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Limonoid
Limonoids are phytochemicals of the triterpenoid class which are abundant in sweet or sour-scented citrus fruit and other plants of the families Cucurbitaceae, Rutaceae, and Meliaceae. Certain limonoids are antifeedants such as azadirachtin from the neem tree.{{cite journal, title=Biological activity of limonoids from the rutales, journal=Phytochemistry, volume=31, pages=377–394, authors=Donald E.Champagne, Opender Koul, Murray B. Isman, Geoffrey G. E.Scudder, G. H. Neil Towers, year=1992, issue=2, doi=10.1016/0031-9422(92)90003-9 Chemically, the limonoids consist of variations of the furanolactone core structure. The prototypical structure consists of four six-membered rings and a furan Furan is a heterocyclic organic compound, consisting of a five-membered aromatic ring with four carbon atoms and one oxygen atom. Chemical compounds containing such rings are also referred to as furans. Furan is a colorless, flammable, highly ... ring. Limonoids are classed as tetra ...
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Antifeedant
Antifeedants are organic compounds produced by plants to inhibit attack by insects and grazing animals. These chemical compounds are typically classified as secondary metabolites in that they are not essential for the metabolism of the plant, but instead confer longevity. Antifeedants exhibit a wide range of activities and chemical structures as biopesticides. Examples include rosin, which inhibits attack on trees, and many alkaloids, which are highly toxic to specific insect species. History "Plant-derived insecticides (e.g., rotenone, veratridines, pyrethrins, and nicotine) have been used for insect control since antiquity." The active ingredients in these plants have been purified and modified. For example, variations on pyrethrin has spawned a large number of synthetic insecticides call pyrethroids. Culinary implications In addition to their role defending the plant, antifeedants often confer taste or odors, enhancing the flavor of certain plants. Examples are provided ...
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Neem
''Azadirachta indica'', commonly known as neem, nimtree or Indian lilac, is a tree in the mahogany family Meliaceae. It is one of two species in the genus '' Azadirachta'', and is native to the Indian subcontinent and most of the countries in Africa. It is typically grown in tropical and semi-tropical regions. Neem trees also grow on islands in southern Iran. Its fruits and seeds are the source of neem oil. Description Neem is a fast-growing tree that can reach a height of , and rarely . It is deciduous, shedding many of its leaves during the dry winter months. The branches are wide and spreading. The fairly dense crown is roundish and may reach a diameter of . The neem tree is similar in appearance to its relative, the chinaberry ('' Melia azedarach''). The opposite, pinnate leaves are long, with 20 to 30 medium to dark green leaflets about long. The terminal leaflet often is missing. The petioles are short. White and fragrant flowers are arranged in more-or-less drooping ...
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Furanolactone
A furanolactone is a heterocyclic chemical compound that contains both a lactone Lactones are cyclic carboxylic esters, containing a 1-oxacycloalkan-2-one structure (), or analogues having unsaturation or heteroatoms replacing one or more carbon atoms of the ring. Lactones are formed by intramolecular esterification of the co ... and a furan ring structure. Examples include: * The salvinorins, including the hallucinogenic compound salvinorin A * Columbin, a bitter diterpenoid from '' Calumbae Radix'' * Limonoids such as limonin, nomilin, and nomilinic acid * Tinosporide, a diterpenoid originally isolated from '' Tinospora cordifolia'' References {{reflist Lactones 3-Furyl compounds ...
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Terpenes And Terpenoids
Terpenes () are a class of natural products consisting of compounds with the formula (C5H8)n for n > 1. Comprising more than 30,000 compounds, these unsaturated hydrocarbons are produced predominantly by plants, particularly conifers. Terpenes are further classified by the number of carbons: monoterpenes (C10), sesquiterpenes (C15), diterpenes (C20), as examples. The terpene alpha-pinene, is a major component of the common solvent, turpentine. History and terminology The term ''terpene'' was coined in 1866 by the German chemist August Kekulé to denote all hydrocarbons having the empirical formula C10H16, of which camphene was one. Previously, many hydrocarbons having the empirical formula C10H16 had been called "camphene", but many other hydrocarbons of the same composition had had different names. Kekulé coined the term "terpene" in order to reduce the confusion. The name "terpene" is a shortened form of "terpentine", an obsolete spelling of "turpentine". Although sometimes u ...
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Tetranortriterpenoid
The tetranortriterpenoid class of chemical compounds most noted for the chemical azadirachtin, extracted from the neem tree (''Azadirachta indica'') that displays insecticidal properties. Azadirachtin mimics insect hormones called ecdysones that regulate pupation of insects; application of azadirachtin interrupts the development and pupation of insects, which eventually kills them. The name indicates that the basic skeleton of such compounds contains 26 carbon atoms (4 fewer than triterpenes). Azadirachtin is a tetranortriterpenoid and a limonoid Limonoids are phytochemicals of the triterpenoid class which are abundant in sweet or sour-scented citrus fruit and other plants of the families Cucurbitaceae, Rutaceae, and Meliaceae. Certain limonoids are antifeedants such as azadirachtin fro .... References {{insecticides Plant toxin insecticides Triterpenes ...
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Limonin
Limonin is a limonoid, and a bitter, white, crystalline substance found in citrus and other plants. It is also known as limonoate D-ring-lactone and limonoic acid di-delta-lactone. Chemically, it is a member of the class of compounds known as furanolactones. Sources Limonin is enriched in citrus fruits and is often found at higher concentrations in seeds, for example orange and lemon seeds. Presence in citrus products Limonin and other limonoid compounds contribute to the bitter taste of some citrus food products. Researchers have proposed removal of limonoids from orange juice and other products (known as "debittering") through the use of polymeric films. Research Limonin is under basic research Basic research, also called pure research or fundamental research, is a type of scientific research with the aim of improving scientific theory, theories for better understanding and prediction of natural or other phenomena. In contrast, applied ... to assess its possible biologic ...
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Tetranortriterpenoid
The tetranortriterpenoid class of chemical compounds most noted for the chemical azadirachtin, extracted from the neem tree (''Azadirachta indica'') that displays insecticidal properties. Azadirachtin mimics insect hormones called ecdysones that regulate pupation of insects; application of azadirachtin interrupts the development and pupation of insects, which eventually kills them. The name indicates that the basic skeleton of such compounds contains 26 carbon atoms (4 fewer than triterpenes). Azadirachtin is a tetranortriterpenoid and a limonoid Limonoids are phytochemicals of the triterpenoid class which are abundant in sweet or sour-scented citrus fruit and other plants of the families Cucurbitaceae, Rutaceae, and Meliaceae. Certain limonoids are antifeedants such as azadirachtin fro .... References {{insecticides Plant toxin insecticides Triterpenes ...
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Furan
Furan is a heterocyclic organic compound, consisting of a five-membered aromatic ring with four carbon atoms and one oxygen atom. Chemical compounds containing such rings are also referred to as furans. Furan is a colorless, flammable, highly volatile liquid with a boiling point close to room temperature. It is soluble in common organic solvents, including alcohol, ether, and acetone, and is slightly soluble in water. Its odor is "strong, ethereal; chloroform-like". It is toxic and may be carcinogenic in humans. Furan is used as a starting point for other speciality chemicals. History The name "furan" comes from the Latin ''furfur'', which means bran. (Furfural is produced from bran.) The first furan derivative to be described was 2-furoic acid, by Carl Wilhelm Scheele in 1780. Another important derivative, furfural, was reported by Johann Wolfgang Döbereiner in 1831 and characterised nine years later by John Stenhouse. Furan itself was first prepared by Heinrich Limp ...
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Limonin
Limonin is a limonoid, and a bitter, white, crystalline substance found in citrus and other plants. It is also known as limonoate D-ring-lactone and limonoic acid di-delta-lactone. Chemically, it is a member of the class of compounds known as furanolactones. Sources Limonin is enriched in citrus fruits and is often found at higher concentrations in seeds, for example orange and lemon seeds. Presence in citrus products Limonin and other limonoid compounds contribute to the bitter taste of some citrus food products. Researchers have proposed removal of limonoids from orange juice and other products (known as "debittering") through the use of polymeric films. Research Limonin is under basic research Basic research, also called pure research or fundamental research, is a type of scientific research with the aim of improving scientific theory, theories for better understanding and prediction of natural or other phenomena. In contrast, applied ... to assess its possible biologic ...
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Phytochemicals
Phytochemicals are chemical compounds produced by plants, generally to help them resist fungi, bacteria and plant virus infections, and also consumption by insects and other animals. The name comes . Some phytochemicals have been used as poisons and others as traditional medicine. As a term, ''phytochemicals'' is generally used to describe plant compounds that are under research with unestablished effects on health, and are not scientifically defined as essential nutrients. Regulatory agencies governing food labeling in Europe and the United States have provided guidance for industry to limit or prevent health claims about phytochemicals on food product or nutrition labels. Definition Phytochemicals are chemicals of plant origin. Phytochemicals (from Greek ''phyto'', meaning "plant") are chemicals produced by plants through primary or secondary metabolism. They generally have biological activity in the plant host and play a role in plant growth or defense against competi ...
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