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Lead(II) Carbonate
Lead(II) carbonate is the chemical compound with the chemical formula . It is a white solid with several practical uses, despite its toxicity. It occurs naturally as the mineral cerussite. Structure Like all metal carbonates, lead(II) carbonate adopts a dense, highly crosslinked structure consisting of intact and metal cation sites. As verified by X-ray crystallography, the Pb(II) centers are seven-coordinate, being surrounded by multiple carbonate ligands. The carbonate centers are bonded to bidentate to a single Pb and bridge to five other Pb sites. Production and use Lead carbonate is manufactured by passing carbon dioxide into a cold dilute solution of lead(II) acetate, or by shaking a suspension of a lead salt more soluble than the carbonate with ammonium carbonate at a low temperature to avoid formation of basic lead carbonate. : Lead carbonate is used as a catalyst to polymerize formaldehyde to poly(oxymethylene). It improves the bonding of chloroprene to wire. Regulat ...
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Cerussite
Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate (PbCO3), and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was mentioned by Conrad Gessner in 1565, and in 1832 F. S. Beudant applied the name ''céruse'' to the mineral, whilst the present form, cerussite, is due to W. Haidinger (1845). Miners' names in early use were lead-spar and white-lead-ore. Cerussite crystallizes in the orthorhombic crystal system and is isomorphous with aragonite. Like aragonite it is very frequently twinned, the compound crystals being pseudo-hexagonal in form. Three crystals are usually twinned together on two faces of the prism, producing six-rayed stellate groups with the individual crystals intercrossing at angles of nearly 60°. Crystals are of frequent occurrence and they usually have very bright and smooth faces. The mineral also occurs in compact granular masses, and sometimes in fibrous fo ...
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Ammonium Carbonate
Ammonium carbonate is a salt with the chemical formula (NH4)2CO3. Since it readily degrades to gaseous ammonia and carbon dioxide upon heating, it is used as a leavening agent and also as smelling salt. It is also known as baker's ammonia and is a predecessor to the more modern leavening agents baking soda and baking powder. It is a component of what was formerly known as sal volatile and salt of hartshorn, and produces a pungent smell when baked. Production Ammonium carbonate is produced by combining carbon dioxide and aqueous ammonia. About 80,000 tons/year were produced as of 1997. An orthorhombic monohydrate is known. It crystallizes in an ammonia solution exposed in a carbon dioxide-rich atmosphere. Decomposition Ammonium carbonate slowly decomposes at standard temperature and pressure through two pathways. Thus any initially pure sample of ammonium carbonate will soon become a mixture including various byproducts. Ammonium carbonate can spontaneously decompose into ammo ...
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Leadhillite
Leadhillite is a lead sulfate carbonate hydroxide mineral, often associated with anglesite. It has the formula Pb4SO4(CO3)2(OH)2. Leadhillite crystallises in the monoclinic system, but develops pseudo-hexagonal forms due to crystal twinning. It forms transparent to translucent variably coloured crystals with an adamantine lustre. It is quite soft with a Mohs hardness of 2.5 and a relatively high specific gravity of 6.26 to 6.55. It was discovered in 1832 in the Susannah Mine, Leadhills in the county of Lanarkshire, Scotland. It is trimorphous with susannite and macphersonite (these three minerals have the same formula, but different structures). Leadhillite is monoclinic, susannite is trigonal and macphersonite is orthorhombic. Leadhillite was named in 1832 after the locality. Unit cell Leadhillite belongs to the monoclinic crystal class 2/m, which is the class with the highest symmetry in the monoclinic system. It has a two-fold axis of symmetry perpendicular to a mirror pl ...
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Abellaite
Abellaite is a hydrous carbonate mineral discovered in the abandoned Eureka uranium mine in the village of Torre de Capdella (Lleida province), Catalonia, Spain. The ideal chemical formula of abellaite is NaPb2(CO3)2(OH). It is named in honor of Joan Abella i Creus, a Catalan gemmologist who has long studied minerals from the Eureka mine and first found abellaite in the mine. A team composed, among others, by Jordi Ibáñez-Insa from the Institute of Earth Sciences Jaume Almera (CSIC) and by Joan Viñals and Xavier Llovet from the University of Barcelona, identified and characterized the mineral’s structure and chemical composition. Abellaite crystals are colorless to white, with a glassy or pearly appearance, and are easily crumbled. The mineral has a known synthetic analogue and is chemically similar to sanrománite. Robert Hazen et al. predicted its existence in 2015. Localities Catalonia, Spain: Eureka mine, Castell-estaó, La Torre de Cabdella, La Vall Fosca, El Pallar ...
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White Lead
White lead is the basic lead carbonate 2PbCO3·Pb(OH)2. It is a complex salt, containing both carbonate and hydroxide ions. White lead occurs naturally as a mineral, in which context it is known as hydrocerussite, a hydrate of cerussite. It was formerly used as an ingredient for lead paint and a cosmetic called Venetian ceruse, because of its opacity and the satiny smooth mixture it made with dryable oils. However, it tended to cause lead poisoning, and its use has been banned in most countries. White lead compounds known as lead soap were also used as additive for lubricants for bearings and in machine shops. Lead soap was also used as an oil drying agent for paints made with drying oil or air drying paints made with alkyd resins. Lead is often used with cobalt driers. Lead free substitutes have been developed to replace this use of lead in paint. History What is commonly known today as the "Dutch method" for the preparation of white lead was described as early as Theoph ...
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Chloroprene
Chloroprene is the common name for 2-chlorobuta-1,3-diene (IUPAC name) with the chemical formula CH2=CCl−CH=CH2. Chloroprene is a colorless volatile liquid, almost exclusively used as a monomer for the production of the polymer polychloroprene, better known as neoprene, a type of synthetic rubber. History Although it may have been discovered earlier, chloroprene was largely developed by DuPont during the early 1930s, specifically with the formation of neoprene in mind. The chemists Elmer K. Bolton, Wallace Carothers, Arnold Collins and Ira Williams are generally accredited with its development and commercialisation although the work was based upon that of Julius Arthur Nieuwland, with whom they collaborated. Production Chloroprene is produced in three steps from 1,3-butadiene: (i) chlorination, (ii) isomerization of part of the product stream, and (iii) dehydrochlorination of 3,4-dichlorobut-1-ene. Chlorine adds to 1,3-butadiene to afford a mixture of 3,4-dichlorobut-1-ene ...
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Poly(oxymethylene)
Polyoxymethylene (POM), also known as acetal, polyacetal, and polyformaldehyde, is an engineering thermoplastic used in precision parts requiring high stiffness, low friction, and excellent dimensional stability. As with many other synthetic polymers, it is produced by different chemical firms with slightly different formulas and sold variously by such names as Delrin, Kocetal, Ultraform, Celcon, Ramtal, Duracon, Kepital, Polypenco, Tenac and Hostaform. POM is characterized by its high strength, hardness and rigidity to −40 °C. POM is intrinsically opaque white because of its high crystalline composition but can be produced in a variety of colors. POM has a density of 1.410–1.420g/cm3. Typical applications for injection-molded POM include high-performance engineering components such as small gear wheels, eyeglass frames, ball bearings, ski bindings, fasteners, gun parts, knife handles, and lock systems. The material is widely used in the automotive and consumer electr ...
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Lead(II) Acetate
Lead(II) acetate (Pb(CH3COO)2), also known as lead acetate, lead diacetate, plumbous acetate, sugar of lead, lead sugar, salt of Saturn, or Goulard's powder, is a white crystalline chemical compound with a slightly sweet taste. Like many other lead compounds, it is toxic. Lead acetate is soluble in water and glycerin. With water it forms the trihydrate, Pb(CH3COO)2·3H2O, a colourless or white efflorescent monoclinic crystalline substance. The substance is used as a reagent to make other lead compounds and as a fixative for some dyes. In low concentrations, it is the principal active ingredient in progressive types of hair colouring dyes. Lead(II) acetate is also used as a mordant in textile printing and dyeing, and as a drier in paints and varnishes. It was historically used as a sweetener and preservative in wines and in other foods and for cosmetics. Production Lead acetate can be made by boiling elemental lead in acetic acid and hydrogen peroxide. This method will also work ...
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Ethanol
Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an Alcohol (chemistry), alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a hydroxyl group). Ethanol is a Volatility (chemistry), volatile, Combustibility and flammability, flammable, colorless liquid with a characteristic wine-like odor and pungent taste. It is a psychoactive recreational drug, the active ingredient in alcoholic drinks. Ethanol is naturally produced by the fermentation process of Carbohydrate, sugars by yeasts or via Petrochemistry, petrochemical processes such as ethylene hydration. It has medical applications as an antiseptic and disinfectant. It is used as a chemical solvent and in the Chemical synthesis, synthesis of organic compounds, and as a Alcohol fuel, fuel source. Ethanol also can be dehydrated to make ethylene, an important chemical feedstock. As of 2006, world produ ...
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Carbon Dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. It is a trace gas in Earth's atmosphere at 421 parts per million (ppm), or about 0.04% by volume (as of May 2022), having risen from pre-industrial levels of 280 ppm. Burning fossil fuels is the primary cause of these increased CO2 concentrations and also the primary cause of climate change.IPCC (2022Summary for policy makersiClimate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, ...
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