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Maxwell Construction
In thermodynamic equilibrium, a necessary condition for stability is that pressure P does not increase with volume V. This basic consistency requirement—and similar ones for other ''conjugate'' pairs of variables—are sometimes violated in analytic models for first order phase transitions. The most famous case is the Van der Waals equation for real gases, see Fig. 1 where a typical ''isotherm'' is drawn (black curve). The Maxwell construction is a way of correcting this deficiency. The decreasing right hand part of the curve in Fig. 1 describes a diluted gas, while its left part describes a liquid. The intermediate (rising) part of the curve in Fig. 1 would be correct, if these two parts were to be joined smoothly—meaning in particular that the system would remain also in this region spatially uniform with a well defined density. But this is not what happens. If the volume of a vessel containing a fixed amount of liquid is expanded at constant temperature, there comes a point w ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Equilibrium
Thermodynamic equilibrium is an axiomatic concept of thermodynamics. It is an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls. In thermodynamic equilibrium, there are no net macroscopic flows of matter nor of energy within a system or between systems. In a system that is in its own state of internal thermodynamic equilibrium, no macroscopic change occurs. Systems in mutual thermodynamic equilibrium are simultaneously in mutual thermal, mechanical, chemical, and radiative equilibria. Systems can be in one kind of mutual equilibrium, while not in others. In thermodynamic equilibrium, all kinds of equilibrium hold at once and indefinitely, until disturbed by a thermodynamic operation. In a macroscopic equilibrium, perfectly or almost perfectly balanced microscopic exchanges occur; this is the physical explanation of the notion of macroscopic equilibrium. A thermodynamic sys ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Van Der Waals Equation
In chemistry and thermodynamics, the Van der Waals equation (or Van der Waals equation of state) is an equation of state which extends the ideal gas law to include the effects of interaction between molecules of a gas, as well as accounting for the finite size of the molecules. The ideal gas law treats gas molecules as point particles that interact with their containers but not each other, meaning they neither take up space nor change kinetic energy during collisions (i.e. all collisions are perfectly elastic). The ideal gas law states that the volume ''V'' occupied by ''n'' moles of any gas has a pressure ''P'' at temperature ''T'' given by the following relationship, where ''R'' is the gas constant: :PV=nRT To account for the volume occupied by real gas molecules, the Van der Waals equation replaces V/n in the ideal gas law with (V_m-b), where ''Vm'' is the molar volume of the gas and ''b'' is the volume occupied by the molecules of one mole: :P(V_m - b)=R T The second m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
James Clerk Maxwell
James Clerk Maxwell (13 June 1831 – 5 November 1879) was a Scottish mathematician and scientist responsible for the classical theory of electromagnetic radiation, which was the first theory to describe electricity, magnetism and light as different manifestations of the same phenomenon. Maxwell's equations for electromagnetism have been called the " second great unification in physics" where the first one had been realised by Isaac Newton. With the publication of "A Dynamical Theory of the Electromagnetic Field" in 1865, Maxwell demonstrated that electric and magnetic fields travel through space as waves moving at the speed of light. He proposed that light is an undulation in the same medium that is the cause of electric and magnetic phenomena. (This article accompanied an 8 December 1864 presentation by Maxwell to the Royal Society. His statement that "light and magnetism are affections of the same substance" is at page 499.) The unification of light and electrical ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Maxwell II Drawing
Maxwell may refer to: People * Maxwell (surname), including a list of people and fictional characters with the name ** James Clerk Maxwell, mathematician and physicist * Justice Maxwell (other) * Maxwell baronets, in the Baronetage of Nova Scotia * Maxwell (footballer, born 1979), Brazilian forward * Maxwell (footballer, born 1981), Brazilian left-back * Maxwell (footballer, born 1986), Brazilian striker * Maxwell (footballer, born 1989), Brazilian left-back * Maxwell (footballer, born 1995), Brazilian forward * Maxwell (musician) (born 1973), American R&B and neo-soul singer * Maxwell (rapper) (born 1993), German rapper, member of rap band 187 Strassenbande * Maxwell Jacob Friedman (born 1997) AEW Professional wrestler * Maxwell Silva (born 1953), Sri Lankan Sinhala Catholic cleric, Auxiliary Bishop of Colombo Places United States * Maxwell, California * Maxwell, Indiana * Maxwell, Iowa * Maxwell, Nebraska * Maxwell, New Mexico * Maxwell, Texas * Maxwell Air ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cubic Function
In mathematics, a cubic function is a function of the form f(x)=ax^3+bx^2+cx+d where the coefficients , , , and are complex numbers, and the variable takes real values, and a\neq 0. In other words, it is both a polynomial function of degree three, and a real function. In particular, the domain and the codomain are the set of the real numbers. Setting produces a cubic equation of the form :ax^3+bx^2+cx+d=0, whose solutions are called roots of the function. A cubic function has either one or three real roots (which may not be distinct); all odd-degree polynomials have at least one real root. The graph of a cubic function always has a single inflection point. It may have two critical points, a local minimum and a local maximum. Otherwise, a cubic function is monotonic. The graph of a cubic function is symmetric with respect to its inflection point; that is, it is invariant under a rotation of a half turn around this point. Up to an affine transformation, there are only th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pseudo 3D P-v-T Diagram For Van Der Waals Fluid Showing Some Tie Lines And Isotherms
The prefix pseudo- (from Greek ψευδής, ''pseudes'', "false") is used to mark something that superficially appears to be (or behaves like) one thing, but is something else. Subject to context, ''pseudo'' may connote coincidence, imitation, intentional deception, or a combination thereof. * In scholarship and studies, pseudo-scholarship refers to material that is presented as, but is not, the product of rigorous and objective study or research. Examples: **Pseudoarchaeology ** Pseudohistory ** Pseudolinguistics *** Pseudoscientific language comparison *** Folk linguistics ** Pseudomathematics ** Pseudophilosophy ** Pseudonym ** Pseudoscience **Pseudoculture * In biology and botany, the prefix 'pseudo' is used to indicate a species with a coincidental visual similarity to another genus. For example, ''Iris pseudacorus'' is known as '''pseud''acorus' for having leaves similar to those of ''Acorus calamus''. In biology, coincidental similarity is not the same as mimicry. * In l ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Van Der Waals Coexistence Locus Of Liquid-gas Equilibrium
A van is a type of road vehicle used for transporting goods or people. Depending on the type of van, it can be bigger or smaller than a pickup truck and SUV, and bigger than a common car. There is some varying in the scope of the word across the different English-speaking countries. The smallest vans, microvans, are used for transporting either goods or people in tiny quantities. Mini MPVs, compact MPVs, and MPVs are all small vans usually used for transporting people in small quantities. Larger vans with passenger seats are used for institutional purposes, such as transporting students. Larger vans with only front seats are often used for business purposes, to carry goods and equipment. Specially-equipped vans are used by television stations as mobile studios. Postal services and courier companies use large step vans to deliver packages. Word origin and usage Van meaning a type of vehicle arose as a contraction of the word caravan. The earliest records of a van as a vehicle i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
University Of Connecticut
The University of Connecticut (UConn) is a public land-grant research university in Storrs, Connecticut, a village in the town of Mansfield. The primary 4,400-acre (17.8 km2) campus is in Storrs, approximately a half hour's drive from Hartford and 90 minutes from Boston. UConn was founded in 1881 as the Storrs Agricultural School, named after two brothers who donated the land for the school. In 1893, the school became a public land grant college, becoming the University of Connecticut in 1939. Over the following decade, social work, nursing and graduate programs were established, while the schools of law and pharmacy were also absorbed into the university. During the 1960s, UConn Health was established for new medical and dental schools. John Dempsey Hospital opened in Farmington in 1975. The university is classified among "R1: Doctoral Universities – Very high research activity". The university has been considered a Public Ivy. UConn is one of the founding institution ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gibbs Free Energy
In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions. The Gibbs free energy change , measured in joules in SI) is the ''maximum'' amount of non-expansion work that can be extracted from a closed system (one that can exchange heat and work with its surroundings, but not matter) at fixed temperature and pressure. This maximum can be attained only in a completely reversible process. When a system transforms reversibly from an initial state to a final state under these conditions, the decrease in Gibbs free energy equals the work done by the system to its surroundings, minus the work of the pressure forces. The Gibbs energy is the thermodynamic potential that is minim ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Common Tangent Construction
Common may refer to: Places * Common, a townland in County Tyrone, Northern Ireland * Boston Common, a central public park in Boston, Massachusetts * Cambridge Common, common land area in Cambridge, Massachusetts * Clapham Common, originally common land, now a park in London, UK * Common Moss, a townland in County Tyrone, Northern Ireland * Lexington Common, a common land area in Lexington, Massachusetts * Salem Common Historic District, a common land area in Salem, Massachusetts People * Common (rapper) (born 1972), American hip hop artist, actor, and poet * Andrew Ainslie Common (born 1841), English amateur astronomer * Andrew Common (born 1889), British shipping director * John Common, American songwriter, musician and singer * Thomas Common (born 1850), Scottish translator and literary critic Arts, entertainment, and media * ''Common'' (film), a 2014 BBC One film, written by Jimmy McGovern, on the UK's Joint Enterprise Law * Dol Common, a character in ''The Alchemist'' b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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