graph of infrared light absorbance (or transmittance) on the vertical axis vs. frequency, wavenumber or wavelength on the horizontal axis. Typical units of wavenumber used in IR spectra are reciprocal centimeters, with the symbol cm−1. Units of IR wavelength are commonly given in micrometers (formerly called "microns"), symbol μm, which are related to the wavenumber in a reciprocal way. A com ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
