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Iron Aluminide
Iron aluminides are intermetallic compounds of iron and aluminium - they typically contain ~18% Al or more. Good oxide and sulfur resistance, with strength comparable to steel alloys, and low cost of materials have made these compounds of metallurgical interest - however low ductility and issues with hydrogen embrittlement are barriers to their processing and use in structural applications. Overview High corrosion resistance of Iron alloys containing more than 18% aluminium was first noted in the 1930s. Their tensile strength compares favorably with steels, whilst utilizing only common elements; however they have low ductility at room temperature, and strength drops of substantially over 600 °C. The alloys also have good sulfide and oxidation resistance, good wear resistance, and lower density than steels. Peak strength and hardness is reached at the Fe3Al stoichiometric region. Although Al gives corrosion resistance via an oxide film surface, reaction (with water) may also g ...
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Intermetallic
An intermetallic (also called an intermetallic compound, intermetallic alloy, ordered intermetallic alloy, and a long-range-ordered alloy) is a type of metallic alloy that forms an ordered solid-state compound between two or more metallic elements. Intermetallics are generally hard and brittle, with good high-temperature mechanical properties. They can be classified as stoichiometric or nonstoichiometic intermetallic compounds. Although the term "intermetallic compounds", as it applies to solid phases, has been in use for many years, its introduction was regretted, for example by Hume-Rothery in 1955. Definitions Research definition Schulze in 1967 defined intermetallic compounds as ''solid phases containing two or more metallic elements, with optionally one or more non-metallic elements, whose crystal structure differs from that of the other constituents''. Under this definition, the following are included: #Electron (or Hume-Rothery) compounds #Size packing phases. e.g. Lav ...
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Argon
Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abundant as water vapor (which averages about 4000 ppmv, but varies greatly), 23 times as abundant as carbon dioxide (400 ppmv), and more than 500 times as abundant as neon (18 ppmv). Argon is the most abundant noble gas in Earth's crust, comprising 0.00015% of the crust. Nearly all of the argon in Earth's atmosphere is radiogenic argon-40, derived from the decay of potassium-40 in Earth's crust. In the universe, argon-36 is by far the most common argon isotope, as it is the most easily produced by stellar nucleosynthesis in supernovas. The name "argon" is derived from the Greek word , neuter singular form of meaning 'lazy' or 'inactive', as a reference to the fact that the element undergoes almost no chemical reactions. The complete octe ...
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Superheater
A superheater is a device used to convert saturated steam or wet steam into superheated steam or dry steam. Superheated steam is used in steam turbines for electricity generation, steam engines, and in processes such as steam reforming. There are three types of superheaters: radiant, convection, and separately fired. A superheater can vary in size from a few tens of feet to several hundred feet (a few metres to some hundred metres). Types * A radiant superheater is placed directly in radiant zone of the combustion chamber near the water wall so as to absorb heat by radiation. * A convection superheater is located in the convective zone of the furnace usually ahead of economizer (in the path of the hot flue gases). These are also called primary superheaters. * A separately fired superheater is a superheater that is placed outside the main boiler, which has its own separate combustion system. This superheater design incorporates additional burners in the area of superheater pipes ...
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Coal Gasification
Coal gasification is the process of producing syngas—a mixture consisting primarily of carbon monoxide (CO), hydrogen (H2), carbon dioxide (CO2), methane (CH4), and water vapour (H2O)—from coal and water, air and/or oxygen. Historically, coal was gasified to produce coal gas, also known as "town gas". Coal gas is combustible and was used for heating and municipal lighting, before the advent of large-scale extraction of natural gas from oil wells. In current practice, large-scale coal gasification installations are primarily for electricity generation (both in conventional thermal power stations and molten carbonate fuel cell power stations), or for production of chemical feedstocks. The hydrogen obtained from coal gasification can be used for various purposes such as making ammonia, powering a hydrogen economy, or upgrading fossil fuels. Alternatively, coal-derived syngas can be converted into transportation fuels such as gasoline and diesel through additional treatment, or ...
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Heating Element
A heating element converts electrical energy into heat through the process of Joule heating. Electric current through the element encounters resistance, resulting in heating of the element. Unlike the Peltier effect, this process is independent of the direction of current. Heating elements types Metal Resistance wire: Metallic resistance heating elements may be wire or ribbon, straight or coiled. They are used in common heating devices like toasters and hair dryers, furnaces for industrial heating, floor heating, roof heating, pathway heating to melt snow, dryers, etc. The most common classes of materials used include: * Nichrome: Most resistance wire heating elements usually use nichrome 80/20 (80% Nickel, 20% Chromium) wire, ribbon, or strip. Nichrome 80/20 is an ideal material, because it has relatively high resistance and forms an adherent layer of chromium oxide when it is heated for the first time. Material beneath this layer will not oxidize, preventing the wire ...
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Precipitation Hardening
Precipitation hardening, also called age hardening or particle hardening, is a heat treatment technique used to increase the yield strength of malleable materials, including most structural alloys of aluminium, magnesium, nickel, titanium, and some steels and stainless steels. In superalloys, it is known to cause yield strength anomaly providing excellent high-temperature strength. Precipitation hardening relies on changes in solid solubility with temperature to produce fine particles of an impurity phase, which impede the movement of dislocations, or defects in a crystal's lattice. Since dislocations are often the dominant carriers of plasticity, this serves to harden the material. The impurities play the same role as the particle substances in particle-reinforced composite materials. Just as the formation of ice in air can produce clouds, snow, or hail, depending upon the thermal history of a given portion of the atmosphere, precipitation in solids can produce many differen ...
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Solid Solution Strengthening
In metallurgy, solid solution strengthening is a type of alloying that can be used to improve the strength of a pure metal. The technique works by adding atoms of one element (the alloying element) to the crystalline lattice of another element (the base metal), forming a solid solution. The local nonuniformity in the lattice due to the alloying element makes plastic deformation more difficult by impeding dislocation motion through stress fields. In contrast, alloying beyond the solubility limit can form a second phase, leading to strengthening via other mechanisms (e.g. the precipitation of intermetallic compounds). Types Depending on the size of the alloying element, a substitutional solid solution or an interstitial solid solution can form. In both cases, atoms are vizualised as rigid spheres where the overall crystal structure is essentially unchanged. The rationale of crystal geometry to atom solubility prediction is summarized in the Hume-Rothery rules and Pauling's rules. ...
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Creep (deformation)
In materials science, creep (sometimes called cold flow) is the tendency of a solid material to move slowly or deform permanently under the influence of persistent mechanical stresses. It can occur as a result of long-term exposure to high levels of stress that are still below the yield strength of the material. Creep is more severe in materials that are subjected to heat for long periods and generally increases as they near their melting point. The rate of deformation is a function of the material's properties, exposure time, exposure temperature and the applied structural load. Depending on the magnitude of the applied stress and its duration, the deformation may become so large that a component can no longer perform its function – for example creep of a turbine blade could cause the blade to contact the casing, resulting in the failure of the blade. Creep is usually of concern to engineers and metallurgists when evaluating components that operate under high stresses or hig ...
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Chemical Vapor Deposition
Chemical vapor deposition (CVD) is a vacuum deposition method used to produce high quality, and high-performance, solid materials. The process is often used in the semiconductor industry to produce thin films. In typical CVD, the wafer (substrate) is exposed to one or more volatile precursors, which react and/or decompose on the substrate surface to produce the desired deposit. Frequently, volatile by-products are also produced, which are removed by gas flow through the reaction chamber. Microfabrication processes widely use CVD to deposit materials in various forms, including: monocrystalline, polycrystalline, amorphous, and epitaxial. These materials include: silicon ( dioxide, carbide, nitride, oxynitride), carbon (fiber, nanofibers, nanotubes, diamond and graphene), fluorocarbons, filaments, tungsten, titanium nitride and various high-κ dielectrics. The term ''chemical vapour deposition'' was coined 1960 by ''John M. Blocher, Jr.'' who intended to differentiate ''chemic ...
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Vacuum Furnace
A vacuum furnace is a type of furnace in which the product in the furnace is surrounded by a vacuum during processing. The absence of air or other gases prevents oxidation, heat loss from the product through convection, and removes a source of contamination. This enables the furnace to heat materials (typically metals and ceramics) to temperatures as high as with select materials. Maximum furnace temperatures and vacuum levels depend on melting points and vapor pressures of heated materials. Vacuum furnaces are used to carry out processes such as annealing, brazing, sintering and heat treatment with high consistency and low contamination. Characteristics of a vacuum furnace are: * Uniform temperatures in the range. * Commercially available vacuum pumping systems can reach vacuum levels as low as * Temperature can be controlled within a heated zone, typically surrounded by heat shielding or insulation. * Low contamination of the product by carbon, oxygen and other gases. * Va ...
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Exothermic
In thermodynamics, an exothermic process () is a thermodynamic process or reaction that releases energy from the system to its surroundings, usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity (e.g. a battery), or sound (e.g. explosion heard when burning hydrogen). The term ''exothermic'' was first coined by 19th-century French chemist Marcellin Berthelot. The opposite of an exothermic process is an endothermic process, one that absorbs energy usually in the form of heat. The concept is frequently applied in the physical sciences to chemical reactions where chemical bond energy is converted to thermal energy (heat). Two types of chemical reactions Exothermic and endothermic describe two types of chemical reactions or systems found in nature, as follows: Exothermic After an exothermic reaction, more energy has been released to the surroundings than was absorbed to initiate and maintain the reaction. An example would be the burn ...
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