Liming (leather Processing)
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Liming (leather Processing)
Liming is a process used for parchment or leather processing, in which hides are soaked in an alkali solution. It is performed using a drum and paddle or a pit. Its objectives are: * Removal of interfibrillary proteins. * Removal of Keratin proteins. * Collagen swelling due to the alkaline pH. * Collagen fibre bundle splitting. * Removal of natural grease and fatsS.S. Dutta, ''An Introduction to the Principles of Leather Manufacture'', p. 160 Liming operations of cattle hides usually last 18 hours and are generally associated with the alkaline phase of beamhouse operations. Removal of interfibrillary proteins The interfibrillary proteins are denatured by the presence of alkali (particularly sodium sulfide), rendered soluble, facilitating their removal from the leather. Removal is done by the mechanical action of liming or reliming, but more prominently when the pelt is deswelled (during deliming). Failure to remove these proteins results in a hard, tinny leather (due to fib ...
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Parchment
Parchment is a writing material made from specially prepared untanned skins of animals—primarily sheep, calves, and goats. It has been used as a writing medium for over two millennia. Vellum is a finer quality parchment made from the skins of young animals such as lambs and young calves. It may be called animal membrane by libraries and museums that wish to avoid distinguishing between ''parchment'' and the more-restricted term ''vellum'' (see below). Parchment and vellum Today the term ''parchment'' is often used in non-technical contexts to refer to any animal skin, particularly goat, sheep or cow, that has been scraped or dried under tension. The term originally referred only to the skin of sheep and, occasionally, goats. The equivalent material made from calfskin, which was of finer quality, was known as ''vellum'' (from the Old French or , and ultimately from the Latin , meaning a calf); while the finest of all was ''uterine vellum'', taken from a calf foetus or still ...
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Epidermis
The epidermis is the outermost of the three layers that comprise the skin, the inner layers being the dermis and hypodermis. The epidermis layer provides a barrier to infection from environmental pathogens and regulates the amount of water released from the body into the atmosphere through transepidermal water loss. The epidermis is composed of multiple layers of flattened cells that overlie a base layer (stratum basale) composed of columnar cells arranged perpendicularly. The layers of cells develop from stem cells in the basal layer. The human epidermis is a familiar example of epithelium, particularly a stratified squamous epithelium. The word epidermis is derived through Latin , itself and . Something related to or part of the epidermis is termed epidermal. Structure Cellular components The epidermis primarily consists of keratinocytes ( proliferating basal and differentiated suprabasal), which comprise 90% of its cells, but also contains melanocytes, Langerhans ...
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Dyeing
Dyeing is the application of dyes or pigments on textile materials such as fibers, yarns, and fabrics with the goal of achieving color with desired color fastness. Dyeing is normally done in a special solution containing dyes and particular chemical material. Dye molecules are fixed to the fiber by absorption, diffusion, or bonding with temperature and time being key controlling factors. The bond between dye molecule and fiber may be strong or weak, depending on the dye used. Dyeing and printing are different applications; in printing, color is applied to a localized area with desired patterns. In dyeing, it is applied to the entire textile. The primary source of dye, historically, has been nature, with the dyes being extracted from animals or plants. Since the mid-19th century, however, humans have produced artificial dyes to achieve a broader range of colors and to render the dyes more stable to washing and general use. Different classes of dyes are used for different types ...
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Tanning (leather)
Tanning is the process of treating Skinning, skins and Hide (skin), hides of animals to produce leather. A tannery is the place where the skins are processed. Tanning hide into leather involves a process which permanently alters the protein structure of skin, making it more durable and less susceptible to decomposition and coloring. Before tanning, the skins are dehaired, degreased, desalted and soaked in water over a period of six hours to two days. Historically this process was considered a noxious or "odoriferous trade" and relegated to the outskirts of town. Historically, tanning used tannin, an acidic chemical compound from which the tanning process draws its name, derived from the bark of certain trees. An alternative method, developed in the 1800s, is chrome tanning, where chromium salts are used instead of natural tannins. History The English word for tanning is from medieval Latin , derivative of (oak bark), from French (tanbark), from old-Cornish (red oak). ...
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Alkaline Swelling
In chemistry, an alkali (; from ar, القلوي, al-qaly, lit=ashes of the saltwort) is a basic, ionic salt of an alkali metal or an alkaline earth metal. An alkali can also be defined as a base that dissolves in water. A solution of a soluble base has a pH greater than 7.0. The adjective alkaline, and less often, alkalescent, is commonly used in English as a synonym for basic, especially for bases soluble in water. This broad use of the term is likely to have come about because alkalis were the first bases known to obey the Arrhenius definition of a base, and they are still among the most common bases. Etymology The word "alkali" is derived from Arabic ''al qalīy'' (or ''alkali''), meaning ''the calcined ashes'' (see calcination), referring to the original source of alkaline substances. A water-extract of burned plant ashes, called potash and composed mostly of potassium carbonate, was mildly basic. After heating this substance with calcium hydroxide (''slaked lime''), ...
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Calcium Hydroxide
Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca( OH)2. It is a colorless crystal or white powder and is produced when quicklime (calcium oxide) is mixed or slaked with water. It has many names including hydrated lime, caustic lime, builders' lime, slaked lime, cal, and pickling lime. Calcium hydroxide is used in many applications, including food preparation, where it has been identified as E number E526. Limewater, also called milk of lime, is the common name for a saturated solution of calcium hydroxide. Properties Calcium hydroxide is poorly soluble in water, with a retrograde solubility increasing from 0.66 g/L at 100 °C to 1.89 g/L at 0 °C. With a solubility product ''K''sp of 5.02 at 25 °C, its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction: : Ca(OH)2 → Ca2+ + 2 OH− At ambient temperature, calcium hydroxide (portlandite) ...
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Sheepskin
Sheepskin is the Hide (skin), hide of a Domestic sheep, sheep, sometimes also called lambskin. Unlike common leather, sheepskin is Tanning (leather), tanned with the Wool, fleece intact, as in a Fur, pelt.Delbridge, Arthur, "The Macquarie Dictionary", 2nd ed., Macquarie Library, North Ryde, 1991 Uses Sheepskin is used to produce sheepskin leather products and soft wool-lined clothing or coverings, including gloves, hats, slippers, footstools, automotive seat covers, baby and invalid rugs and pelts. Sheepskin numnahs, saddle pads, saddle seat covers, sheepskin horse boots, tack linings and girth tubes are also made and used in equestrianism. The fleece of sheepskin has excellent insulating properties and it is also resistant to flame and static electricity. Wool is considered by the medical profession to be hypoallergenic. Sheepskin is a natural insulator, and draws perspiration away from the wearer and into the fibers. There, it traps between 30 and 36 percent of its own weight i ...
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Disulfide
In biochemistry, a disulfide (or disulphide in British English) refers to a functional group with the structure . The linkage is also called an SS-bond or sometimes a disulfide bridge and is usually derived by the coupling of two thiol groups. In biology, disulfide bridges formed between thiol groups in two cysteine residues are an important component of the secondary and tertiary structure of proteins. ''Persulfide'' usually refers to compounds. In inorganic chemistry disulfide usually refers to the corresponding anion (−S−S−). Organic disulfides Symmetrical disulfides are compounds of the formula . Most disulfides encountered in organo sulfur chemistry are symmetrical disulfides. Unsymmetrical disulfides (also called heterodisulfides) are compounds of the formula . They are less common in organic chemistry, but most disulfides in nature are unsymmetrical. Properties The disulfide bonds are strong, with a typical bond dissociation energy of 60 kcal/mol (251&nbs ...
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Hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution reaction, substitution, elimination reaction, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolysis is the cleavage of biomolecules where a water molecule is consumed to effect the separation of a larger molecule into component parts. When a carbohydrate is broken into its component sugar molecules by hydrolysis (e.g., sucrose being broken down into glucose and fructose), this is recognized as saccharification. Hydrolysis reactions can be the reverse of a condensation reaction in which two molecules join into a larger one and eject a water molecule. Thus hydrolysis adds water to break down, whereas condensation builds up by removing water. Types Usually hydrolysis is a chemical process in which a molecule of water is added to a substance. Sometimes this addition causes both the substance and w ...
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Denaturation (biochemistry)
In biochemistry, denaturation is a process in which proteins or nucleic acids lose the quaternary structure, tertiary structure, and secondary structure which is present in their native state, by application of some external stress or compound such as a strong acid or base, a concentrated inorganic salt, an organic solvent (e.g., alcohol or chloroform), agitation and radiation or heat. If proteins in a living cell are denatured, this results in disruption of cell activity and possibly cell death. Protein denaturation is also a consequence of cell death. Denatured proteins can exhibit a wide range of characteristics, from conformational change and loss of solubility to aggregation due to the exposure of hydrophobic groups. The loss of solubility as a result of denaturation is called ''coagulation''. Denatured proteins lose their 3D structure and therefore cannot function. Protein folding is key to whether a globular or membrane protein can do its job correctly; it must be ...
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Leather
Leather is a strong, flexible and durable material obtained from the tanning, or chemical treatment, of animal skins and hides to prevent decay. The most common leathers come from cattle, sheep, goats, equine animals, buffalo, pigs and hogs, and aquatic animals such as seals and alligators. Leather can be used to make a variety of items, including clothing, footwear, handbags, furniture, tools and sports equipment, and lasts for decades. Leather making has been practiced for more than 7,000 years and the leading producers of leather today are China and India. Animal rights groups claim that modern commercial leather making and the consumption of its products is unethically killing animals. According to the life-cycle assessment (LCA) report for the United Nations Industrial Development Organization, 99% of the raw hides and skins used in the production of leather derive from animals raised for meat and/or dairy production. Critics of tanneries claim that they engage in uns ...
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