Cerussite
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Cerussite (also known as lead carbonate or white lead ore) is a
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
consisting of
lead carbonate Lead(II) carbonate is the chemical compound with the chemical formula . It is a white solid with several practical uses, despite its toxicity. It occurs naturally as the mineral cerussite. Structure Like all metal carbonates, lead(II) carbonate a ...
(PbCO3), and is an important
ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
of lead. The name is from the
Latin Latin (, or , ) is a classical language belonging to the Italic branch of the Indo-European languages. Latin was originally a dialect spoken in the lower Tiber area (then known as Latium) around present-day Rome, but through the power of the ...
''cerussa'',
white lead White lead is the basic lead carbonate 2PbCO3·Pb(OH)2. It is a complex salt, containing both carbonate and hydroxide ions. White lead occurs naturally as a mineral, in which context it is known as hydrocerussite, a hydrate of cerussite. It was ...
. ''Cerussa nativa'' was mentioned by
Conrad Gessner Conrad Gessner (; la, Conradus Gesnerus 26 March 1516 – 13 December 1565) was a Swiss physician, naturalist, bibliographer, and philologist. Born into a poor family in Zürich, Switzerland, his father and teachers quickly realised his tale ...
in 1565, and in 1832 F. S. Beudant applied the name ''céruse'' to the mineral, whilst the present form, cerussite, is due to W. Haidinger (1845). Miners' names in early use were lead-spar and white-lead-ore. Cerussite
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
lizes in the
orthorhombic crystal system In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with ...
and is isomorphous with
aragonite Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including pre ...
. Like aragonite it is very frequently twinned, the compound crystals being pseudo-hexagonal in form. Three crystals are usually twinned together on two faces of the prism, producing six-rayed stellate groups with the individual crystals intercrossing at angles of nearly 60°. Crystals are of frequent occurrence and they usually have very bright and smooth faces. The mineral also occurs in compact granular masses, and sometimes in fibrous forms. The mineral is usually colorless or white, sometimes grey or greenish in tint and varies from transparent to translucent with an adamantine lustre. It is very brittle, and has a conchoidal fracture. It has a
Mohs hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by t ...
of 3 to 3.75 and a
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its densest ...
of 6.5. A variety containing 7% of zinc carbonate, replacing lead carbonate, is known as iglesiasite, from Iglesias in
Sardinia Sardinia ( ; it, Sardegna, label=Italian, Corsican and Tabarchino ; sc, Sardigna , sdc, Sardhigna; french: Sardaigne; sdn, Saldigna; ca, Sardenya, label=Algherese and Catalan) is the second-largest island in the Mediterranean Sea, after ...
, where it is found. The mineral may be readily recognized by its characteristic twinning, in conjunction with the adamantine lustre and high specific gravity. It dissolves with effervescence in dilute
nitric acid Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitri ...
. A blowpipe test will cause it to fuse very readily, and gives indications for lead. Finely crystallized specimens have been obtained from the Friedrichssegen mine in
Lahnstein Lahnstein () is a ''verband''-free town of Rhein-Lahn-Kreis in Rhineland-Palatinate, Germany. It is situated at the confluence of the Lahn with the Rhine, approximately south of Koblenz. Lahnstein was created in 1969 by the merger of the prev ...
in
Rhineland-Palatinate Rhineland-Palatinate ( , ; german: link=no, Rheinland-Pfalz ; lb, Rheinland-Pfalz ; pfl, Rhoilond-Palz) is a western state of Germany. It covers and has about 4.05 million residents. It is the ninth largest and sixth most populous of the ...
,
Johanngeorgenstadt Johanngeorgenstadt () is a mining town in Saxony’s Ore Mountains, 17 km south of Aue, and 27 km northwest of Karlovy Vary. It lies in the district of Erzgebirgskreis, on the border with the Czech Republic, is a state-recognized heal ...
in
Saxony Saxony (german: Sachsen ; Upper Saxon: ''Saggsn''; hsb, Sakska), officially the Free State of Saxony (german: Freistaat Sachsen, links=no ; Upper Saxon: ''Freischdaad Saggsn''; hsb, Swobodny stat Sakska, links=no), is a landlocked state of ...
, Stříbro in the
Czech Republic The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...
,
Phoenixville Phoenixville is a borough in Chester County, Pennsylvania, United States. It is located northwest of Philadelphia at the junction of French Creek and the Schuylkill River. It is in the Philadelphia metropolitan area. The population is 18,616 ...
in
Pennsylvania Pennsylvania (; ( Pennsylvania Dutch: )), officially the Commonwealth of Pennsylvania, is a state spanning the Mid-Atlantic, Northeastern, Appalachian, and Great Lakes regions of the United States. It borders Delaware to its southeast, ...
, Broken Hill in New South Wales, and several other localities. Delicate acicular crystals of considerable length were found long ago in the Pentire Glaze mine near
St Minver St Minver ( kw, Sen Menvra) is the name of an ecclesiastical parish, a civil parish and a village in north Cornwall, England, United Kingdom. The civil parish of St Minver is in Bodmin Registration District and is nominally divided into St Minv ...
in
Cornwall Cornwall (; kw, Kernow ) is a historic county and ceremonial county in South West England. It is recognised as one of the Celtic nations, and is the homeland of the Cornish people. Cornwall is bordered to the north and west by the Atlantic ...
. Cerussite is often found in considerable quantities, and has a lead content of up to 77.5%. Lead(II) carbonate is practically insoluble in neutral water (solubility product b2+CO32−] ≈ 1.5×10−13 at 25 °C), but will dissolve in dilute acids.


Commercial uses

"
White lead White lead is the basic lead carbonate 2PbCO3·Pb(OH)2. It is a complex salt, containing both carbonate and hydroxide ions. White lead occurs naturally as a mineral, in which context it is known as hydrocerussite, a hydrate of cerussite. It was ...
" is the key ingredient in (now discontinued)
lead paint Lead paint or lead-based paint is paint containing lead. As pigment, lead(II) chromate (, "chrome yellow"), lead(II,IV) oxide, (, "red lead"), and lead(II) carbonate (, "white lead") are the most common forms.. Lead is added to paint to accele ...
s. Ingestion of lead-based paint chips is the most common cause of lead poisoning in children. Both "white lead" and
lead acetate Lead acetate can refer to: * Lead subacetate (Basic lead acetate), Pb3(OH)4(CH3COO)2 * Lead(IV) acetate Lead(IV) acetate or lead tetraacetate is an organometallic compound with chemical formula . It is a colorless solid that is soluble in nonpo ...
have been used in cosmetics throughout history, though this practice has ceased in Western countries.


Cerussite images

File:cerussite09.jpg, Crystals of cerussite, a secondary lead ore File:Light of the Desert.jpg, At 890 carats, the Light of the Desert (located at
Toronto Toronto ( ; or ) is the capital city of the Canadian province of Ontario. With a recorded population of 2,794,356 in 2021, it is the most populous city in Canada and the fourth most populous city in North America. The city is the anch ...
's Royal Ontario Museum) is the world's largest faceted cerussite. File:Cerussite-Malachite-Mimetite-158529.jpg, Colorless cerussite crystal that has been included by wisps of light green malachite File:Cerussite-18566.jpg, Fine example of reticulated growth


See also

* Venetian ceruse – Cerussite-based cosmetic popularly thought to be worn by
Elizabeth I of England Elizabeth I (7 September 153324 March 1603) was Queen of England and Ireland from 17 November 1558 until her death in 1603. Elizabeth was the last of the five House of Tudor monarchs and is sometimes referred to as the "Virgin Queen". Eli ...


References

* {{Reflist


External links


Mineral galleries
Carbonate minerals Gemstones Lead minerals Luminescent minerals Minerals in space group 62 Orthorhombic minerals Aragonite group