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Lead–acid Battery
The lead–acid battery is a type of rechargeable battery first invented in 1859 by French physicist Gaston Planté. It was the first type of rechargeable battery to be invented. Compared to modern rechargeable batteries, lead–acid batteries have relatively low energy density. Despite this, they are able to supply high surge currents. These features, along with their low cost, make them attractive for use in motor vehicles in order to provide the high current required by starter motors. Lead–acid batteries suffer from relatively short cycle lifespan (usually less than 500 deep cycles) and overall lifespan (due to the ''double sulfation'' in the discharged state), as well as long charging times. As they are not as expensive when compared to newer technologies, lead–acid batteries are widely used even when surge current is not important and other designs could provide higher energy densities. In 1999, lead–acid battery sales accounted for 40–50% of the value from batteries ...
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Car Battery
An automotive battery, or car battery, is a usually 12 Volt lead-acid rechargeable battery that is used to start a motor vehicle, and to power lights, screen wiper etc. while the engine is off. Its main purpose is to provide an electric current to the Starter (engine), electric-powered starting motor, which in turn starts the chemically-powered internal combustion engine that actually propels the vehicle. Once the engine is running, power for the car's electrical systems is still supplied by the battery, with the alternator (automotive), alternator charging the battery as demands increase or decrease. Battery in modern cars Gasoline and diesel engine Typically, starting uses less than three percent of the battery capacity. For this reason, automotive batteries are designed to deliver maximum current for a short period of time. They are sometimes referred to as "SLI batteries" for this reason, for starting, lighting and ignition. SLI batteries are not designed for deep dischargi ...
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Lead Dioxide
Lead(IV) oxide, commonly known as lead dioxide, is an inorganic compound with the chemical formula . It is an oxide where lead is in an oxidation state of +4. It is a dark-brown solid which is insoluble in water. It exists in two crystalline forms. It has several important applications in electrochemistry, in particular as the positive plate of lead acid batteries. Properties Physical Lead dioxide has two major polymorphs, alpha and beta, which occur naturally as rare minerals scrutinyite and plattnerite, respectively. Whereas the beta form had been identified in 1845, α- was first identified in 1946 and found as a naturally occurring mineral 1988. The alpha form has orthorhombic symmetry, space group Pbcn (No. 60), Pearson symbol ''oP''12, lattice constants ''a'' = 0.497 nm, ''b'' = 0.596 nm, ''c'' = 0.544 nm, ''Z'' = 4 (four formula units per unit cell). The lead atoms are six-coordinate. The symmetry of the beta form is tetragonal, space group P42/mnm ...
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Watt-hour
A kilowatt-hour ( unit symbol: kW⋅h or kW h; commonly written as kWh) is a non-SI unit of energy equal to 3.6 megajoules (MJ) in SI units, which is the energy delivered by one kilowatt of power for one hour. Kilowatt-hours are a common billing unit for electrical energy supplied by electric utilities. Metric prefixes are used for multiples and submultiples of the basic unit, the watt-hour (3.6 kJ). Definition The kilowatt-hour is a composite unit of energy equal to one kilowatt (kW) multiplied by (i.e., sustained for) one hour. The International System of Units (SI) unit of energy meanwhile is the joule (symbol J). Because a watt is by definition one joule per second, and because there are 3,600 seconds in an hour, one kWh equals 3,600 kilojoules or 3.6 MJ."Half-high dots or spaces are used to express a derived unit formed from two or more other units by multiplication.", Barry N. Taylor. (2001 ed.''The International System of Units.'' (Special publication 33 ...
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Ampere Hour
An ampere-hour or amp-hour (symbol: A⋅h or A h; often simplified as Ah) is a unit of electric charge, having dimensions of electric current multiplied by time, equal to the charge transferred by a steady current of one ampere flowing for one hour (3,600 seconds), thus equal to 3600 A⋅s or Coulomb. The commonly seen milliampere-hour (symbol: mA⋅h, mA h, often simplified as mAh) is one-thousandth of an ampere-hour (3.6 coulombs). Use The ampere-hour is frequently used in measurements of electrochemical systems such as electroplating and for battery capacity where the commonly known nominal voltage is understood. A ''milliampere second'' (mA⋅s) is a unit of measurement used in X-ray imaging, diagnostic imaging, and radiation therapy. It is equivalent to a ''millicoulomb''. This quantity is proportional to the total X-ray energy produced by a given X-ray tube operated at a particular voltage. The same total dose can be delivered in different time periods d ...
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Coulomb
The coulomb (symbol: C) is the unit of electric charge in the International System of Units (SI). It is defined to be equal to the electric charge delivered by a 1 ampere current in 1 second, with the elementary charge ''e'' as a defining constant in the SI. Definition The SI defines the coulomb as "the quantity of electricity carried in 1 second by a current of 1 ampere" by fixing the value of the elementary charge, . Inverting the relationship, the coulomb can be expressed in terms of the elementary charge: 1 ~ \mathrm = \frac = \frac ~ e. It is approximately and is thus not an integer multiple of the elementary charge. The coulomb was previously defined in terms of the ampere based on the force between two wires, as . The 2019 redefinition of the ampere and other SI base units fixed the numerical value of the elementary charge when expressed in coulombs and therefore fixed the value of the coulomb when expressed as a multiple of the fundamental charge. SI pref ...
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Faraday (unit)
In physical chemistry, the Faraday constant (symbol , sometimes stylized as ℱ) is a physical constant defined as the quotient of the total electric charge () by the amount () of elementary charge carriers in any given sample of matter: it is expressed in units of coulombs per mole (C/mol). As such, it represents the " molar elementary charge", that is, the electric charge of one mole of elementary carriers (e.g., protons). It is named after the English scientist Michael Faraday. Since the 2019 revision of the SI, the Faraday constant has an exactly defined value, the product of the elementary charge (, in coulombs) and the Avogadro constant (, in reciprocal moles): : Derivation The Faraday constant can be thought of as the proportionality factor between the charge in coulombs (used in physics and in practical electrical measurements) and the amount of substance in moles (used in chemistry), and is therefore of particular use in electrochemistry, particularly in elect ...
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Mole (unit)
The mole (symbol mol) is a unit of measurement, the base unit in the International System of Units (SI) for ''amount of substance'', an SI base quantity proportional to the number of elementary entities of a substance. One mole is an aggregate of exactly elementary entities (approximately 602 sextillion or 602 billion times a trillion), which can be atoms, molecules, ions, ion pairs, or other particles. The number of particles in a mole is the Avogadro number (symbol ) and the numerical value of the '' Avogadro constant'' (symbol ) expressed in mol−1. The relationship between the mole, Avogadro number, and Avogadro constant can be expressed in the following equation:1\text = \frac = \frac The current SI value of the mole is based on the historical definition of the mole as the amount of substance that corresponds to the number of atoms in 12  grams of 12C, which made the molar mass of a compound in grams per mole, numerically equal to the average molecular mass or ...
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Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (English in the Commonwealth of Nations, Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen, and hydrogen, with the molecular formula . It is a colorless, odorless, and Viscosity, viscous liquid that is Miscibility, miscible with water. Pure sulfuric acid does not occur naturally due to its Dehydration reaction, strong affinity to water vapor; it is Hygroscopy, hygroscopic and readily absorbs water vapor from the Atmosphere of Earth, air. Concentrated sulfuric acid is a strong oxidant with powerful dehydrating properties, making it highly corrosive towards other materials, from rocks to metals. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid but, to the contrary, dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is releas ...
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Electrolyte
An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. This includes most soluble Salt (chemistry), salts, acids, and Base (chemistry), bases, dissolved in a polar solvent like water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout the solvent. Solid-state electrolytes also exist. In medicine and sometimes in chemistry, the term electrolyte refers to the substance that is dissolved. Electrically, such a solution is neutral. If an electric potential is applied to such a solution, the cations of the solution are drawn to the electrode that has an abundance of electrons, while the anions are drawn to the electrode that has a deficit of electrons. The movement of anions and cations in opposite directions within the solution amounts to a current. Some gases, such as hydrogen chloride (HCl), under conditions of high temperature or low pressure can also functi ...
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Lead(II) Sulfate
Lead(II) sulfate (PbSO4) is a white solid, which appears white in microcrystalline form. It is also known as ''fast white'', ''milk white'', ''sulfuric acid lead salt'' or ''anglesite''. It is often seen in the plates/electrodes of car batteries, as it is formed when the battery is discharged (when the battery is recharged, then the lead sulfate is transformed back to metallic lead and sulfuric acid on the negative terminal or lead dioxide and sulfuric acid on the positive terminal). Lead sulfate is poorly soluble in water. Structure Anglesite (lead(II) sulfate, ) adopts the same orthorhombic crystal structure as celestite ( strontium sulfate, ) and barite (barium sulfate, ). All three minerals' structures are in the space group ''Pbnm'' (number 62). Each lead(II) ion is surrounded by 12 oxygen atoms from 7 sulfate ions, forming a PbO12 polyhedron. The lead–oxygen distances range from 2.612 Å to 3.267 Å and the average distance is 2.865 Å. Manufacturing Lead(II) sulfat ...
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Discharged
Discharge may refer to: * The act of firing a gun * Termination of employment, the end of an employee's duration with an employer * Military discharge, the release of a member of the armed forces from service Flow * Discharge (hydrology), the amount of water flowing through the channel ** Effluent released into a river or sea ** Groundwater discharge, the volumetric flow rate of groundwater through an aquifer * Discharging method (discrete mathematics) is a proof technique in discrete mathematics * Electric discharge: ** Corona discharge, a type of electric current ** Glow discharge, a plasma ** Discharger, an electrical device that releases stored energy *** Battery discharging *** Static discharger, a device used on airplanes to maintain use of electrical equipment ** Electrostatic discharge, sudden and momentary electric current flows between two objects *** Dielectric barrier discharge, the electrical discharge between two electrodes separated by an insulating dielectric ...
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American Physical Society
The American Physical Society (APS) is a not-for-profit membership organization of professionals in physics and related disciplines, comprising nearly fifty divisions, sections, and other units. Its mission is the advancement and diffusion of knowledge of physics. It publishes more than a dozen scientific journals, including the prestigious '' Physical Review'' and ''Physical Review Letters'', and organizes more than twenty science meetings each year. It is a member society of the American Institute of Physics. Since January 2021, it is led by chief executive officer Jonathan Bagger. History The American Physical Society was founded on May 20, 1899, when thirty-six physicists gathered at Columbia University for that purpose. They proclaimed the mission of the new Society to be "to advance and diffuse the knowledge of physics", and in one way or another the APS has been at that task ever since. In the early years, virtually the sole activity of the APS was to hold scientific m ...
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