Hofmann Voltameter
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Hofmann Voltameter
A Hofmann voltameter is an apparatus for electrolysing water, invented by August Wilhelm von Hofmann (1818–1892) in 1866. It consists of three joined upright cylinders, usually glass. The inner cylinder is open at the top to allow addition of water which contains a low concentration of a compound such as sulfuric acid to improve conductivity and complete the circuit . A platinum electrode is placed inside the bottom of each of the two side cylinders, connected to the positive and negative terminals of a source of electricity. When current is run through Hofmann's voltameter, gaseous oxygen forms at the anode and gaseous hydrogen at the cathode. Each gas displaces water and collects at the top of the two outer tubes. The tubes which collect the product gases are usually graduated, so that the volume of gas can be measured. Name The name ' voltameter' was coined by Daniell, who shortened Faraday's original name of "volta-electrometer". Hofmann voltameters are no longer used ...
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Hofmann Voltameter Fr
Hoffman is a surname of Germany, German and Jews, Jewish origin. The original meaning in medieval times was "steward", i.e. one who manages the property of another. In English language, English and other European languages, including Yiddish and Dutch language, Dutch, the name can also be spelled Hoffmann, Hofmann (surname), Hofmann, Hofman, Huffman (other), Huffman, Hofmans. People with the surname A * Aaron Hoffman (1880–1944), American writer, director and comedian * Abbie Hoffman (1936–1989), American social activist of prominence in the 1960s and 1970s * Abraham Hoffman (1938–2015), Israeli basketball player * Al Hoffman (1902–1960), Russian-born American songwriter * Cloudant, Alan Hoffman (born 1982), American entrepreneur * Albert Hofmann (1906–2008), Swiss chemist and discoverer of LSD * Alex Hoffman-Ellis (born 1989), American football player * Alice Hoffman (born 1952), American author * Anthony Hoffman (1739–1790), New York politician * Arthur Su ...
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Ammeter
An ammeter (abbreviation of ''Ampere meter'') is an instrument used to measure the current in a circuit. Electric currents are measured in amperes (A), hence the name. For direct measurement, the ammeter is connected in series with the circuit in which the current is to be measured. An ammeter usually has low resistance so that it does not cause a significant voltage drop in the circuit being measured. Instruments used to measure smaller currents, in the milliampere or microampere range, are designated as ''milliammeters'' or ''microammeters''. Early ammeters were laboratory instruments that relied on the Earth's magnetic field for operation. By the late 19th century, improved instruments were designed which could be mounted in any position and allowed accurate measurements in electric power systems. It is generally represented by letter 'A' in a circuit. History The relation between electric current, magnetic fields and physical forces was first noted by Hans Christian Ør ...
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Electrolytic Cells
An electrolytic cell is an electrochemical cell that utilizes an external source of electrical energy to force a chemical reaction that would not otherwise occur. The external energy source is a voltage applied between the cell′s two electrodes; an anode (positively charged electrode) and a cathode (negatively charged electrode), which are immersed in an electrolyte solution. This is in contrast to a galvanic cell, which itself is a source of electrical energy and the foundation of a battery. The net reaction taking place in a galvanic cell is a spontaneous reaction, i.e, the Gibbs free energy remains -ve, while the net reaction taking place in an electrolytic cell is the reverse of this spontaneous reaction, i.e, the Gibbs free energy is +ve.Skoog, Douglas A.; West, Donald M.; Holler, F. James; Crouch, Stanley R. (2014). ''Fundamentals of Analytical Chemistry.'' (9th ed.)''.'' Belmont: Brooks/Cole, Cengage Learning. p. 446-449. Principles In an electrolytic cell, a current ...
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Electrolysis Of Water
Electrolysis of water, also known as electrochemical water splitting, is the process of using electricity to decompose water into oxygen and hydrogen gas by electrolysis. Hydrogen gas released in this way can be used as hydrogen fuel, or remixed with the oxygen to create oxyhydrogen gas, which is used in welding and other applications. Electrolysis of water requires a minimum potential difference of 1.23 volts, though at that voltage external heat is required. E lectrolysis is rarely used in industrial applications since hydrogen can be produced less expensively from fossil fuels. History In 1789, Jan Rudolph Deiman and Adriaan Paets van Troostwijk used an electrostatic machine to make electricity that was discharged on gold electrodes in a Leyden jar with water. In 1800 Alessandro Volta invented the voltaic pile, and a few weeks later English scientists William Nicholson and Anthony Carlisle used it to electrolyse water. In 1806 Humphry Davy reported the results of ext ...
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Timeline Of Hydrogen Technologies
This is a timeline of the history of hydrogen technology. Timeline 16th century * c. 1520 – First recorded observation of hydrogen by Paracelsus through dissolution of metals (iron, zinc, and tin) in sulfuric acid. 17th century * 1625 – First description of hydrogen by Johann Baptista van Helmont. First to use the word "gas". * 1650 – Turquet de Mayerne obtained a gas or "inflammable air" by the action of dilute sulphuric acid on iron. * 1662 – Boyle's law (gas law relating pressure and volume) * 1670 – Robert Boyle produced hydrogen by reacting metals with acid. * 1672 – "New Experiments touching the Relation between Flame and Air" by Robert Boyle. * 1679 – Denis Papin – safety valve * 1700 – Nicolas Lemery showed that the gas produced in the sulfuric acid/iron reaction was explosive in air 18th century * 1755 – Joseph Black confirmed that different gases exist. / Latent heat * 1766 – Henry Cavendish published in "On Factitious Airs" a description of " ...
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Stoichiometry
Stoichiometry refers to the relationship between the quantities of reactants and products before, during, and following chemical reactions. Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the total mass of the products, leading to the insight that the relations among quantities of reactants and products typically form a ratio of positive integers. This means that if the amounts of the separate reactants are known, then the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of the products can be empirically determined, then the amount of the other reactants can also be calculated. This is illustrated in the image here, where the balanced equation is: : Here, one molecule of methane reacts with two molecules of oxygen gas to yield one molecule of carbon dioxide and two molecules of water. This particular chemical equation is an example of complete combustion. St ...
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Thomas Edison
Thomas Alva Edison (February 11, 1847October 18, 1931) was an American inventor and businessman. He developed many devices in fields such as electric power generation, mass communication, sound recording, and motion pictures. These inventions, which include the phonograph, the motion picture camera, and early versions of the electric light bulb, have had a widespread impact on the modern industrialized world. He was one of the first inventors to apply the principles of organized science and teamwork to the process of invention, working with many researchers and employees. He established the first industrial research laboratory. Edison was raised in the American Midwest. Early in his career he worked as a telegraph operator, which inspired some of his earliest inventions. In 1876, he established his first laboratory facility in Menlo Park, New Jersey, where many of his early inventions were developed. He later established a botanical laboratory in Fort Myers, Florida, in co ...
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Coulometer
A voltameter or coulometer is a scientific instrument used for measuring electric charge (quantity of electricity) through electrolytic action. The SI unit of electric charge is the coulomb. The voltameter should not be confused with a voltmeter, which measures electric potential. The SI unit for electric potential is the volt. Types of voltameter The voltameter is an electrolytic cell and the measurement is made by weighing the element deposited or released at the cathode in a specified time. Silver voltameter This is the most accurate type. It consists of two silver plates in a solution of silver nitrate. When current is flowing, silver dissolves at the anode and is deposited at the cathode. The cathode is initially massed, current is passed for a measured time and the cathode is massed again. Copper coulometer This is similar to the silver voltameter but the anode and cathode are copper and the solution is copper sulfate, acidified with sulfuric acid. It is cheaper tha ...
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Faraday's Law Of Electrolysis
Faraday's laws of electrolysis are quantitative relationships based on the electrochemical research published by Michael Faraday in 1833. First law Michael Faraday reported that the mass (m) of elements deposited at an electrode is directly proportional to the charge (Q; SI units are ampere seconds or coulombs). \begin m &\propto Q \\ \implies \frac &= Z \end Here, the constant of proportionality, Z, is called the electro-chemical equivalent (e.c.e) of the substance. Thus, the e.c.e. can be defined as the mass of the substance deposited/liberated per unit charge. Second law Faraday discovered that when the same amount of electric current is passed through different electrolytes/elements connected in series, the mass of the substance liberated/deposited at the electrodes is directly proportional to their chemical equivalent/equivalent weight (E). This turns out to be the molar mass (M) divided by the valence (v) : m \propto E : E = \frac : \implies m_1 : m_2 : m_3 : ... ...
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Electroplating
Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the reduction of cations of that metal by means of a direct electric current. The part to be coated acts as the cathode (negative electrode) of an electrolytic cell; the electrolyte is a solution of a salt of the metal to be coated; and the anode (positive electrode) is usually either a block of that metal, or of some inert conductive material. The current is provided by an external power supply. Electroplating is widely used in industry and decorative arts to improve the surface qualities of objects—such as resistance to abrasion and corrosion, lubricity, reflectivity, electrical conductivity, or appearance. It is used to build up thickness on undersized or worn-out parts, or to manufacture metal plates with complex shape, a process called electroforming. It is used to deposit copper and other conductors in forming printe ...
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Copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form ( native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create ...
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Iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in front of oxygen (32.1% and 30.1%, respectively), forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust. In its metallic state, iron is rare in the Earth's crust, limited mainly to deposition by meteorites. Iron ores, by contrast, are among the most abundant in the Earth's crust, although extracting usable metal from them requires kilns or furnaces capable of reaching or higher, about higher than that required to smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BCE and the use of iron tools and weapons began to displace copper alloys, in some regions, only around 1200 BCE. That event is considered the transition from the Bronze Age to the Iron A ...
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