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Goethite
Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient times for its use as a pigment (brown ochre). Evidence has been found of its use in paint pigment samples taken from the caves of Lascaux in France. It was first described in 1806 based on samples found in the Hollertszug Mine in Herdorf, Germany. The mineral was named after the German polymath and poet Johann Wolfgang von Goethe (1749–1832). Composition Goethite is an iron oxyhydroxide containing ferric iron. It is the main component of rust and bog iron ore. Goethite's hardness ranges from 5.0 to 5.5 on the Mohs Scale, and its specific gravity varies from 3.3 to 4.3. The mineral forms prismatic needle-like crystals ("needle ironstone") but is more typically massive. Feroxyhyte and lepidocrocite are both polymorphs of the iron oxy ...
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Bog Iron
Bog iron is a form of impure iron deposit that develops in bogs or swamps by the chemical or biochemical oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or ... of iron carried in solution. In general, bog ores consist primarily of iron oxyhydroxides, commonly goethite (FeO(OH)). Iron-bearing groundwater typically emerges as a Spring (hydrology), spring and the iron in it forms ferric hydroxide upon encountering the oxidizing environment of the surface. Bog ore often combines goethite, magnetite, and vugs or stained quartz. Oxidation may occur through enzyme catalysis by iron bacteria. It is not clear whether the magnetite precipitates upon the first contact with oxygen, then oxidizes to ferric compounds, or whether the ferric compounds are reduced when exposed to Anoxic ...
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Iron(III) Oxide-hydroxide
Iron(III) oxide-hydroxide or ferric oxyhydroxideA. L. Mackay (1960): "β-Ferric Oxyhydroxide". ''Mineralogical Magazine'' (''Journal of the Mineralogical Society''), volume 32, issue 250, pages 545-557. is the chemical compound of iron, oxygen, and hydrogen with formula . The compound is often encountered as one of its hydrates, ·''n'' ust The monohydrate · is often referred to as iron(III) hydroxide ,CAS , C.I. 77492 hydrated iron oxide, yellow iron oxide, or Pigment Yellow 42. Natural occurrences Minerals Anhydrous ferric hydroxide occurs in the nature as the exceedingly rare mineral bernalite, Fe(OH)3·''n''H2O (n=0.0-0.25). Iron oxyhydroxides, , are much more common and occur naturally as structurally different minerals (polymorphs) denoted by the Greek letters α, β, γ and δ. * Goethite, α-FeO(OH), has been used as an ochre pigment since prehistoric times. * Akaganeite is the β polymorph,A. L. Mackay (1962): "β-Ferric oxyhydroxide—akaganéite", ''Miner ...
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Iron(III) Oxide-hydroxide
Iron(III) oxide-hydroxide or ferric oxyhydroxideA. L. Mackay (1960): "β-Ferric Oxyhydroxide". ''Mineralogical Magazine'' (''Journal of the Mineralogical Society''), volume 32, issue 250, pages 545-557. is the chemical compound of iron, oxygen, and hydrogen with formula . The compound is often encountered as one of its hydrates, ·''n'' ust The monohydrate · is often referred to as iron(III) hydroxide ,CAS , C.I. 77492 hydrated iron oxide, yellow iron oxide, or Pigment Yellow 42. Natural occurrences Minerals Anhydrous ferric hydroxide occurs in the nature as the exceedingly rare mineral bernalite, Fe(OH)3·''n''H2O (n=0.0-0.25). Iron oxyhydroxides, , are much more common and occur naturally as structurally different minerals (polymorphs) denoted by the Greek letters α, β, γ and δ. * Goethite, α-FeO(OH), has been used as an ochre pigment since prehistoric times. * Akaganeite is the β polymorph,A. L. Mackay (1962): "β-Ferric oxyhydroxide—akaganéite", ''Miner ...
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Johann Wolfgang Von Goethe
Johann Wolfgang von Goethe (28 August 1749 – 22 March 1832) was a German poet, playwright, novelist, scientist, statesman, theatre director, and critic. His works include plays, poetry, literature, and aesthetic criticism, as well as treatises on botany, anatomy, and colour. He is widely regarded as the greatest and most influential writer in the German language, his work having a profound and wide-ranging influence on Western literary, political, and philosophical thought from the late 18th century to the present day.. Goethe took up residence in Weimar in November 1775 following the success of his first novel, '' The Sorrows of Young Werther'' (1774). He was ennobled by the Duke of Saxe-Weimar, Karl August, in 1782. Goethe was an early participant in the '' Sturm und Drang'' literary movement. During his first ten years in Weimar, Goethe became a member of the Duke's privy council (1776–1785), sat on the war and highway commissions, oversaw the reopening of ...
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Lascaux
Lascaux ( , ; french: Grotte de Lascaux , "Lascaux Cave") is a network of caves near the village of Montignac, in the department of Dordogne in southwestern France. Over 600 parietal wall paintings cover the interior walls and ceilings of the cave. The paintings represent primarily large animals, typical local contemporary fauna that correspond with the fossil record of the Upper Paleolithic in the area. They are the combined effort of many generations and, with continued debate, the age of the paintings is now usually estimated at around 17,000 years (early Magdalenian). Because of the outstanding prehistoric art in the cave, Lascaux was inducted into the UNESCO World Heritage List in 1979, as an element of the ''Prehistoric Sites and Decorated Caves of the Vézère Valley''. The original caves have been closed to the public since 1963, as their condition was deteriorating, but there are now a number of replicas. History since rediscovery On 12 September 1940, the entra ...
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Ochre
Ochre ( ; , ), or ocher in American English, is a natural clay earth pigment, a mixture of ferric oxide and varying amounts of clay and sand. It ranges in colour from yellow to deep orange or brown. It is also the name of the colours produced by this pigment, especially a light brownish-yellow. A variant of ochre containing a large amount of hematite, or dehydrated iron oxide, has a reddish tint known as "red ochre" (or, in some dialects, ruddle). The word ochre also describes clays coloured with iron oxide derived during the extraction of tin and copper. Earth pigments Ochre is a family of earth pigments, which includes yellow ochre, red ochre, purple ochre, sienna, and umber. The major ingredient of all the ochres is iron(III) oxide-hydroxide, known as limonite, which gives them a yellow colour. * Yellow ochre, , is a hydrated iron hydroxide (limonite) also called gold ochre. * Red ochre, , takes its reddish colour from the mineral hematite, which is an anhydrous i ...
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Weathering
Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), and so is distinct from erosion, which involves the transport of rocks and minerals by agents such as water, ice, snow, wind, waves and gravity. Weathering processes are divided into ''physical'' and ''chemical weathering''. Physical weathering involves the breakdown of rocks and soils through the mechanical effects of heat, water, ice, or other agents. Chemical weathering involves the chemical reaction of water, atmospheric gases, and biologically produced chemicals with rocks and soils. Water is the principal agent behind both physical and chemical weathering, though atmospheric oxygen and carbon dioxide and the activities of biological organisms are also important. Chemical weathering by biological action is also known as biologic ...
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Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is a natural p ...
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Feroxyhyte
Feroxyhyte is an oxide/hydroxide of iron, δ-Fe3+O(OH). Feroxyhyte crystallizes in the hexagonal system. It forms as brown rounded to concretionary masses. Feroxyhyte is opaque, magnetic, has a yellow streak, and has a relative density of 4.2. It occurs in manganese-iron nodules on the Atlantic and Pacific Ocean floors. It is also found in the Baltic, White, and Kara Seas. Forms under high pressure conditions and reverts to goethite on exposure to surface conditions. It also occurs as cement and coatings on clasts in poorly drained soils and sediments, formed by the rapid oxidation of iron(II) oxide compounds. It was first described in 1976 for an occurrence in soils at its type locality: Kolomyya, Ivano-Frankivsk Oblast, Ukraine Ukraine ( uk, Україна, Ukraïna, ) is a country in Eastern Europe. It is the second-largest European country after Russia, which it borders to the east and northeast. Ukraine covers approximately . Prior to the ongoing Russian inv ...
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Diaspore
Diaspore , also known as diasporite, empholite, kayserite, or tanatarite, is an aluminium oxide hydroxide mineral, α-AlO(OH), crystallizing in the orthorhombic system and isomorphous with goethite. It occurs sometimes as flattened crystals, but usually as lamellar or scaly masses, the flattened surface being a direction of perfect cleavage on which the lustre is markedly pearly in character. It is colorless or greyish-white, yellowish, sometimes violet in color, and varies from translucent to transparent. It may be readily distinguished from other colorless transparent minerals with a perfect cleavage and pearly luster—like mica, talc, brucite and gypsum— by its greater hardness of 6.5–7. The specific gravity is 3.4. When heated before the blowpipe it decrepitates violently, breaking up into white pearly scales. The mineral occurs as an alteration product of corundum or emery and is found in granular limestone and other crystalline rocks. Well-developed crystals ar ...
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Crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification. The word ''crystal'' derives from the Ancient Greek word (), meaning both "ice" and "rock crystal", from (), "icy cold, frost". Examples of large crystals include snowflakes, diamonds, and table salt. Most inorganic solids are not crystals but polycrystals, i.e. many microscopic crystals fused together into a single solid. Polycrystals include most metals, rocks, ceramics, and ice. A third category ...
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Specific Gravity
Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its densest (at ); for gases, the reference is air at room temperature (). The term "relative density" (often abbreviated r.d. or RD) is often preferred in scientific usage, whereas the term "specific gravity" is deprecated. If a substance's relative density is less than 1 then it is less dense than the reference; if greater than 1 then it is denser than the reference. If the relative density is exactly 1 then the densities are equal; that is, equal volumes of the two substances have the same mass. If the reference material is water, then a substance with a relative density (or specific gravity) less than 1 will float in water. For example, an ice cube, with a relative density of about 0.91, will float. A substance with a relative density greater ...
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