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Galvani Potential
In electrochemistry, the Galvani potential (also called Galvani potential difference, or inner potential difference, Δφ, delta phi) is the electric potential difference between two points in the bulk of two phases. These phases can be two different solids (e.g., two metals joined together), or a solid and a liquid (e.g., a metal electrode submerged in an electrolyte). The Galvani potential is named after Luigi Galvani. Galvani potential between two metals First, consider the Galvani potential between two metals. When two metals are electrically isolated from each other, an arbitrary voltage difference may exist between them. However, when two different metals are brought into electronic contact, electrons will flow from the metal with a lower voltage to the metal with the higher voltage until the Fermi level of the electrons in the bulk of both phases are equal. The actual numbers of electrons that passes between the two phases is small (it depends on the capacitance betwee ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Galvani Volta Surface Potential
Luigi Galvani (, also ; ; la, Aloysius Galvanus; 9 September 1737 – 4 December 1798) was an Italian physician, physicist, biologist and philosopher, who studied animal electricity. In 1780, he discovered that the muscles of dead frogs' legs twitched when struck by an electrical spark. This was an early study of bioelectricity, following experiments by John Walsh and Hugh Williamson. Early life Luigi Galvani was born to Domenico Galvani and Barbara Caterina Foschi, in Bologna, then part of the Papal States. Domenico was a goldsmith. Galvani then began taking an interest in the field of "medical electricity". This field emerged in the middle of the 18th century, following electrical researches and the discovery of the effects of electricity on the human body by scientists including Bertrand Bajon and Ramón M. Termeyer in the 1760s, and by John Walsh and Hugh Williamson in the 1770s. Galvani vs. Volta Alessandro Volta, a professor of experimental physics in the Unive ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Double Layer (surface Science)
A double layer (DL, also called an electrical double layer, EDL) is a structure that appears on the surface of an object when it is exposed to a fluid. The object might be a solid particle, a gas bubble, a liquid droplet, or a porous body. The DL refers to two parallel layers of charge surrounding the object. The first layer, the surface charge (either positive or negative), consists of ions adsorbed onto the object due to chemical interactions. The second layer is composed of ions attracted to the surface charge via the Coulomb force, electrically screening the first layer. This second layer is loosely associated with the object. It is made of free ions that move in the fluid under the influence of electric attraction and thermal motion rather than being firmly anchored. It is thus called the "diffuse layer". Interfacial DLs are most apparent in systems with a large surface area to volume ratio, such as a colloid or porous bodies with particles or pores (respectively) on the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Donnan Potential
Donnan potential is the difference in the Galvani potentials which appears as a result of Donnan equilibrium, named after Frederick G. Donnan, which refers to the distribution of ion species between two ionic solutions separated by a semipermeable membrane or boundary.{{GoldBookRef , title=Donnan emf (Donnan potential) , file=MD01830 The boundary layer maintains an unequal distribution of ionic solute concentration by acting as a selective barrier to ionic diffusion. Some species of ions may pass through the barrier while others may not. The solutions may be gels or colloids as well as ionic liquids, and as such the phase boundary between gels or a gel and a liquid can also act as a selective barrier. Electric potential arises between two solutions is called Donnan potential. Donnan equilibrium is prominent in the triphasic model for articular cartilage proposed by Mow and Ratcliffe, as well as in electrochemical fuel cells and dialysis. The Donnan effect is extra osmotic p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Volta Potential
The Volta potential (also called Volta potential difference, contact potential difference, outer potential difference, Δψ, or "delta psi") in electrochemistry, is the electrostatic potential difference between two metals (or one metal and one electrolyte) that are in contact and are in thermodynamic equilibrium. Specifically, it is the potential difference between a point close to the surface of the first metal and a point close to the surface of the second metal (or electrolyte). The Volta potential is named after Alessandro Volta. Volta potential between two metals When two metals are electrically isolated from each other, an arbitrary potential difference may exist between them. However, when two different neutral metal surfaces are brought into electrical contact (even indirectly, say, through a long electro-conductive wire), electrons will flow from the metal with the higher Fermi level to the metal with the lower Fermi level until the Fermi levels in the two phases are e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
ITIES
In electrochemistry, ITIES (interface between two immiscible electrolyte solutions) is an electrochemical interface that is either polarisable or polarised. An ITIES is polarisable if one can change the Galvani potential difference, or in other words the difference of inner potentials between the two adjacent phases, without noticeably changing the chemical composition of the respective phases (i.e. without noticeable electrochemical reactions taking place at the interface). An ITIES system is polarised if the distribution of the different charges and redox species between the two phases determines the Galvani potential difference. Usually, one electrolyte is an aqueous electrolyte composed of hydrophilic ions such as NaCl dissolved in water and the other electrolyte is a lipophilic salt such as tetrabutylammonium tetraphenylborate dissolved in an organic solvent immiscible with water such as nitrobenzene, or 1,2-dichloroethane. Charge transfer reactions of an ITIES Three major ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrode Potential
In electrochemistry, electrode potential is the electromotive force of a galvanic cell built from a standard reference electrode and another electrode to be characterized. By convention, the reference electrode is the standard hydrogen electrode (SHE). It is defined to have a potential of zero volts. It may also be defined as the potential difference between the charged metallic rods and salt solution. The electrode potential has its origin in the potential difference developed at the interface between the electrode and the electrolyte. It is common, for instance, to speak of the electrode potential of the M+/M redox couple. Origin and interpretation Electrode potential appears at the interface between an electrode and electrolyte due to the transfer of charged species across the interface, specific adsorption of ions at the interface, and specific adsorption/orientation of polar molecules, including those of the solvent. In an electrochemical cell, the cathode and the anode ha ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Absolute Electrode Potential
Absolute electrode potential, in electrochemistry, according to an IUPAC definition, is the electrode potential of a metal measured with respect to a universal reference system (without any additional metal–solution interface). Definition According to a more specific definition presented by Trasatti, the absolute electrode potential is the difference in electronic energy between a point inside the metal (Fermi level) of an electrode and a point outside the electrolyte in which the electrode is submerged (an electron at rest in vacuum). This potential is difficult to determine accurately. For this reason, standard hydrogen electrode is typically used for reference potential. The absolute potential of the SHE is 4.44 ± 0.02 V at 25 °C. Therefore, for any electrode at 25 °C: :E^M_ = E^M_+(4.44 \pm 0.02)\ where: : is electrode potential :V is the unit volt :''M'' denotes the electrode made of metal M :(abs) denotes the absolute potential :(SHE) denot ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Galvanic Cell
A galvanic cell or voltaic cell, named after the scientists Luigi Galvani and Alessandro Volta, respectively, is an electrochemical cell in which an electric current is generated from spontaneous Oxidation-Reduction reactions. A common apparatus generally consists of two different metals, each immersed in separate beakers containing their respective metal ions in solution that are connected by a salt bridge or separated by a porous membrane. Volta was the inventor of the voltaic pile, the first Battery (electricity), electrical battery. In common usage, the word "battery" has come to include a single galvanic cell, but a battery properly consists of multiple cells. History In 1780, Luigi Galvani discovered that when two different metals (e.g., copper and zinc) are in contact and then both are touched at the same time to two different parts of a muscle of a frog leg, to close the circuit, the frog's leg contracts. He called this "bioelectricity, animal electricity". The frog ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Faraday Constant
In physical chemistry, the Faraday constant, denoted by the symbol and sometimes stylized as ℱ, is the electric charge per mole of elementary charges. It is named after the English scientist Michael Faraday. Since the 2019 redefinition of SI base units, which took effect on 20 May 2019, the Faraday constant has the exactly defined value given by the product of the elementary charge ''e'' and Avogadro constant ''N''A: : : :. Derivation The Faraday constant can be thought of as the conversion factor between the mole (used in chemistry) and the coulomb (used in physics and in practical electrical measurements), and is therefore of particular use in electrochemistry. Because 1 mole contains exactly entities, and 1 coulomb contains exactly elementary charges, the Faraday constant is given by the quotient of these two quantities: :. One common use of the Faraday constant is in electrolysis calculations. One can divide the amount of charge (the current integrated over time) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Potential
In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a species in a mixture is defined as the rate of change of free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system. Thus, it is the partial derivative of the free energy with respect to the amount of the species, all other species' concentrations in the mixture remaining constant. When both temperature and pressure are held constant, and the number of particles is expressed in moles, the chemical potential is the partial molar Gibbs free energy. At chemical equilibrium or in phase equilibrium, the total sum of the product of chemical potentials and stoichiometric coefficients is zero, as the free energy is at a minimum. In a system in diffusion equilibrium, th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fermi Level
The Fermi level of a solid-state body is the thermodynamic work required to add one electron to the body. It is a thermodynamic quantity usually denoted by ''µ'' or ''E''F for brevity. The Fermi level does not include the work required to remove the electron from wherever it came from. A precise understanding of the Fermi level—how it relates to electronic band structure in determining electronic properties, how it relates to the voltage and flow of charge in an electronic circuit—is essential to an understanding of solid-state physics. In band structure theory, used in solid state physics to analyze the energy levels in a solid, the Fermi level can be considered to be a hypothetical energy level of an electron, such that at thermodynamic equilibrium this energy level would have a ''50% probability of being occupied at any given time''. The position of the Fermi level in relation to the band energy levels is a crucial factor in determining electrical properties. The Fermi le ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrochemistry
Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outcome of a particular chemical change, or vice versa. These reactions involve electrons moving via an electronically-conducting phase (typically an external electrical circuit, but not necessarily, as in electroless plating) between electrodes separated by an ionically conducting and electronically insulating electrolyte (or ionic species in a solution). When a chemical reaction is driven by an electrical potential difference, as in electrolysis, or if a potential difference results from a chemical reaction as in an electric battery or fuel cell, it is called an ''electrochemical'' reaction. Unlike in other chemical reactions, in electrochemical reactions electrons are not transferred directly between atoms, ions, or molecules, but via the af ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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