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Iranite
Iranite (Persian: ایرانیت) is a triclinic lead copper chromate silicate mineral with formula Pb10Cu(CrO4)6(SiO4)2(F,OH)2. It was first described from an occurrence in Iran. It is the copper analogue of hemihedrite (Pb10Zn(CrO4)6(SiO4)2(F,OH)2). It occurs as an oxidation product of hydrothermal lead-bearing veins. Associated minerals include dioptase, fornacite, wulfenite, mimetite, cerussite and diaboleite. It was first described in 1970 for an occurrence in the Sebarz Mine, northeast of Anarak, Iran Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkmeni .... References Tectosilicates {{silicate-mineral-stub ...
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Silicate Mineral
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphism (materials science), polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this carbonate–silicate cycle, geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous e ...
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Oxidation
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogenation, C=C (and other) bonds ar ...
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Diaboleite
Diaboleite is a blue-colored mineral with formula Pb2CuCl2(OH)4. It was discovered in England in 1923 and named ''diaboleite'', from the Greek word διά and boleite, meaning "distinct from boleite". The mineral has since been found in a number of countries. Description Diaboleite is deep blue in color and pale blue in transmitted light. The mineral occurs as tabular crystals up to in size, as subparallel aggregates, or it has massive habit. Vicinal forms of the tabular crystals have a square or octagonal outline and rarely exhibit pyramidal hemihedralism. Formation Diaboleite occurs in manganese oxide ores, as a secondary mineral in lead and copper oxide ores, and in seawater-exposed slag. Diaboleite has been found in association with atacamite, boleite, caledonite, cerussite, chloroxiphite, hydrocerussite, leadhillite, mendipite, paratacamite, phosgenite, and wherryite. A study in 1986 synthesized diaboleite crystals up to in size using two different methods. The study de ...
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Cerussite
Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate (PbCO3), and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was mentioned by Conrad Gessner in 1565, and in 1832 F. S. Beudant applied the name ''céruse'' to the mineral, whilst the present form, cerussite, is due to W. Haidinger (1845). Miners' names in early use were lead-spar and white-lead-ore. Cerussite crystallizes in the orthorhombic crystal system and is isomorphous with aragonite. Like aragonite it is very frequently twinned, the compound crystals being pseudo-hexagonal in form. Three crystals are usually twinned together on two faces of the prism, producing six-rayed stellate groups with the individual crystals intercrossing at angles of nearly 60°. Crystals are of frequent occurrence and they usually have very bright and smooth faces. The mineral also occurs in compact granular masses, and sometimes in fibrous fo ...
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Mimetite
Mimetite is a lead arsenate chloride mineral (Pb5(AsO4)3Cl) which forms as a secondary mineral in lead deposits, usually by the oxidation of galena and arsenopyrite. The name derives from the Greek Μιμητής ''mimetes'', meaning "imitator" and refers to mimetite's resemblance to the mineral pyromorphite. This resemblance is not coincidental, as mimetite forms a mineral series with pyromorphite () and with vanadinite (). Notable occurrences are Mapimi, Durango, Mexico and Tsumeb, Namibia. Properties Mimetite is a lead chloride arsenate mineral with the composition . It is a secondary mineral, formed by oxidation of primary lead minerals in arsenic-bearing lead deposits. It typically forms short hexagonal crystals that are yellow to brown to orange in color, very brittle, moderately hard (Mohs hardness 3.5-4), and dense (specific gravity 7.24). It is distinctive for its lack of transparency, its resinous to adamantine luster, and its solubility in nitric acid. Mimetite fo ...
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Wulfenite
Wulfenite is a lead molybdate mineral with the formula Pb Mo O4. It can be most often found as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form it is sometimes called "yellow lead ore". It crystallizes in the tetragonal system, often occurring as stubby, pyramidal or tabular crystals. It also occurs as earthy, granular masses. It is found in many localities, associated with lead ores as a secondary mineral associated with the oxidized zone of lead deposits. It is also a secondary ore of molybdenum, and is sought by collectors. Discovery and occurrence Wulfenite was first described in 1845 for an occurrence in Bad Bleiberg, Carinthia, Austria. It was named for Franz Xavier von Wulfen (1728–1805), an Austrian mineralogist. It occurs as a secondary mineral in oxidized hydrothermal lead deposits. It occurs with cerussite, anglesite, smithsonite, hemimorphite, vanadinite, pyromor ...
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Fornacite
Fornacite is a rare lead, copper chromate arsenate hydroxide mineral with the formula: Pb2Cu(CrO4)(AsO4)(OH). It forms a series with the phosphate mineral vauquelinite. It forms variably green to yellow, translucent to transparent crystals in the monoclinic - prismatic crystal system. It has a Mohs hardness of 2.3 and a specific gravity of 6.27. It was first described in 1915 and named after Lucien Lewis Forneau (1867–1930) the governor of the French Congo. Its type locality is in Reneville, Republic of Congo. It occurs in the oxidized zone of ore deposits and is associated with dioptase, wulfenite, hemihedrite, phoenicochroite, duftite, mimetite, shattuckite, chrysocolla, hemimorphite, willemite and fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs sca .... References ...
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Dioptase
Dioptase is an intense emerald-green to bluish-green copper cyclosilicate mineral. It is transparent to translucent. Its luster is vitreous to sub- adamantine. Its formula is Cu6Si6O18·6H2O (also reported as CuSiO2(OH)2). It has a hardness of 5, the same as tooth enamel. Its specific gravity is 3.28–3.35, and it has two perfect and one very good cleavage directions. Additionally, dioptase is very fragile, and specimens must be handled with great care. It is a trigonal mineral, forming 6-sided crystals that are terminated by rhombohedra. It is popular with mineral collectors and is sometimes cut into small gems. It can also be ground up and used as a pigment for painting. History Dioptase was used to highlight the edges of the eyes on the three Pre-Pottery Neolithic B lime plaster statues discovered at ' Ain Ghazal known as Micah, Heifa and Noah. These sculptures date back to about 7200 BC. Late in the 18th century, copper miners at the Altyn-Tyube (Altyn-Tube) mine, Karaga ...
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Vein (geology)
In geology, a vein is a distinct sheetlike body of crystallized minerals within a rock. Veins form when mineral constituents carried by an aqueous solution within the rock mass are deposited through precipitation. The hydraulic flow involved is usually due to hydrothermal circulation. Veins are classically thought of as being the ones in the body not the rock veins and arteries planar fractures in rocks, with the crystal growth occurring normal to the walls of the cavity, and the crystal protruding into open space. This certainly is the method for the formation of some veins. However, it is rare in geology for significant open space to remain open in large volumes of rock, especially several kilometers below the surface. Thus, there are two main mechanisms considered likely for the formation of veins: ''open-space filling'' and ''crack-seal growth''. Open space filling Open space filling is the hallmark of epithermal vein systems, such as a stockwork, in greisens or in cert ...
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Hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with the assistance of. Roderick McKenzie.'' Oxford: Clarendon Press. and θέρμη, ''heat'' ). Hydrothermal circulation occurs most often in the vicinity of sources of heat within the Earth's crust. In general, this occurs near volcanic activity, but can occur in the shallow to mid crust along deeply penetrating fault irregularities or in the deep crust related to the intrusion of granite, or as the result of orogeny or metamorphism. Seafloor hydrothermal circulation Hydrothermal circulation in the oceans is the passage of the water through mid-oceanic ridge systems. The term includes both the circulation of the well-known, high-temperature vent waters near the ridge crests, and the much-lower-temperature, diffuse flow of water through sedim ...
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Hemihedrite
Hemihedrite is a rare lead zinc chromate silicate mineral with formula Pb10Zn(CrO4)6(SiO4)2(F,OH)2. It forms a series with the copper analogue iranite. Discovery and occurrence Hemihedrite was first described in 1967 for occurrences in the Florence lead silver mine in the Ripsey District, Tortilla Mountains, Pinal County, Arizona, US. It was named for the hemihedral morphology of its crystals. It occurs in oxidized veins containing galena, sphalerite and pyrite. Associated secondary minerals include cerussite, phoenicochroite, vauquelinite, willemite, wulfenite, galena, sphalerite, pyrite, tennantite and chalcopyrite. It has been reported from several mining districts in Arizona and one in Nevada. It has also been reported from the Antofagasta Region of Chile and the Anarak District of Esfahan Province, Iran Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the ...
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