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Martensite
Martensite is a very hard form of steel crystalline structure. It is named after German metallurgist Adolf Martens. By analogy the term can also refer to any crystal structure that is formed by diffusionless transformation. Properties Martensite is formed in carbon steels by the rapid cooling (quenching) of the austenite form of iron at such a high rate that carbon atoms do not have time to diffuse out of the crystal structure in large enough quantities to form cementite (Fe3C). Austenite is gamma-phase iron (γ-Fe), a solid solution of iron and alloying elements. As a result of the quenching, the face-centered cubic austenite transforms to a highly strained body-centered tetragonal form called martensite that is supersaturated with carbon. The shear deformations that result produce a large number of dislocations, which is a primary strengthening mechanism of steels. The highest hardness of a pearlitic steel is 400  Brinell, whereas martensite can achieve 700 Brinel ...
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Martensite
Martensite is a very hard form of steel crystalline structure. It is named after German metallurgist Adolf Martens. By analogy the term can also refer to any crystal structure that is formed by diffusionless transformation. Properties Martensite is formed in carbon steels by the rapid cooling (quenching) of the austenite form of iron at such a high rate that carbon atoms do not have time to diffuse out of the crystal structure in large enough quantities to form cementite (Fe3C). Austenite is gamma-phase iron (γ-Fe), a solid solution of iron and alloying elements. As a result of the quenching, the face-centered cubic austenite transforms to a highly strained body-centered tetragonal form called martensite that is supersaturated with carbon. The shear deformations that result produce a large number of dislocations, which is a primary strengthening mechanism of steels. The highest hardness of a pearlitic steel is 400  Brinell, whereas martensite can achieve 700 Bri ...
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Pearlite
Pearlite is a two-phased, lamellar (or layered) structure composed of alternating layers of ferrite (87.5 wt%) and cementite (12.5 wt%) that occurs in some steels and cast irons. During slow cooling of an iron-carbon alloy, pearlite forms by a eutectoid reaction as austenite cools below (the eutectoid temperature). Pearlite is a microstructure occurring in many common grades of steels. The eutectoid composition of austenite is approximately 0.8% carbon; steel with less carbon content ( hypoeutectoid steel) will contain a corresponding proportion of relatively pure ferrite crystallites that do not participate in the eutectoid reaction and cannot transform into pearlite. Likewise steels with higher carbon content ( hypereutectoid steels) will form cementite before reaching the eutectoid point. The proportion of ferrite and cementite forming above the eutectoid point can be calculated from the iron/iron—carbide equilibrium phase diagram using the lever rule. Steels with p ...
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Tungsten
Tungsten, or wolfram, is a chemical element with the symbol W and atomic number 74. Tungsten is a rare metal found naturally on Earth almost exclusively as compounds with other elements. It was identified as a new element in 1781 and first isolated as a metal in 1783. Its important ores include scheelite and wolframite, the latter lending the element its alternate name. The free element is remarkable for its robustness, especially the fact that it has the highest melting point of all known elements barring carbon (which sublimes at normal pressure), melting at . It also has the highest boiling point, at . Its density is , comparable with that of uranium and gold, and much higher (about 1.7 times) than that of lead. Polycrystalline tungsten is an intrinsically brittle and hard material (under standard conditions, when uncombined), making it difficult to work. However, pure single-crystalline tungsten is more ductile and can be cut with a hard-steel hacksaw. Tungsten occurs in many ...
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Tempering (metallurgy)
Tempering is a process of heat treating, which is used to increase the toughness of iron-based alloys. Tempering is usually performed after hardening, to reduce some of the excess hardness, and is done by heating the metal to some temperature below the critical point for a certain period of time, then allowing it to cool in still air. The exact temperature determines the amount of hardness removed, and depends on both the specific composition of the alloy and on the desired properties in the finished product. For instance, very hard tools are often tempered at low temperatures, while springs are tempered at much higher temperatures. Introduction Tempering is a heat treatment technique applied to ferrous alloys, such as steel or cast iron, to achieve greater toughness by decreasing the hardness of the alloy. The reduction in hardness is usually accompanied by an increase in ductility, thereby decreasing the brittleness of the metal. Tempering is usually performed after quench ...
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Phase Diagram
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, volume, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium. Overview Common components of a phase diagram are ''lines of equilibrium'' or ''phase boundaries'', which refer to lines that mark conditions under which multiple phases can coexist at equilibrium. Phase transitions occur along lines of equilibrium. Metastable phases are not shown in phase diagrams as, despite their common occurrence, they are not equilibrium phases. Triple points are points on phase diagrams where lines of equilibrium intersect. Triple points mark conditions at which three different phases can coexist. For example, the water phase diagram has a triple point corresponding to the single temperature and pressure at which solid, liquid, and gaseous water can coexist in a stabl ...
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Deformation (physics)
In physics, deformation is the continuum mechanics transformation of a body from a ''reference'' configuration to a ''current'' configuration. A configuration is a set containing the positions of all particles of the body. A deformation can occur because of external loads, intrinsic activity (e.g. muscle contraction), body force In physics, a body force is a force that acts throughout the volume of a body. Springer site - Book 'Solid mechanics'preview paragraph 'Body forces'./ref> Forces due to gravity, electric fields and magnetic fields are examples of body forces. Bo ...s (such as gravity or electromagnetic forces), or changes in temperature, moisture content, or chemical reactions, etc. Strain is related to deformation in terms of ''relative'' displacement of particles in the body that excludes rigid-body motions. Different equivalent choices may be made for the expression of a strain field depending on whether it is defined with respect to the initial or the final ...
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Cryogenics
In physics, cryogenics is the production and behaviour of materials at very low temperatures. The 13th IIR International Congress of Refrigeration (held in Washington DC in 1971) endorsed a universal definition of “cryogenics” and “cryogenic” by accepting a threshold of 120 K (or –153 °C) to distinguish these terms from the conventional refrigeration. This is a logical dividing line, since the normal boiling points of the so-called permanent gases (such as helium, hydrogen, neon, nitrogen, oxygen, and normal air) lie below 120K while the Freon refrigerants, hydrocarbons, and other common refrigerants have boiling points above 120K. The U.S. National Institute of Standards and Technology considers the field of cryogenics as that involving temperatures below -153 Celsius (120K; -243.4 Fahrenheit) Discovery of superconducting materials with critical temperatures significantly above the boiling point of nitrogen has provided new interest in reliable, low cost method ...
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Activation Energy
In chemistry and physics, activation energy is the minimum amount of energy that must be provided for compounds to result in a chemical reaction. The activation energy (''E''a) of a reaction is measured in joules per mole (J/mol), kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol). Activation energy can be thought of as the magnitude of the potential barrier (sometimes called the energy barrier) separating minima of the potential energy surface pertaining to the initial and final thermodynamic state. For a chemical reaction to proceed at a reasonable rate, the temperature of the system should be high enough such that there exists an appreciable number of molecules with translational energy equal to or greater than the activation energy. The term "activation energy" was introduced in 1889 by the Swedish scientist Svante Arrhenius. Other uses Although less commonly used, activation energy also applies to nuclear reactions and various other physical phenomena. Te ...
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TRIP Steel
TRIP steel are a class of high-strength steel alloys typically used in naval and marine applications and in the automotive industry. TRIP stands for "Transformation induced plasticity," which implies a phase transformation in the material, typically when a stress is applied. These alloys are known to possess an outstanding combination of strength and ductility. Microstructure TRIP steels possess a microstructure consisting of austenite with sufficient thermodynamic instability such that transformation to martensite is achieved during loading or deformation. Many automotive TRIP steels possess retained austenite within a ferrite matrix, which may also contain hard phases like bainite and martensite. In the case of these alloys, the high silicon and carbon content of TRIP steels results in significant volume fractions of retained austenite in the final microstructure. TRIP steels use higher quantities of carbon than dual-phase steels to obtain sufficient carbon content for stabilizi ...
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Yttria-stabilized Zirconia
Yttria-stabilized zirconia (YSZ) is a ceramic in which the cubic crystal structure of zirconium dioxide is made stable at room temperature by an addition of yttrium oxide. These oxides are commonly called "zirconia" ( Zr O2) and "yttria" ( Y2 O3), hence the name. Stabilization Pure zirconium dioxide undergoes a phase transformation from monoclinic (stable at room temperature) to tetragonal (at about 1173 °C) and then to cubic (at about 2370 °C), according to the scheme : monoclinic (1173 °C) ↔ tetragonal (2370 °C) ↔ cubic (2690 °C) ↔ melt. Obtaining stable sintered zirconia ceramic products is difficult because of the large volume change, about 5%, accompanying the transition from tetragonal to monoclinic. Stabilization of the cubic polymorph of zirconia over wider range of temperatures is accomplished by substitution of some of the Zr4+ ions (ionic radius of 0.82 Å, too small for ideal lattice of fluorite characteristic for the cubi ...
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Alloy Steel
Alloy steel is steel that is alloyed with a variety of elements in total amounts between 1.0% and 50% by weight to improve its mechanical properties. Alloy steels are broken down into two groups: low alloy steels and high alloy steels. The difference between the two is disputed. Smith and Hashemi define the difference at 4.0%, while Degarmo, ''et al.'', define it at 8.0%.Degarmo, p. 112. Most commonly, the phrase "alloy steel" refers to low-alloy steels. Strictly speaking, every steel is an alloy, but not all steels are called "alloy steels". The simplest steels are iron (Fe) alloyed with carbon (C) (about 0.1% to 1%, depending on type) and nothing else (excepting negligible traces via slight impurities); these are called carbon steels. However, the term "alloy steel" is the standard term referring to steels with ''other'' alloying elements added deliberately ''in addition to'' the carbon. Common alloyants include manganese (the most common one), nickel, chromium, molybdenum, van ...
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Lath
A lath or slat is a thin, narrow strip of straight-grained wood used under roof shingles or tiles, on lath and plaster walls and ceilings to hold plaster, and in lattice and trellis work. ''Lath'' has expanded to mean any type of backing material for plaster. This includes metal wire mesh or expanded metal that is applied to a wood or metal framework as matrix over which stucco or plaster is applied, as well as wallboard products called gypsum or rock lath.Ching, Frank. ''A visual dictionary of architecture''. New York: Van Nostrand Reinhold, 1995. 198. Print. Historically, reed mat was also used as a lath material. One of the key elements of lath, whether wooden slats or wire mesh, are the openings or gaps that allow plaster or stucco to ooze behind and form a mechanical bond to the lath. This is not necessary for gypsum lath, which relies on a chemical bond. Etymology The word is recorded from the late 13th century and is likely derived from the Old English word *, a var ...
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