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Glass-to-metal Seal
Glass-to-metal seals are a very important element of the construction of vacuum tubes, electric discharge tubes, incandescent light bulbs, glass encapsulated semiconductor diodes, reed switches, pressure tight glass windows in metal cases, Vacuum Insulating Glass (Vacuum Glass) and metal or ceramic packages of electronic components. Properly done, such a seal is Hermetic seal, hermetic (vacuum tight, good electrical insulation, special optical properties e.g. UV lamps). To achieve such a seal, two properties must hold: # The molten glass must be capable of wetting the metal, in order to form a tight bond, and # The thermal expansion of the glass and metal must be closely matched so that the seal remains solid as the assembly cools. Thinking for example about a metal wire in a glass bulb sealing, the metal glass contact can break if coefficients of thermal expansion (CTE) are not well aligned. For the case that the CTE of the metal is larger than the CTE of the glass, the sealing s ...
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Vacuum Capacitor With Uranium Glass
A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or "void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often discuss ideal test results that would occur in a ''perfect'' vacuum, which they sometimes simply call "vacuum" or free space, and use the term partial vacuum to refer to an actual imperfect vacuum as one might have in a laboratory or in space. In engineering and applied physics on the other hand, vacuum refers to any space in which the pressure is considerably lower than atmospheric pressure. The Latin term ''in vacuo'' is used to describe an object that is surrounded by a vacuum. The ''quality'' of a partial vacuum refers to how closely it approaches a perfect vacuum. Other things equal, lower gas pressure means higher-quality vacuum. For example, a typical vacuum cleaner produces enough suction to reduce air pressure by around 20%. But hig ...
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Redox
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogenation, C=C (and other) bonds ...
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Platinum
Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Platinum is a member of the platinum group of elements and group 10 of the periodic table of elements. It has six naturally occurring isotopes. It is one of the rarer elements in Earth's crust, with an average abundance of approximately 5 μg/kg. It occurs in some nickel and copper ores along with some native deposits, mostly in South Africa, which accounts for ~80% of the world production. Because of its scarcity in Earth's crust, only a few hundred tonnes are produced annually, and given its important uses, it is highly valuable and is a major precious metal commodity. Platinum is one of the least reactive metals. It has remarkable resistance to corrosion, even at high temperatures, and is therefore considered a noble metal. Conse ...
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Dumet
Fernico describe a family of metal alloys made primarily of iron, nickel and cobalt. The family includes Kovar, FerNiCo I, FerNiCo II, and Dumet. The name is made up of the chemical symbols of its constituent three elements. "Dumet" is a portmanteau of "dual" and "metal," because it is a heterogeneous alloy, usually fabricated in the form of a wire with an alloy core and a copper cladding. These alloys possess the properties of electrical conductivity, minimal oxidation and formation of porous surfaces at working temperatures of glass and thermal coefficients of expansion which match glass closely. These requirements allow the alloys to be used in glass seals, such that the seal does not crack, fracture or leak with changes in temperature. Dumet is most commonly used in seals where lead-in wires pass through the glass bulb wall of standard household electric lamps (light bulbs) among other things. The two Fernico alloys both consist of iron (Fe), nickel (Ni), and cobalt (Co). F ...
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Hydrogen Embrittlement
Hydrogen embrittlement (HE), also known as hydrogen-assisted cracking or hydrogen-induced cracking (HIC), is a reduction in the ductility of a metal due to absorbed hydrogen. Hydrogen atoms are small and can permeate solid metals. Once absorbed, hydrogen lowers the stress required for cracks in the metal to initiate and propagate, resulting in embrittlement. Hydrogen embrittlement occurs most notably in steels, as well as in iron, nickel, titanium, cobalt, and their alloys. Copper, aluminium, and stainless steels are less susceptible to hydrogen embrittlement. The essential facts about the nature of hydrogen embrittlement have been known since the 19th century. Hydrogen embrittlement is maximised at around room temperature in steels, and most metals are relatively immune to hydrogen embrittlement at temperatures above 150 °C. Hydrogen embrittlement requires the presence of both atomic ("diffusible") hydrogen and a mechanical stress to induce crack growth, although that ...
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Copper(I) Oxide
Copper(I) oxide or cuprous oxide is the inorganic compound with the formula Cu2O. It is one of the principal oxides of copper, the other being or copper(II) oxide or cupric oxide (CuO). This red-coloured solid is a component of some antifouling paints. The compound can appear either yellow or red, depending on the size of the particles. Copper(I) oxide is found as the reddish mineral cuprite. Preparation Copper(I) oxide may be produced by several methods. Most straightforwardly, it arises via the oxidation of copper metal: : 4 Cu + O2 → 2 Cu2O Additives such as water and acids affect the rate of this process as well as the further oxidation to copper(II) oxides. It is also produced commercially by reduction of copper(II) solutions with sulfur dioxide. Reactions Aqueous cuprous chloride solutions react with base to give the same material. In all cases, the color is highly sensitive to the procedural details. Formation of copper(I) oxide is the basis of the F ...
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Gas-filled Tube
A gas-filled tube, also commonly known as a discharge tube or formerly as a Plücker tube, is an arrangement of electrodes in a gas within an insulating, temperature-resistant envelope. Gas-filled tubes exploit phenomena related to electric discharge in gases, and operate by ionizing the gas with an applied voltage sufficient to cause electrical conduction by the underlying phenomena of the Townsend discharge. A gas-discharge lamp is an electric light using a gas-filled tube; these include fluorescent lamps, metal-halide lamps, sodium-vapor lamps, and neon lights. Specialized gas-filled tubes such as krytrons, thyratrons, and ignitrons are used as switching devices in electric devices. The voltage required to initiate and sustain discharge is dependent on the pressure and composition of the fill gas and geometry of the tube. Although the envelope is typically glass, power tubes often use ceramics, and military tubes often use glass-lined metal. Both hot cathode and ...
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Hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol 1H) each atom has one proton, one electron, and no neutrons. In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral hydrogen atoms throughout the universe occur ...
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Oxygen-free Copper
Oxygen-free copper (OFC) or oxygen-free high thermal conductivity (OFHC) copper is a group of wrought high-conductivity copper alloys that have been electrolytically refined to reduce the level of oxygen to 0.001% or below. Specification Oxygen-free copper is typically specified according to the ASTM/ UNS database. The UNS database includes many different compositions of high conductivity electrical copper. Of these, three are widely used and two are considered oxygen-free: * C10100 – also known as ''oxygen-free electronic'' (OFE). This is a 99.99% pure copper with 0.0005% oxygen content. It achieves a minimum 101% IACS conductivity rating. This copper is finished to a final form in a carefully regulated, oxygen-free environment. Silver (Ag) is considered an impurity in the OFE chemical specification. This is also the most expensive of the three grades listed here. * C10200 – also known as ''oxygen-free'' (OF). While OF is considered oxygen-free, its conductivity rating ...
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Sodium Borate
Sodium borate is a generic name for any salt of sodium with an anion consisting of boron and oxygen, and possibly hydrogen, or any hydrate thereof. It can be seen as a hydrated sodium salt of the appropriate boroxy acid, although the latter may not be a stable compound. Many sodium borates have important industrial and household applications; the best known being borax, = . The ternary phase diagram of the –– phase diagram in the 0–100 °C temperature range contains 13 unique hydrated crystalline sodium borates, including five important industrial products. Sodium borates, as well as boroxy acids, are often described as mixtures = , with ''x'', ''y'', and ''z'' chosen to fit the elemental formula, or a multiple thereof. Thus, for example, borax would be , and boric acid would be = . The elemental formula was often intrepreted as a ''z''-hydrate of an "anhydrous" salt without any hydrogen, namely . However, later research uncovered that many borates have hydroxyl ...
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Borax
Borax is a salt ( ionic compound), a hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a basic solution. It is commonly available in powder or granular form, and has many industrial and household uses, including as a pesticide, as a metal soldering flux, as a component of glass, enamel, and pottery glazes, for tanning of skins and hides, for artificial aging of wood, as a preservative against wood fungus, and as a pharmaceutic alkalizer. In chemical laboratories, it is used as a buffering agent. The compound is often called sodium tetraborate decahydrate, but that name is not consistent with its structure. The anion is not tetraborate but tetrahydroxy tetraborate , so the more correct formula should be . Informally, the product is often called sodium borate decahydrate or just sodium borate. The terms tincal "tinkle" and tincar "tinker" refer to native borax, historically mine ...
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Copper(II) Oxide
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is a product of Copper extraction, copper mining and the precursor to many other copper-containing products and chemical compounds. Production It is produced on a large scale by pyrometallurgy, as one stage in extracting copper from its ores. The ores are treated with an aqueous mixture of ammonium carbonate, ammonia, and oxygen to give copper(I) and copper(II) ammine complexes, which are extracted from the solids. These complexes are decomposed with steam to give CuO. It can be formed by heating copper in air at around 300–800°C: : 2 Cu + O2 → 2 CuO For laboratory uses, pure copper(II) oxide is better prepared by heating copper(II) nitrate, copper(II) hydroxide, or basic copper(II) carbonate: : 2 Cu(NO3)2(s) → 2 CuO(s) + 4 NO2(g) ...
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