Metalloanthocyanin
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Metalloanthocyanin
A metalloanthocyanin is a chemical complex giving color to petals of certain plants. These complexes are self-assembled, supramolecular metal complex pigment composed of stoichiometric amounts of anthocyanins, flavones, and metal ions. The various colors, such as red, mauve, purple, violet and blue, in ''Hydrangea macrophylla'' are developed from one simple anthocyanin, delphinidin 3-glucoside forming complexes with metal ions. Examples Commelinin, a blue pigment from the flowers of ''Commelina communis'', is a complex of 4 Mg2+ ions chelating six anthocyanin molecules. Cyanosalvianin, a blue pigment from the flowers of '' Salvia uliginosa'', is a complex formed of six molecules of the anthocyanin type, six molecules of the flavone type and two magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals ...
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Hydrangea Macrophylla - Hortensia Hydrangea
''Hydrangea'', () commonly named the hortensia, is a genus of over 75 species of flowering plants native to Asia and the Americas. By far the greatest species diversity is in eastern Asia, notably China, Korea, and Japan. Most are shrubs tall, but some are small trees, and others lianas reaching up to by climbing up trees. They can be either deciduous or evergreen, though the widely cultivated temperate species are all deciduous. ''Hydrangea'' is derived from Greek and means ‘water vessel’ (from ''húdōr'' "water" + ''ángos'' or ''angeîon'' "vessel"), in reference to the shape of its seed capsules. The earlier name, ''Hortensia'', is a Latinised version of the French given name Hortense, honoring French astronomer and mathematician Nicole-Reine Hortense Lepaute. This claim is disputed in page 88 on citation 10 at Nicole-Reine Hortense Lepaute page, which says: "Larousse considers this an injustice, and remarks that it has led many persons to the erroneous notion th ...
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Chemical Complex
A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of chemical bond, bound molecules or ions, that are in turn known as ''ligands'' or complexing agents. Many metal-containing chemical compound, compounds, especially those that include transition metals (elements like titanium that belong to the Block (periodic table), Periodic Table's d-block), are coordination complexes. Nomenclature and terminology Coordination complexes are so pervasive that their structures and reactions are described in many ways, sometimes confusingly. The atom within a ligand that is bonded to the central metal atom or ion is called the donor atom. In a typical complex, a metal ion is bonded to several donor atoms, which can be the same or different. A Ligand#Polydentate and polyhapto ligand motifs and nomenclature, polydentate (multiple bonded) ligand is a molecule or ion that bonds to the central atom ...
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Anthocyanin
Anthocyanins (), also called anthocyans, are water-soluble vacuolar pigments that, depending on their pH, may appear red, purple, blue, or black. In 1835, the German pharmacist Ludwig Clamor Marquart gave the name Anthokyan to a chemical compound that gives flowers a blue color for the first time in his treatise "''Die Farben der Blüthen''". Food plants rich in anthocyanins include the blueberry, raspberry, black rice, and black soybean, among many others that are red, blue, purple, or black. Some of the colors of autumn leaves are derived from anthocyanins. Anthocyanins belong to a parent class of molecules called flavonoids synthesized via the phenylpropanoid pathway. They occur in all tissues of higher plants, including leaves, stems, roots, flowers, and fruits. Anthocyanins are derived from anthocyanidins by adding sugars. They are odorless and moderately astringent. Although approved as food and beverage colorant in the European Union, anthocyanins are not approved ...
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Flavone
Flavone is an organic compound with the formula . A white solid, flavone is a derivative of chromone with a phenyl (Ph) substituent adjacent to the ether group. The compound is of little direct practical importance, but susbstituted derivatives, the flavones and flavonoids are a large class of nutritionally important natural products. Flavone can be prepared in the laboratory by cyclization of 2-hydroxacetophenone. Isomeric with flavone is isoflavone, where the phenyl group is adjacent to the ketone In organic chemistry, a ketone is a functional group with the structure R–C(=O)–R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group –C(=O)– (which contains a carbon-oxygen double bo .... References {{Flavones ...
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Metal Ion
A metal (from ancient Greek, Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. Metals are typically ductile (can be drawn into wires) and malleable (they can be hammered into thin sheets). These properties are the result of the ''metallic bond'' between the atoms or molecules of the metal. A metal may be a chemical element such as iron; an alloy such as stainless steel; or a molecular compound such as polythiazyl, polymeric sulfur nitride. In physics, a metal is generally regarded as any substance capable of conducting electricity at a temperature of absolute zero. Many elements and compounds that are not normally classified as metals become metallic under high pressures. For example, the nonmetal iodine gradually becomes a metal at a pressure of between 40 ...
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Hydrangea Macrophylla
''Hydrangea macrophylla'' is a species of flowering plant in the family Hydrangeaceae, native to Japan. It is a deciduous shrub growing to tall by broad with large heads of pink or blue flowers in summer and autumn. Common names include bigleaf hydrangea, French hydrangea, lacecap hydrangea, mophead hydrangea, penny mac and hortensia. It is widely cultivated in many parts of the world in many climates. It is not to be confused with '' H. aspera'' 'Macrophylla'. Description The term ''macrophylla'' means large- or long-leaved. The opposite leaves can grow to in length. They are simple, membranous, orbicular to elliptic and acuminate. They are generally serrated. The inflorescence of ''Hydrangea macrophylla'' is a corymb, with all flowers placed in a plane or hemisphere, or even a whole sphere in cultivated forms. Two distinct types of flowers can be identified: central, non-ornamental, pentamerous ones, and peripheral, ornamental, tetramerous ones. The latter have sterile ...
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Delphinidin 3-glucoside
Myrtillin is an anthocyanin. It is the 3-glucoside of delphinidin. It can be found in all green plants, most abundantly in blackcurrant, blueberry, huckleberry, bilberry leaves and in various myrtles, roselle plants, and '' Centella asiatica'' plant. It is also present in yeast and oatmeal. The sumac fruit's pericarp owes its dark red colour to anthocyanin pigments, of which chrysanthemin, myrtillin and delphinidin have yet been identified. The various colors, such as red, mauve, purple, violet, and blue in '' Hydrangea macrophylla'' are developed from myrtillin complexes with metal ions called metalloanthocyanins. Metabolism The enzyme anthocyanin 3-O-glucoside 6''-O-hydroxycinnamoyltransferase produces delphinidin 3-(6-p-coumaroyl)glucoside from myrtillin and ''p''-coumaroyl-CoA in the anthocyanin biosynthesis Anthocyanins (), also called anthocyans, are water-soluble vacuolar pigments that, depending on their pH, may appear red, purple, blue, or black. In 1835, the G ...
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Commelina Communis
''Commelina communis'', commonly known as the Asiatic dayflower, is an herbaceous annual plant in the dayflower family. It gets its name because the blooms last for only one day. It is native throughout much of East Asia and northern parts of Southeast Asia. In China, the plant is known as ''yazhicao'' (), roughly translating to "duckfoot herb", while in Japan it is known as , meaning "dew herb". It has also been introduced to parts of central and southeastern Europe and much of eastern North America, where it has spread to become a noxious weed. It is common in disturbed sites and in moist soil. The flowers emerge from summer through fall and are distinctive with two relatively large blue petals and one very small white petal. The Asiatic dayflower plant serves as the type species for its large genus. Linnaeus picked the name ''Commelina'' in honour of the two Dutch botanists of the Commelijn family, using the two large showy petals of ''Commelina communis'' to symbolise them ...
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Magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic table) it occurs naturally only in combination with other elements and it almost always has an oxidation state of +2. It reacts readily with air to form a thin passivation coating of magnesium oxide that inhibits further corrosion of the metal. The free metal burns with a brilliant-white light. The metal is obtained mainly by electrolysis of magnesium salts obtained from brine. It is less dense than aluminium and is used primarily as a component in strong and lightweight alloys that contain aluminium. In the cosmos, magnesium is produced in large, aging stars by the sequential addition of three helium nuclei to a carbon nucleus. When such stars explode as supernovas, much of the magnesium is expelled into the interstellar medium where it ma ...
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Salvia Uliginosa
The plant known as ''Salvia uliginosa'', the bog sage, is a species of flowering plant in the family Lamiaceae, native to southern Brazil, Uruguay, and Argentina. It was described and named by botanist George Bentham for its typical habitat "of swamps and marshes", or ''uliginosa''. Description ''Salvia uliginosa'' is an herbaceous perennial growing up to tall in one season, with multiple thin stems and yellow-green lance-shaped leaves that have serrated edges. The plant quickly spreads on underground runners and is readily divided. The bright azure-blue flowers are long with a white beeline in the throat pointing toward the nectar and pollen. They grow in whorls beginning in summer until fall, with many flowers coming into bloom at the same time. Cyanosalvianin, the blue pigment from the flowers of ''S. uliginosa'', is a metalloanthocyanin, a complex formed of six molecules of the anthocyanin type, six molecules of the flavone type and two magnesium ions. Cultivation ''Sa ...
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