Langbeinite
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Langbeinite
Langbeinite is a potassium magnesium sulfate mineral with the chemical formula K2Mg2(SO4)3. Langbeinite crystallizes in the isometric-tetartoidal (cubic) system as transparent colorless or white with pale tints of yellow to green and violet crystalline masses. It has a vitreous luster. The Mohs hardness is 3.5 to 4 and the specific gravity is 2.83. The crystals are piezoelectric. The mineral is an ore of potassium and occurs in marine evaporite deposits in association with carnallite, halite, and sylvite. It was first described in 1891 for an occurrence in Wilhelmshall, Halberstadt, Saxony-Anhalt, Germany, and named for A. Langbein of Leopoldshall, Germany. Langbeinite gives its name to the langbeinites, a family of substances with the same cubic structure, a tetrahedral anion, and large and small cations. Related substances include hydrated salts leonite (K2Mg(SO4)2·4H2O) and picromerite Picromerite (synonyms: schoenite, schönite) is a mineral from the class of hydrous ...
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Langbeinites
Langbeinites are a family of crystalline substances based on the structure of langbeinite with general formula , where M is a large univalent cation (such as potassium, rubidium, caesium, or ammonium), and M' is a small divalent cation (for example, magnesium, calcium, manganese, iron, cobalt, nickel, copper, zinc or cadmium). The sulfate group, , can be substituted by other tetrahedral anions with a double negative charge such as tetrafluoroberyllate (), selenate (), chromate (), molybdate (), or tungstates. Although monofluorophosphates are predicted, they have not been described. By redistributing charges other anions with the same shape such as phosphate also form langbeinite structures. In these the M' atom must have a greater charge to balance the extra three negative charges. At higher temperatures the crystal structure is cubic P213. However, the crystal structure may change to lower symmetries at lower temperatures, for example, P21, P1, or P212121. Usually this temper ...
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Sulfate Mineral
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary minerals in the oxidizing zone of sulfide mineral deposits. The chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates **Barite BaSO4 ** Celestite SrSO4 **Anglesite PbSO4 **Anhydrite CaSO4 **Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates **Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O **Kieserite MgSO4·H2O ** Starkeyite MgSO4·4H2O **Hexahydrite MgSO4·6H2O **Epsomite MgSO4·7H2O **Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O **Antlerite Cu3SO4(OH)4 **Brochantite Cu4SO4 ...
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Evaporite
An evaporite () is a water-soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocean deposits, and non-marine, which are found in standing bodies of water such as lakes. Evaporites are considered sedimentary rocks and are formed by chemical sediments. Formation of evaporite rocks Although all water bodies on the surface and in aquifers contain dissolved salts, the water must evaporate into the atmosphere for the minerals to precipitate. For this to happen, the water body must enter a restricted environment where water input into this environment remains below the net rate of evaporation. This is usually an arid environment with a small basin fed by a limited input of water. When evaporation occurs, the remaining water is enriched in salts, and they precipitate when the water becomes supersaturated. Evaporite depositi ...
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Sulfate Minerals
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal Vein (geology), veins and as secondary minerals in the Redox, oxidizing zone of sulfide mineral deposits. The Chromate ion, chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates **Barite BaSO4 **Celestite SrSO4 **Anglesite PbSO4 **Anhydrite CaSO4 **Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates **Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O **Kieserite MgSO4·H2O **Starkeyite MgSO4·4H2O **Hexahydrite MgSO4·6H2O **Epsomite MgSO4·7H2O **Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O **Antlerite ...
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Evaporite
An evaporite () is a water-soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocean deposits, and non-marine, which are found in standing bodies of water such as lakes. Evaporites are considered sedimentary rocks and are formed by chemical sediments. Formation of evaporite rocks Although all water bodies on the surface and in aquifers contain dissolved salts, the water must evaporate into the atmosphere for the minerals to precipitate. For this to happen, the water body must enter a restricted environment where water input into this environment remains below the net rate of evaporation. This is usually an arid environment with a small basin fed by a limited input of water. When evaporation occurs, the remaining water is enriched in salts, and they precipitate when the water becomes supersaturated. Evaporite depositi ...
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Magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic table) it occurs naturally only in combination with other elements and it almost always has an oxidation state of +2. It reacts readily with air to form a thin passivation coating of magnesium oxide that inhibits further corrosion of the metal. The free metal burns with a brilliant-white light. The metal is obtained mainly by electrolysis of magnesium salts obtained from brine. It is less dense than aluminium and is used primarily as a component in strong and lightweight alloys that contain aluminium. In the cosmos, magnesium is produced in large, aging stars by the sequential addition of three helium nuclei to a carbon nucleus. When such stars explode as supernovas, much of the magnesium is expelled into the interstellar medium where it ma ...
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Sylvite
Sylvite, or sylvine, is potassium chloride (KCl) in natural mineral form. It forms crystals in the isometric system very similar to normal rock salt, halite ( NaCl). The two are, in fact, isomorphous. Sylvite is colorless to white with shades of yellow and red due to inclusions. It has a Mohs hardness of 2.5 and a specific gravity of 1.99. It has a refractive index of 1.4903. Sylvite has a salty taste with a distinct bitterness. Sylvite is one of the last evaporite minerals to precipitate out of solution. As such, it is only found in very dry saline areas. Its principal use is as a potassium fertilizer. Sylvite is found in many evaporite deposits worldwide. Massive bedded deposits occur in New Mexico and western Texas, and in Utah in the US, but the largest world source is in Saskatchewan, Canada. The vast deposits in Saskatchewan, Canada were formed by the evaporation of a Devonian seaway. Sylvite is the official mineral of Saskatchewan. Sylvite was first described in 1832 a ...
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Piezoelectric
Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied Stress (mechanics), mechanical stress. The word ''piezoelectricity'' means electricity resulting from pressure and latent heat. It is derived from the Greek language, Greek word ; ''piezein'', which means to squeeze or press, and ''ēlektron'', which means amber, an ancient source of electric charge. The piezoelectric effect results from the linear electromechanical interaction between the mechanical and electrical states in crystalline materials with no Centrosymmetry, inversion symmetry. The piezoelectric effect is a reversible process (thermodynamics), reversible process: List of piezoelectric materials, materials exhibiting the piezoelectric effect also exhibit the reverse piezoelectric effect, the internal generation of a mechanical strain resulting from an appli ...
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Picromerite
Picromerite (synonyms: schoenite, schönite) is a mineral from the class of hydrous Sulfate minerals, sulfates lacking additional anions, and containing medium to large cations according to the Nickel–Strunz classification. Etymology The name comes from the Greek words πικρός [pikros] for "bitter" and μέρος [meros] for "part", and relates to the bitter taste of the mineral. Occurrence Picromerite is found on comparatively few places, currently (2015) only about 40 localities are known. It was first identified in active volcanic fumaroles on Mount Vesuvius by Arcangelo Scacchi in 1855 and has also been found in volcanic deposits on Mount Etna and on Hawaii (island), Hawai'i. It is more commonly found in the kainite zones of some marine salt deposits, among them salt mines in Thuringia, Lower Saxony and Saxony-Anhalt (Germany), near Hall in Tirol, Hallstatt and Bad Ischl (Austria), near Whitby (UK), and in the Carlsbad Potash District (New Mexico), also on salt la ...
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Leonite
Leonite is a hydrated double sulfate of magnesium and potassium. It has the formula K2SO4·MgSO4·4H2O. The mineral was named after Leo Strippelmann, who was director of the salt works at Westeregeln in Germany. The mineral is part of the blodite group of hydrated double sulfate minerals. Properties Leonite has a bitter taste. When leonite is analyzed for elements, it is usually contaminated with sodium and chloride ions, as it commonly occurs with sodium chloride. Crystal structure In the mineral family of leonite, the lattice contains sulfate tetrahedrons, a divalent element in an octahedral position surrounded by oxygen, and water and univalent metal (potassium) linking these other components together. One sulfate group is disordered at room temperature. The disordered sulfate becomes fixed in position as temperature is lowered. The crystal form also changes at lower temperatures, so two other crystalline forms of leonite exist at lower temperatures. The divalent meta ...
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Potassium
Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmospheric oxygen to form flaky white potassium peroxide in only seconds of exposure. It was first isolated from potash, the ashes of plants, from which its name derives. In the periodic table, potassium is one of the alkali metals, all of which have a single valence electron in the outer electron shell, that is easily removed to create an ion with a positive charge – a cation, that combines with anions to form salts. Potassium in nature occurs only in ionic salts. Elemental potassium reacts vigorously with water, generating sufficient heat to ignite hydrogen emitted in the reaction, and burning with a lilac- colored flame. It is found dissolved in sea water (which is 0.04% potassium by weight), and occurs in many minerals such as orthoclase, ...
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