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History Of Entropy
The concept of entropy developed in response to the observation that a certain amount of functional energy released from combustion reactions is always lost to dissipation or friction and is thus not transformed into useful work. Early heat-powered engines such as Thomas Savery's (1698), the Newcomen engine (1712) and the Cugnot steam tricycle (1769) were inefficient, converting less than two percent of the input energy into useful work output; a great deal of useful energy was dissipated or lost. Over the next two centuries, physicists investigated this puzzle of lost energy; the result was the concept of entropy. In the early 1850s, Rudolf Clausius set forth the concept of the thermodynamic system and posited the argument that in any irreversible process a small amount of heat energy ''δQ'' is incrementally dissipated across the system boundary. Clausius continued to develop his ideas of lost energy, and coined the term ''entropy''. Since the mid-20th century the concept of e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Entropy
Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication. The thermodynamic concept was referred to by Scottish scientist and engineer William Rankine in 1850 with the names ''thermodynamic function'' and ''heat-potential''. In 1865, German physicist Rudolf Clausius, one of the leading founders of the field of thermodynamics, defined it as the quotient of an infinitesimal amount of hea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reflections On The Motive Power Of Fire
''Reflections on the Motive Power of Fire and on Machines Fitted to Develop that Power'' is a book published in 1824 by French physicist Sadi Carnot.full text of 1897 ed. ( Full text of 1897 edition on Wikisource ) The 118-page book's French title was ''Réflexions sur la puissance motrice du feu et sur les machines propres à développer cette puissance''. It is a significant publication in the history of thermodynamics about a generalized theory of heat engines. Overview The book is considered the founding work of thermodynamics. It contains the preliminary outline of the second law of thermodynamics. Carnot stated that motive power is due to the fall of caloric (heat) from a hot to a cold body. The work was unnoticed until 1834 when French mining engineer Émile Clapeyron put it on a graphical footing in his ''Memoir on the Motive Power of Heat''. Through Clapeyron's paper, German physicist Rudolf Clausius learned of Carnot's theory of heat and through a modification of Ca ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Absolute Temperature
Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics. Historically, thermodynamic temperature was defined by Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are now understood as manifestations of the kinetic energy of free motion of microscopic particles such as atoms, molecules, and electrons. From the thermodynamic viewpoint, for historical reasons, because of how it is defined and measured, this microscopic kinetic definition is regarded as an "empirical" temperature. It was adopted because in practice it can generally be measured more precisely than can Kelvin's thermodynamic temperature. A thermodynamic temperature reading of zero is of particular importance for the third law of thermodynamics. By convention, it is reported on the ''Kelvin scale'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mechanical Theory Of Heat
The history of thermodynamics is a fundamental strand in the history of physics, the history of chemistry, and the history of science in general. Owing to the relevance of thermodynamics in much of science and technology, its history is finely woven with the developments of classical mechanics, quantum mechanics, magnetism, and chemical kinetics, to more distant applied fields such as meteorology, information theory, and biology (physiology), and to technological developments such as the steam engine, internal combustion engine, cryogenics and electricity generation. The development of thermodynamics both drove and was driven by atomic theory. It also, albeit in a subtle manner, motivated new directions in probability and statistics; see, for example, the timeline of thermodynamics. History Contributions from antiquity The ancients viewed heat as that related to fire. In 3000 BC, the ancient Egyptians viewed heat as related to origin mythologies. The ancient Indian philosophy inc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Theory Of Heat
The history of thermodynamics is a fundamental strand in the history of physics, the history of chemistry, and the history of science in general. Owing to the relevance of thermodynamics in much of science and technology, its history is finely woven with the developments of classical mechanics, quantum mechanics, magnetism, and chemical kinetics, to more distant applied fields such as meteorology, information theory, and biology (physiology), and to technological developments such as the steam engine, internal combustion engine, cryogenics and electricity generation. The development of thermodynamics both drove and was driven by atomic theory. It also, albeit in a subtle manner, motivated new directions in probability and statistics; see, for example, the timeline of thermodynamics. History Contributions from antiquity The ancients viewed heat as that related to fire. In 3000 BC, the ancient Egyptians viewed heat as related to origin mythologies. The ancient Indian philosophy in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mechanical Equivalent Of Heat
In the history of science, the mechanical equivalent of heat states that motion and heat are mutually interchangeable and that in every case, a given amount of work would generate the same amount of heat, provided the work done is totally converted to heat energy. The mechanical equivalent of heat was a concept that had an important part in the development and acceptance of the conservation of energy and the establishment of the science of thermodynamics in the 19th century. History and priority dispute Benjamin Thompson, Count Rumford, had observed the frictional heat generated by boring cannon at the arsenal in Munich, Germany circa 1797. Rumford immersed a cannon barrel in water and arranged for a specially blunted boring tool. He showed that the water could be boiled within roughly two and a half hours and that the supply of frictional heat was seemingly inexhaustible. Based on his experiments, he published "An Experimental Enquiry Concerning the Source of the Heat which is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Clausius
Rudolf Julius Emanuel Clausius (; 2 January 1822 – 24 August 1888) was a German physicist and mathematician and is considered one of the central founding fathers of the science of thermodynamics. By his restatement of Sadi Carnot's principle known as the Carnot cycle, he gave the theory of heat a truer and sounder basis. His most important paper, "On the Moving Force of Heat", published in 1850, first stated the basic ideas of the second law of thermodynamics. In 1865 he introduced the concept of entropy. In 1870 he introduced the virial theorem, which applied to heat. Life Clausius was born in Köslin (now Koszalin, Poland) in the Province of Pomerania in Prussia. His father was a Protestant pastor and school inspector, and Rudolf studied in the school of his father. In 1838, he went to the Gymnasium in Stettin. Clausius graduated from the University of Berlin in 1844 where he had studied mathematics and physics since 1840 with, among others, Gustav Magnus, Peter Gustav Le ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carnot Cycle
A Carnot cycle is an ideal thermodynamic cycle proposed by French physicist Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. By Carnot's theorem, it provides an upper limit on the efficiency of any classical thermodynamic engine during the conversion of heat into work, or conversely, the efficiency of a refrigeration system in creating a temperature difference through the application of work to the system. In a Carnot cycle, a system or engine transfers energy in the form of heat between two thermal reservoirs at temperatures T_H and T_C (referred to as the hot and cold reservoirs, respectively), and a part of this transferred energy is converted to the work done by the system. The cycle is reversible, and there is no generation of entropy. (In other words, entropy is conserved; entropy is only transferred between the thermal reservoirs and the system without gain or loss of it.) When work is applied to the system, heat moves from the cold to hot reser ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat Engine
In thermodynamics and engineering, a heat engine is a system that converts heat to mechanical energy, which can then be used to do mechanical work. It does this by bringing a working substance from a higher state temperature to a lower state temperature. A heat source generates thermal energy that brings the working substance to the higher temperature state. The working substance generates work in the working body of the engine while transferring heat to the colder sink until it reaches a lower temperature state. During this process some of the thermal energy is converted into work by exploiting the properties of the working substance. The working substance can be any system with a non-zero heat capacity, but it usually is a gas or liquid. During this process, some heat is normally lost to the surroundings and is not converted to work. Also, some energy is unusable because of friction and drag. In general, an engine is any machine that converts energy to mechanical work. Heat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Working Fluid
For fluid power, a working fluid is a gas or liquid that primarily transfers force, motion, or mechanical energy. In hydraulics, water or hydraulic fluid transfers force between hydraulic components such as hydraulic pumps, hydraulic cylinders, and hydraulic motors that are assembled into hydraulic machinery, hydraulic drive systems, etc. In pneumatics, the working fluid is air or another gas which transfers force between pneumatic components such as compressors, vacuum pumps, pneumatic cylinders, and pneumatic motors. In pneumatic systems, the working gas also energy storage, stores energy because it is compressible. (Gases also heat up as they are compressed and cool as they expand; this incidental heat pump is rarely exploited.) (Some gases also condense into liquids as they are compressed and boil as pressure is reduced.) For passive heat transfer, a working fluid is a gas or liquid, usually called a coolant or heat transfer fluid, that primarily transfers heat into or out of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Temperature
Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied on various reference points and thermometric substances for definition. The most common scales are the Celsius scale with the unit symbol °C (formerly called ''centigrade''), the Fahrenheit scale (°F), and the Kelvin scale (K), the latter being used predominantly for scientific purposes. The kelvin is one of the seven base units in the International System of Units (SI). Absolute zero, i.e., zero kelvin or −273.15 °C, is the lowest point in the thermodynamic temperature scale. Experimentally, it can be approached very closely but not actually reached, as recognized in the third law of thermodynamics. It would be impossible to extract energy as heat from a body at that temperature. Temperature is important in all fields of natur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
