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Guanidine Nitrate
Guanidine nitrate is the chemical compound with the formula (NH2)3O3. It is a colorless, water-soluble salt. It is produced on a large scale and finds use as precursor for nitroguanidine, fuel in pyrotechnics and gas generators. Its correct name is guanidinium nitrate, but the colloquial term guanidine nitrate is widely used. Production and properties Although it is the salt formed by neutralizing guanidine with nitric acid, guanidine nitrate is produced industrially by the reaction of dicyandiamide (or calcium salt) and ammonium nitrate.Thomas Güthner, Bernd Mertschenk and Bernd Schulz "Guanidine and Derivatives" in Ullmann's Encyclopedia of Industrial Chemistry, 2006, Wiley-VCH, Weinheim. It has been used as a monopropellant in the Jetex engine for model airplanes. It is attractive because it has a high gas output and low flame temperature. It has a relatively high monopropellant specific impulse of 177 seconds (1.7 kN·s/kg).1000 lbf/in2 (700 kPa) chamber pressure, 14. ...
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Nitroguanidine
Nitroguanidine - sometimes abbreviated NGu - is a colorless, crystalline solid that melts at 257 °C and decomposes at 254 °C. Nitroguanidine is an extremely insensitive but powerful high explosive. Wetting it with > 20 wt.-% water effects desensitization from HD 1.1 down to HD 4.1 (flammable solid). Nitroguanidine is used as an energetic material, i.e., propellant or high explosive, precursor for insecticides, and for other purposes. Manufacture Nitroguanidine is produced worldwide on a large scale starting with the reaction of dicyandiamide (DCD) with ammonium nitrate to afford the salt guanidinium nitrate, which is then nitrated by treatment with concentrated sulfuric acid at low temperature. : (NH2)3O3 → (NH2)2CNNO2 + H2O Nitroguanidine can also be generated by treatment of urea with ammonium nitrate (via the BMA process). However, owing to problems of reliability and safety, this process has never been commercialized despite its attractive economic feat ...
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Specific Impulse
Specific impulse (usually abbreviated ) is a measure of how efficiently a reaction mass engine (a rocket using propellant or a jet engine using fuel) creates thrust. For engines whose reaction mass is only the fuel they carry, specific impulse is exactly proportional to the effective exhaust gas velocity. A propulsion system with a higher specific impulse uses the mass of the propellant more efficiently. In the case of a rocket, this means less propellant needed for a given delta-v, so that the vehicle attached to the engine can more efficiently gain altitude and velocity. In an atmospheric context, specific impulse can include the contribution to impulse provided by the mass of external air that is accelerated by the engine in some way, such as by an internal turbofan or heating by fuel combustion participation then thrust expansion or by external propeller. Jet engines breathe external air for both combustion and by-pass, and therefore have a much higher specific impulse than ...
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Nitrates
Nitrate is a polyatomic ion with the chemical formula . Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are soluble in water. An example of an insoluble nitrate is bismuth oxynitrate. Structure The ion is the conjugate base of nitric acid, consisting of one central nitrogen atom surrounded by three identically bonded oxygen atoms in a trigonal planar arrangement. The nitrate ion carries a formal charge of −1. This charge results from a combination formal charge in which each of the three oxygens carries a − charge, whereas the nitrogen carries a +1 charge, all these adding up to formal charge of the polyatomic nitrate ion. This arrangement is commonly used as an example of resonance. Like the isoelectronic carbonate ion, the nitrate ion can be represented by resonance structures: Dietary nitrate A rich source of inorganic nitrate in the human diets come from leafy green foods ...
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Guanidinium Compounds
Guanidine is the compound with the formula HNC(NH2)2. It is a colourless solid that dissolves in polar solvents. It is a strong base that is used in the production of plastics and explosives. It is found in urine predominantly in patients experiencing renal failure. A guanidine moiety also appears in larger organic molecules, including on the side chain of arginine. Structure Guanidine can be thought of as a nitrogenous analogue of carbonic acid. That is, the C=O group in carbonic acid is replaced by a C=NH group, and each OH is replaced by a group. Isobutene can be seen as the carbon analogue in much the same way. A detailed crystallographic analysis of guanidine was elucidated 148 years after its first synthesis, despite the simplicity of the molecule. In 2013, the positions of the hydrogen atoms and their displacement parameters were accurately determined using single-crystal neutron diffraction. Production Guanidine can be obtained from natural sources, being first i ...
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Silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as a synthetic product. Notable examples include fused quartz, fumed silica, silica gel, opal and aerogels. It is used in structural materials, microelectronics (as an Insulator (electricity), electrical insulator), and as components in the food and pharmaceutical industries. Structure In the majority of silicates, the silicon atom shows tetrahedral coordination geometry, tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. In contrast, CO2 is a linear ...
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Potassium Nitrate
Potassium nitrate is a chemical compound with the chemical formula . This alkali metal nitrate salt is also known as Indian saltpetre (large deposits of which were historically mined in India). It is an ionic salt of potassium ions K+ and nitrate ions NO3−, and is therefore an alkali metal nitrate. It occurs in nature as a mineral, niter (or ''nitre'' in the UK). It is a source of nitrogen, and nitrogen was named after niter. Potassium nitrate is one of several nitrogen-containing compounds collectively referred to as saltpeter (or ''saltpetre'' in the UK). Major uses of potassium nitrate are in fertilizers, tree stump removal, rocket propellants and fireworks. It is one of the major constituents of gunpowder (black powder). In processed meats, potassium nitrate reacts with hemoglobin and myoglobin generating a red color. Etymology Potassium nitrate, because of its early and global use and production, has many names. Hebrew and Egyptian words for it had the consonants n-t-r ...
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Airbag
An airbag is a vehicle occupant-restraint system using a bag designed to inflate extremely quickly, then quickly deflate during a collision. It consists of the airbag cushion, a flexible fabric bag, an inflation module, and an impact sensor. The purpose of the airbag is to provide a vehicle occupant with soft cushioning and restraint during a collision. It can reduce injuries between the flailing occupant and the interior of the vehicle. The airbag provides an energy-absorbing surface between the vehicle's occupants and a steering wheel, instrument panel, body pillar, headliner, and windshield. Modern vehicles may contain up to 10 airbag modules in various configurations, including: driver, passenger, side-curtain, seat-mounted, door-mounted, B and C-pillar mounted side-impact, knee bolster, inflatable seat belt, and pedestrian airbag modules. During a crash, the vehicle's crash sensors provide crucial information to the airbag electronic controller unit (ECU), including colli ...
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Model Airplane
A model aircraft is a small unmanned aircraft. Many are replicas of real aircraft. Model aircraft are divided into two basic groups: flying and non-flying. Non-flying models are also termed static, display, or shelf models. Aircraft manufacturers and researchers make wind tunnel models for testing aerodynamic properties, for basic research, or for the development of new designs. Sometimes only part of the aircraft is modelled. Static models range from mass-produced toys in white metal or plastic to highly accurate and detailed models produced for museum display and requiring thousands of hours of work. Many are available in kits, typically made of injection-moulded polystyrene or resin. Flying models range from simple toy gliders made of sheets of paper, balsa, card stock or foam polystyrene to powered scale models built up from balsa, bamboo sticks, plastic, (including both moulded or sheet polystyrene, and styrofoam), metal, synthetic resin, either alone or with carbon fibr ...
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Gas Generator
A gas generator is a device for generating gas. A gas generator may create gas by a chemical reaction or from a solid or liquid source, when storing a pressurized gas is undesirable or impractical. The term often refers to a device that uses a rocket propellant to generate large quantities of gas. The gas is typically used to drive a turbine rather than to provide thrust as in a rocket engine. Gas generators of this type are used to power turbopumps in rocket engines, in a gas-generator cycle. It is also used by some auxiliary power units to power electric generators and hydraulic pumps. Another common use of the term is in the industrial gases industry, where gas generators are used to produce gaseous chemicals for sale. For example, the chemical oxygen generator, which delivers breathable oxygen at a controlled rate over a prolonged period. During World War II, portable gas generators that converted coke to producer gas were used to power vehicles as a way of alleviat ...
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Jetex Engine
The Jetex motor is a miniature solid-fuel rocket motor produced for use as a powerplant for flying model aircraft. Its production led to a number of imitators and, after its demise, successors of similar type. __FORCETOC__ Original Jetex motors Jetex was developed in 1947, by Wilmot, Mansour & Company Ltd of Southampton, which had started operations in a decommissioned hangar at RAF Beaulieu. The first motor was demonstrated in early 1948 and was available to the public in June 1948, when ''Aeromodeller'' magazine featured Jetex power on its front cover. The first motors were the Jetex 100 and 200, with the more powerful Jetex 350 following in November 1948. The most popular motor, the Jetex 50, was introduced in May 1949, along with kits for a model plane and model car using Jetex power. The subsequent popularity of Jetex led to the manufacture of numerous kits by third-party companies such as KeilKraft and Skyleada. Jetex motors are powered by a solid pellet consisting main ...
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Monopropellant
Monopropellants are propellants consisting of chemicals that release energy through exothermic chemical decomposition. The molecular bond energy of the monopropellant is released usually through use of a catalyst. This can be contrasted with bipropellants that release energy through the chemical reaction between an oxidizer and a fuel. While stable under defined storage conditions, monopropellants decompose very rapidly under certain other conditions to produce a large volume of its own energetic (hot) gases for the performance of mechanical work. Although solid deflagrants such as nitrocellulose, the most commonly used propellant in firearms, could be thought of as monopropellants, the term is usually reserved for liquids in engineering literature. Uses The most common use of monopropellants is in low-impulse monopropellant rocket motors, such as reaction control thrusters, the usual propellant being hydrazine, p. 230 which is generally decomposed by exposure to an iridium, ...
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