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Hafnium Diboride
Hafnium diboride belongs to the class of ultra-high-temperature ceramics, a type of ceramic composed of hafnium and boron. It has a melting temperature of about 3250 °C. It is an unusual ceramic, having relatively high thermal and electrical conductivities, properties it shares with isostructural titanium diboride and zirconium diboride. It is a grey, metallic looking material. Hafnium diboride has a hexagonal crystal structure, a molar mass of 200.11 grams per mole, and a density of ~10.5 g/cm3. Hafnium diboride is often combined with carbon, boron, silicon, silicon carbide, and/or nickel to improve the consolidation of the hafnium diboride powder (sintering). It is commonly formed into a solid by a process called hot pressing, where the powders are pressed together using both heat and pressure. The material has potential for use in hypervelocity reentry vehicles such as ICBM heat shields or aerodynamic leading-edges, due to its strength and thermal properties. Unlike ...
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Pearson Symbol
The Pearson symbol, or Pearson notation, is used in crystallography as a means of describing a crystal structure, and was originated by W. B. Pearson. The symbol is made up of two letters followed by a number. For example: * Diamond structure, ''cF''8 * Rutile structure, ''tP''6 The two (italicised) letters specify the Bravais lattice. The lower-case letter specifies the crystal family, and the upper-case letter the centering type. The number at the end of the Pearson symbol gives the number of the atoms in the conventional unit cell.Nomenclature of Inorganic Chemistry IUPAC Recommendations 2005
IR-3.4.4, pp. 49–51; IR-11.5, pp. 241–242.

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Nickel
Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide forms on the surface that prevents further corrosion. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks, and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere. Meteoric nickel is found in combination with iron, a reflection of the origin of those elements as major end products of supernova nucleosynthesis. An iron–nickel mixture is thought to compose Earth's outer and inner cores. Use of nickel (as natural meteoric nickel–iron alloy) has been traced as far back as 3500 BCE. Nickel was first isolated and classified a ...
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Borides
A boride is a compound between boron and a less electronegative element, for example silicon boride (SiB3 and SiB6). The borides are a very large group of compounds that are generally high melting and are covalent more than ionic in nature. Some borides exhibit very useful physical properties. The term boride is also loosely applied to compounds such as B12As2 (N.B. Arsenic has an electronegativity higher than boron) that is often referred to as icosahedral boride. Ranges of compounds The borides can be classified loosely as boron rich or metal rich, for example the compound YB66 at one extreme through to Nd2Fe14B at the other. The generally accepted definition is that if the ratio of boron atoms to metal atoms is 4:1 or more, the compound is boron rich; if it is less, then it is metal rich. Boron rich borides (B:M 4:1 or more) The main group metals, lanthanides and actinides form a wide variety of boron-rich borides, with metal:boron ratios up to YB66. The properties of this ...
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Hafnium Compounds
Hafnium compounds are compounds containing the element hafnium (Hf). Due to the lanthanide contraction, the ionic radius of hafnium(IV) (0.78 ångström) is almost the same as that of zirconium(IV) (0.79 angstroms). Consequently, compounds of hafnium(IV) and zirconium(IV) have very similar chemical and physical properties. Hafnium and zirconium tend to occur together in nature and the similarity of their ionic radii makes their chemical separation rather difficult. Hafnium tends to form inorganic compounds in the oxidation state of +4. Halogens react with it to form hafnium tetrahalides. At higher temperatures, hafnium reacts with oxygen, nitrogen, carbon, boron, sulfur, and silicon. Some compounds of hafnium in lower oxidation states are known. Halides Hafnium(IV) fluoride (HfF4) is a white crystalline powder. It has a monoclinic crystal structure, with space group C2/c (No.15), and lattice constants ''a'' = 1.17 nm, ''b'' = 0.986 nm and ''c'' = 0.764 nm. Hafnium(IV) ...
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Diffusion Barrier
A diffusion barrier is a thin layer (usually micrometres thick) of metal usually placed between two other metals. It is done to act as a barrier to protect either one of the metals from corrupting the other.. Adhesion of a plated metal layer to its substrate requires a physical interlocking, inter-diffusion of the deposit or a chemical bonding between plate and substrate in order to work. The role of a diffusion barrier is to prevent or to retard the inter-diffusion of the two superposed metals. Therefore, to be effective, a good diffusion barrier requires inertness with respect to adjacent materials. To obtain good adhesion and a diffusion barrier simultaneously, the bonding between layers needs to come from a chemical reaction of limited range at both boundaries. Materials providing good adhesion are not necessarily good diffusion barriers and vice versa. Consequently, there are cases where two or more separate layers must be used to provide a proper interface between substrates ...
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Control Rod
Control rods are used in nuclear reactors to control the rate of fission of the nuclear fuel – uranium or plutonium. Their compositions include chemical elements such as boron, cadmium, silver, hafnium, or indium, that are capable of absorbing many neutrons without themselves decaying. These elements have different neutron capture cross sections for neutrons of various energies. Boiling water reactors (BWR), pressurized water reactors (PWR), and heavy-water reactors (HWR) operate with thermal neutrons, while breeder reactors operate with fast neutrons. Each reactor design can use different control rod materials based on the energy spectrum of its neutrons. Control rods have been used in nuclear aircraft engines like Project Pluto as a method of control. Operating principle Control rods are inserted into the core of a nuclear reactor and adjusted in order to control the rate of the nuclear chain reaction and, thereby, the thermal power output of the reactor, the rat ...
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Nuclear Reactor
A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat from nuclear fission is passed to a working fluid (water or gas), which in turn runs through steam turbines. These either drive a ship's propellers or turn electrical generators' shafts. Nuclear generated steam in principle can be used for industrial process heat or for district heating. Some reactors are used to produce isotopes for medical and industrial use, or for production of weapons-grade plutonium. , the International Atomic Energy Agency reports there are 422 nuclear power reactors and 223 nuclear research reactors in operation around the world. In the early era of nuclear reactors (1940s), a reactor was known as a nuclear pile or atomic pile (so-called because the graphite moderator blocks of the first reactor were placed in ...
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Ablation
Ablation ( la, ablatio – removal) is removal or destruction of something from an object by vaporization, chipping, erosive processes or by other means. Examples of ablative materials are described below, and include spacecraft material for ascent and atmospheric reentry, ice and snow in glaciology, biological tissues in medicine and passive fire protection materials. Artificial intelligence In artificial intelligence (AI), especially machine learning, ablation is the removal of a component of an AI system. The term is by analogy with biology: removal of components of an organism. Biology Biological ablation is the removal of a biological structure or functionality. Genetic ablation is another term for gene silencing, in which gene expression is abolished through the alteration or deletion of genetic sequence information. In cell ablation, individual cells in a population or culture are destroyed or removed. Both can be used as experimental tools, as in loss-of-functi ...
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Leading Edge
The leading edge of an airfoil surface such as a wing is its foremost edge and is therefore the part which first meets the oncoming air.Crane, Dale: ''Dictionary of Aeronautical Terms, third edition'', page 305. Aviation Supplies & Academics, 1997. Characteristics Sweep Seen in plan the leading edge may be straight, curved, kinked or a combination of these. A straight leading edge may be swept or unswept, while curves or kinks always mean that part of the leading edge is swept. On a swept wing the sweep angle may differ from that of the wing, as wing sweep is conventionally measured at the airfoil 25% chord line. However on a delta wing the leading edge sweep defines the wing sweep. Radius and stagnation point A rounded leading edge helps to maintain a smooth airflow at varying angles of incidence to the airflow. Most subsonic airfoils therefore have a rounded leading edge. The degree of rounding is characterised by the profile radius at that point. The airflow divides ...
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Heat Shield
In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is also often used to refer to the thermal energy contained in a system as a component of its internal energy and that is reflected in the temperature of the system. For both uses of the term, heat is a form of energy. An example of formal vs. informal usage may be obtained from the right-hand photo, in which the metal bar is "conducting heat" from its hot end to its cold end, but if the metal bar is considered a thermodynamic system, then the energy flowing within the metal bar is called internal energy, not heat. The hot metal bar is also transferring heat to its surroundings, a correct statement for both the strict and loose meanings of ''heat''. Another example of informal usage is the term '' heat content'', used despite the fact that ...
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ICBM
An intercontinental ballistic missile (ICBM) is a ballistic missile with a range greater than , primarily designed for nuclear weapons delivery (delivering one or more thermonuclear warheads). Conventional, chemical, and biological weapons can also be delivered with varying effectiveness, but have never been deployed on ICBMs. Most modern designs support multiple independently targetable reentry vehicles (MIRVs), allowing a single missile to carry several warheads, each of which can strike a different target. Russia, the United States, China, France, India, the United Kingdom, and North Korea are the only countries known to have operational ICBMs. Early ICBMs had limited precision, which made them suitable for use only against the largest targets, such as cities. They were seen as a "safe" basing option, one that would keep the deterrent force close to home where it would be difficult to attack. Attacks against military targets (especially hardened ones) still demanded ...
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Reentry
Atmospheric entry is the movement of an object from outer space into and through the gases of an atmosphere of a planet, dwarf planet, or natural satellite. There are two main types of atmospheric entry: ''uncontrolled entry'', such as the entry of astronomical objects, space debris, or bolides; and ''controlled entry'' (or ''reentry'') of a spacecraft capable of being navigated or following a predetermined course. Technologies and procedures allowing the controlled atmospheric ''entry, descent, and landing'' of spacecraft are collectively termed as ''EDL''. Objects entering an atmosphere experience atmospheric drag, which puts mechanical stress on the object, and aerodynamic heating—caused mostly by compression of the air in front of the object, but also by drag. These forces can cause loss of mass (ablation) or even complete disintegration of smaller objects, and objects with lower compressive strength can explode. Crewed space vehicles must be slowed to subsonic spee ...
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