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Hooker Reaction
In the Hooker reaction (1936) an alkyl chain in a certain naphthoquinone (phenomenon first observed in the compound lapachol) is reduced by one methylene unit as carbon dioxide in each potassium permanganate oxidation.''On the Oxidation of 2-Hydroxy-1,4-naphthoquinone Derivatives with Alkaline Potassium Permanganate. Part II. Compounds with Unsaturated Side'' Chains Samuel C. Hooker and Al Steyermark J. Am. Chem. Soc. 1936; 58(7); pp 1179–81; : :Mechanistically oxidation causes ring-cleavage at the alkene group, extrusion of carbon dioxide in decarboxylation Decarboxylation is a chemical reaction that removes a carboxyl group and releases carbon dioxide (CO2). Usually, decarboxylation refers to a reaction of carboxylic acids, removing a carbon atom from a carbon chain. The reverse process, which is t ... with subsequent ring-closure. : References {{reflist Organic reactions Name reactions Degradation reactions Homologation reactions ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Naphthoquinone
Naphthoquinones constitute a class of organic compounds structurally related to naphthalene. Two isomers are common for the parent naphthoquinones: * 1,2-Naphthoquinone * 1,4-Naphthoquinone Natural products * Alkannin * Hexahydroxy-1,4-naphthalenedione * Juglone * Lapachol * Lawsone * Menatetrenone * 2-Methoxy-1,4-naphthoquinone, a compound found in ''Impatiens'' species * Nigrosporin B * 2,3,5,6,8-Pentahydroxy-1,4-naphthalenedione * Phylloquinone * Plumbagin * 2,3,5,7-Tetrahydroxy-1,4-naphthalenedione * Vitamin K and related compounds Synthetic naphthoquinones * Menadione (2-Methyl-1,4-naphthoquinone), a vitamin K mimic * 5,8-Dihydroxy-1,4-naphthoquinone and dihydroxynaphthoquinones * Atovaquone * Buparvaquone, an antiprotozoal drug used in veterinary medicine * Diazonaphthoquinone, a diazo derivative of naphthoquinone * 1,2-Naphthoquinone, from the biodegradation of naphthalene. See also * Hydroxynaphthoquinone A hydroxynaphthoquinone (formula: ) is any of sever ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lapachol
Lapachol is a natural phenolic compound isolated from the bark of the lapacho tree.Record, Samuel J.. "Lapachol" pages 17-19. In: ''Tropical Woods'' (1925). This tree is known botanically as ''Handroanthus impetiginosus'', but was formerly known by various other botanical names such as ''Tabebuia avellanedae''. Lapachol is also found in other species of ''Handroanthus''. Lapachol is usually encountered as a yellow, skin-irritating powder from wood. Chemically, it is a derivative of vitamin K Vitamin K refers to structurally similar, fat-soluble vitamers found in foods and marketed as dietary supplements. The human body requires vitamin K for post-synthesis modification of certain proteins that are required for blood coagulation ....Louis F.Fieser. ''The Scientific Method'' pages 163-191. Reinhold Publishing Corporation, New York, 1964 Once studied as a possible treatment for some types of cancer, it is now considered too toxic for use. See also * Hooker reaction R ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methylene (compound)
Methylene (systematically named methylidene and dihydridocarbon; also called carbene) is an organic compound with the chemical formula (also written ). It is a colourless gas that fluoresces in the mid-infrared range, and only persists in dilution, or as an adduct. Methylene is the simplest carbene.Roald Hoffman (2005), ''Molecular Orbitals of Transition Metal Complexes''. Oxford. It is usually detected only at very low temperatures, or as a short-lived intermediate in chemical reactions. W. B. DeMore and S. W. Benson (1964), Preparation, properties, and reactivity of methylene'. In ''Advances in Photochemistry'', John Wiley & Sons, 453 pages. Nomenclature The trivial name ''carbene'' is the preferred IUPAC name. The systematic names ''methylidene'' and ''dihydridocarbon'', valid IUPAC names, are constructed according to the substitutive and additive nomenclatures, respectively. ''Methylidene'' is viewed as methane with two hydrogen atoms removed. By default, this name ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. It is a trace gas in Earth's atmosphere at 421 parts per million (ppm), or about 0.04% by volume (as of May 2022), having risen from pre-industrial levels of 280 ppm. Burning fossil fuels is the primary cause of these increased CO2 concentrations and also the primary cause of climate change.IPCC (2022Summary for policy makersiClimate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Permanganate
Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, that dissolves in water as K+ and , an intensely pink to purple solution. Potassium permanganate is widely used in the chemical industry and laboratories as a strong oxidizing agent, and also as a medication for dermatitis, for cleaning wounds, and general disinfection. It is on the World Health Organization's List of Essential Medicines. In 2000, worldwide production was estimated at 30,000 tonnes. Properties Potassium permanganate is the potassium salt of the tetrahedral transition metal oxo complex permanganate, in which four O2- ligands are bound to a manganese(VII) center. Structure KMnO4 forms orthorhombic crystals with constants: ''a'' = 910.5 pm, ''b'' = 572.0 pm, ''c'' = 742.5 pm. The overall motif is similar to that for barium sulfate, with which it forms solid solutions. In the solid (as in solution), each MnO4− centre is t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Oxidation
Organic reductions or organic oxidations or organic redox reactions are redox reactions that take place with organic compounds. In organic chemistry oxidations and reductions are different from ordinary redox reactions, because many reactions carry the name but do not actually involve electron transfer.March Jerry; (1985). Advanced Organic Chemistry reactions, mechanisms and structure (3rd ed.). New York: John Wiley & Sons, inc. Instead the relevant criterion for organic oxidation is gain of oxygen and/or loss of hydrogen, respectively.''Organic Redox Systems: Synthesis, Properties, and Applications'', Tohru Nishinaga 2016 Simple functional groups can be arranged in order of increasing oxidation state. The oxidation numbers are only an approximation: When methane is oxidized to carbon dioxide its oxidation number changes from −4 to +4. Classical reductions include alkene reduction to alkanes and classical oxidations include oxidation of alcohols to aldehydes. In oxidations ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Updated Hooker Reaction , also known as a software update
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Update(s) or Updated may refer to: Music * ''Update'' (Anouk album), 2004 * ''Update'' (Berlin Jazz Orchestra album), 2004 * ''Update'' (Jane Zhang album), 2007 * ''Update'' (Mal Waldron album), 1987 * ''Update'' (Yandel album), 2017 * ''Updated'' (M. Pokora album), an English-language version of ''Mise à jour'', 2011 Other uses * Update (SQL), a statement for changing database records * ''Updates'', a program broadcast by CNN Philippines See also * Patch (computing) A patch is a set of changes to a computer program or its supporting data designed to update, fix, or improve it. This includes fixing security vulnerabilities and other bugs, with such patches usually being called bugfixes or bug fixes. Patche ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Decarboxylation
Decarboxylation is a chemical reaction that removes a carboxyl group and releases carbon dioxide (CO2). Usually, decarboxylation refers to a reaction of carboxylic acids, removing a carbon atom from a carbon chain. The reverse process, which is the first chemical step in photosynthesis, is called carboxylation, the addition of CO2 to a compound. Enzymes that catalyze decarboxylations are called decarboxylases or, the more formal term, carboxy-lyases (Enzyme Commission number, EC number 4.1.1). In organic chemistry The term "decarboxylation" usually means replacement of a carboxyl group () with a hydrogen atom: :RCO2H -> RH + CO2 Decarboxylation is one of the oldest known organic reactions. It is one of the processes assumed to accompany pyrolysis and destructive distillation. Metal salts, especially copper compounds, facilitate the reaction via the intermediacy of metal carboxylate complexes. Decarboxylation of aryl carboxylates can generate the equivalent of the correspond ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hooker Oxidation Mechanismus-v6
Hooker may refer to: People * Hooker (surname) Places Antarctica * Mount Hooker (Antarctica) * Cape Hooker (Antarctica) * Cape Hooker (South Shetland Islands) New Zealand * Hooker River * Mount Hooker (New Zealand) in the Southern Alps * Hooker Glacier (New Zealand), in the Southern Alps United States * Hooker, California, an unincorporated community * Hooker, Georgia, an unincorporated community * Little Goose Creek (Kentucky), location of Hooker post office and river branch * Hooker, Missouri, a ghost town * Hooker, Ohio, an unincorporated community * Hooker, Oklahoma, a city * Hooker, South Dakota, an unincorporated community * Hooker County, Nebraska * Hooker Township, Dixon County, Nebraska * Hooker Township, Gage County, Nebraska * Hooker Dam, a proposed dam on the Gila River in New Mexico * Hooker Falls, North Carolina * Mount Hooker (Wyoming) Elsewhere * Mount Hooker (Canada), a mountain on the Continental Divide and border between British Columbia and Alberta, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Reactions
Organic reactions are chemical reactions involving organic compounds. The basic organic chemistry reaction types are addition reactions, elimination reactions, substitution reactions, pericyclic reactions, rearrangement reactions, photochemical reactions and redox reactions. In organic synthesis, organic reactions are used in the construction of new organic molecules. The production of many man-made chemicals such as drugs, plastics, food additives, fabrics depend on organic reactions. The oldest organic reactions are combustion of organic fuels and saponification of fats to make soap. Modern organic chemistry starts with the Wöhler synthesis in 1828. In the history of the Nobel Prize in Chemistry awards have been given for the invention of specific organic reactions such as the Grignard reaction in 1912, the Diels-Alder reaction in 1950, the Wittig reaction in 1979 and olefin metathesis in 2005. Classifications Organic chemistry has a strong tradition of naming a specific reac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Name Reactions
A name reaction is a chemical reaction named after its discoverers or developers. Among the tens of thousands of organic reactions that are known, hundreds of such reactions are well-known enough to be named after people. Well-known examples include the Grignard reaction, the Sabatier reaction, the Wittig reaction, the Claisen condensation, the Friedel-Crafts acylation, and the Diels-Alder reaction. Books have been published devoted exclusively to name reactions;Alfred Hassner, C. Stumer. ''Organic syntheses based on name reactions''. Elsevier, 2002. Li, Jie Jack. ''Name Reactions: A Collection of Detailed Reaction Mechanisms''. Springer, 2003. the Merck Index, a chemical encyclopedia, also includes an appendix on name reactions. As organic chemistry developed during the 20th century, chemists started associating synthetically useful reactions with the names of the discoverers or developers; in many cases, the name is merely a mnemonic. Some cases of reactions that were not reall ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Degradation Reactions
Degradation may refer to: Science * Degradation (geology), lowering of a fluvial surface by erosion * Degradation (telecommunications), of an electronic signal * Biodegradation of organic substances by living organisms * Environmental degradation in ecology * Land degradation, a process in which the value of the biophysical environment is affected by a combination of human-induced processes acting upon the land * Polymer degradation, as plastics age Other * Elegant degradation, gradual rather than sudden * Graceful degradation, in a fault-tolerant system * Degradation (knighthood), revocation of knighthood * Cashiering, whereby a military officer is dismissed for misconduct * Reduction in rank, whereby a military officer is reduced to a lower rank for misconduct * Degradation, the former ceremony of defrocking a disgraced priest * ''Degradation'', a song by the Violent Femmes, from ''Add It Up (1981–1993) ''Add It Up (1981–1993)'' is a compilation album released by Violent ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
