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HETP
A theoretical plate in many separation processes is a hypothetical zone or stage in which two phases, such as the liquid and vapor phases of a substance, establish an equilibrium with each other. Such equilibrium stages may also be referred to as an equilibrium stage, ideal stage, or a theoretical tray. The performance of many separation processes depends on having series of equilibrium stages and is enhanced by providing more such stages. In other words, having more theoretical plates increases the efficiency of the separation process be it either a distillation, absorption, chromatographic, adsorption or similar process. Applications The concept of theoretical plates and trays or equilibrium stages is used in the design of many different types of separation. Distillation columns The concept of theoretical plates in designing distillation processes has been discussed in many reference texts. Any physical device that provides good contact between the vapor and liquid phases pres ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Van Deemter Equation
The van Deemter equation in chromatography, named for Jan van Deemter, relates the variance per unit length of a separation column to the linear mobile phase velocity by considering physical, kinetic, and thermodynamic properties of a separation. These properties include pathways within the column, diffusion ( axial and longitudinal), and mass transfer kinetics between stationary and mobile phases. In liquid chromatography, the mobile phase velocity is taken as the exit velocity, that is, the ratio of the flow rate in ml/second to the cross-sectional area of the ‘column-exit flow path.’ For a packed column, the cross-sectional area of the column exit flow path is usually taken as 0.6 times the cross-sectional area of the column. Alternatively, the linear velocity can be taken as the ratio of the column length to the dead time. If the mobile phase is a gas, then the pressure correction must be applied. The variance per unit length of the column is taken as the ratio of the co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Packed Bed
In chemical processing, a packed bed is a hollow tube, pipe, or other vessel that is filled with a packing material. The packing can be randomly filled with small objects like Raschig rings or else it can be a specifically designed structured packing. Packed beds may also contain catalyst particles or adsorbents such as zeolite pellets, granular activated carbon, etc. The purpose of a packed bed is typically to improve contact between two phases in a chemical or similar process. Packed beds can be used in a chemical reactor, a distillation process, or a scrubber, but packed beds have also been used to store heat in chemical plants. In this case, hot gases are allowed to escape through a vessel that is packed with a refractory material until the packing is hot. Air or other cool gas is then fed back to the plant through the hot bed, thereby pre-heating the air or gas feed. Applications Packed column In industry, a packed column is a type of packed bed used to perform s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Continuous Distillation
Continuous distillation, a form of distillation, is an ongoing separation in which a mixture is continuously (without interruption) fed into the process and separated fractions are removed continuously as output streams. Distillation is the separation or partial separation of a liquid feed mixture into components or fractions by selective boiling (or evaporation) and condensation. The process produces at least two output fractions. These fractions include at least one '' volatile'' distillate fraction, which has boiled and been separately captured as a vapor condensed to a liquid, and practically always a ''bottoms'' (or ''residuum'') fraction, which is the least volatile residue that has not been separately captured as a condensed vapor. An alternative to continuous distillation is batch distillation, where the mixture is added to the unit at the start of the distillation, distillate fractions are taken out sequentially in time (one after another) during the distillation, and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Distillation
Distillation, or classical distillation, is the process of separation process, separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the heating of solid materials to produce gaseous products (which may condense into liquids or solids); this may involve chemical changes such as destructive distillation or Cracking (chemistry), cracking. Distillation may result in essentially complete separation (resulting in nearly pure components), or it may be a partial separation that increases the concentration of selected components; in either case, the process exploits differences in the relative volatility of the mixture's components. In Chemical industry, industrial applications, distillation is a unit operation of practically universal importance, but is a physical separation process, not a chemical reaction. An installation used for distillation, especially of distilled ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Distillation Design
''Distillation Design'' is a book which provides complete coverage of the design of industrial distillation columns for the petroleum refining, chemical and petrochemical plants, natural gas processing, pharmaceutical, food and alcohol distilling industries. It has been a classical chemical engineering textbook since it was first published in February 1992. The subjects covered in the book include: *''Vapor–liquid equilibrium(VLE)'': Vapor–liquid K values, relative volatilities, ideal and non-ideal systems, phase diagrams, calculating bubble points and dew points *''Key fractional distillation concepts'': theoretical stages, x-y diagrams, multicomponent distillation, column composition and temperature profiles *''Process design and optimization'': minimum reflux and minimum stages, optimum reflux, short-cut methods, feed entry location *''Rigorous calculation methods'': Bubble point method, sum rates method, numerical methods (Newton–Raphson technique), inside out metho ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Separation Process
A separation process is a method that converts a mixture or a solution (chemistry), solution of chemical substances into two or more distinct product mixtures, a scientific process of separating two or more substance in order to obtain purity. At least one product mixture from the separation is enriched in one or more of the source mixture's constituents. In some cases, a separation may fully divide the mixture into pure constituents. Separations exploit differences in chemical properties or physical properties (such as size, shape, mass, density, or chemical affinity) between the constituents of a mixture. Processes are often classified according to the particular properties they exploit to achieve separation. If no single difference can be used to accomplish the desired separation, multiple unit operation, operations can often be combined to achieve the desired end. With a few exceptions, chemical element, elements or Chemical compound, compounds exist in nature in an impure ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Richard Laurence Millington Synge
Richard Laurence Millington Synge FRS FRSE FRIC FRSC MRIA (Liverpool, 28 October 1914 – Norwich, 18 August 1994) was a British biochemist, and shared the 1952 Nobel Prize in Chemistry for the invention of partition chromatography with Archer Martin. Life Richard Laurence Millington Synge was born in West Kirby on 28 October 1914, the son of Lawrence Millington Synge, a Liverpool stock-broker, and his wife, Katherine C. Swan. Synge was educated at the Old Hall in Wellington, Shropshire and at Winchester College. He then studied Chemistry at Trinity College, Cambridge. He spent his entire career in research, at the Wool Industries Research Association, Leeds (1941–1943), Lister Institute for Preventive Medicine, London (1943–1948), Rowett Research Institute, Aberdeen (1948–1967), and Food Research Institute, Norwich (1967–1976). It was during his time in Leeds that he worked with Archer Martin, developing partition chromatography, a technique used in the separation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Structured Packing
The term structured packing refers to a range of specially designed materials for use in absorption and distillation columns and chemical reactors. Structured packings typically consist of thin corrugated metal plates or gauzes arranged in a way that force fluids to take complicated paths through the column, thereby creating a large surface area for contact between different phases. Structured packing is formed from corrugated sheets of perforated embossed metal, plastic (including PTFE) or wire gauze. The result is a very open honeycomb structure with inclined flow channels giving a relatively high surface area but with very low resistance to gas flow. The surface enhancements have been chosen to maximize liquid spreading. These characteristics tend to show significant performance benefits in low pressure and low irrigation rate applications. History Structured packings have been established for several decades. The first generation of structured packing arose in the early ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mass Transfer
Mass transfer is the net movement of mass from one location (usually meaning stream, phase, fraction or component) to another. Mass transfer occurs in many processes, such as absorption, evaporation, drying, precipitation, membrane filtration, and distillation. Mass transfer is used by different scientific disciplines for different processes and mechanisms. The phrase is commonly used in engineering for physical processes that involve diffusive and convective transport of chemical species within physical systems. Some common examples of mass transfer processes are the evaporation of water from a pond to the atmosphere, the purification of blood in the kidneys and liver, and the distillation of alcohol. In industrial processes, mass transfer operations include separation of chemical components in distillation columns, absorbers such as scrubbers or stripping, adsorbers such as activated carbon beds, and liquid-liquid extraction. Mass transfer is often coupled to additional tr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Archer John Porter Martin
Archer John Porter Martin (1 March 1910 – 28 July 2002) was a British chemist who shared the 1952 Nobel Prize in Chemistry for the invention of partition chromatography with Richard Synge. Early life Martin's father was a GP. Martin was educated at Bedford School, and Peterhouse, Cambridge. Career Working first in the Physical Chemistry Laboratory, he moved to the Dunn Nutritional Laboratory, and in 1938 moved to Wool Industries Research Institution in Leeds. He was head of the biochemistry division of Boots Pure Drug Company from 1946 to 1948, when he joined the Medical Research Council. There, he was appointed head of the physical chemistry division of the National Institute for Medical Research in 1952, and was chemical consultant from 1956 to 1959. He specialised in biochemistry, in some aspects of vitamins E and B2, and in techniques that laid the foundation for several new types of chromatography. He developed partition chromatography whilst working on the separati ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Capillary Electrophoresis
Capillary electrophoresis (CE) is a family of electrokinetic separation methods performed in submillimeter diameter capillaries and in micro- and nanofluidic channels. Very often, CE refers to capillary zone electrophoresis (CZE), but other electrophoretic techniques including capillary gel electrophoresis (CGE), capillary isoelectric focusing (CIEF), capillary isotachophoresis and micellar electrokinetic chromatography (MEKC) belong also to this class of methods. In CE methods, analytes migrate through electrolyte solutions under the influence of an electric field. Analytes can be separated according to ionic mobility and/or partitioning into an alternate phase via non-covalent interactions. Additionally, analytes may be concentrated or "focused" by means of gradients in conductivity and pH. Instrumentation The instrumentation needed to perform capillary electrophoresis is relatively simple. A basic schematic of a capillary electrophoresis system is shown in ''figure 1''. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
IUPAC
The International Union of Pure and Applied Chemistry (IUPAC ) is an international federation of National Adhering Organizations working for the advancement of the chemical sciences, especially by developing nomenclature and terminology. It is a member of the International Science Council (ISC). IUPAC is registered in Zürich, Switzerland, and the administrative office, known as the "IUPAC Secretariat", is in Research Triangle Park, North Carolina, United States. This administrative office is headed by IUPAC's executive director, currently Lynn Soby. IUPAC was established in 1919 as the successor of the International Congress of Applied Chemistry for the advancement of chemistry. Its members, the National Adhering Organizations, can be national chemistry societies, national academies of sciences, or other bodies representing chemists. There are fifty-four National Adhering Organizations and three Associate National Adhering Organizations. IUPAC's Inter-divisional Committee on ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
