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Fred Basolo
Fred Basolo (11 February 1920 – 27 February 2007) was an American inorganic chemist. He received his Ph.D. at the University of Illinois at Urbana-Champaign in 1943, under Prof. John C. Bailar, Jr. Basolo spent his professional career at Northwestern University. He was a prolific contributor to the fields of coordination chemistry, organometallic, and bioinorganic chemistry, publishing over 400 papers. He supervised many Ph.D. students. With colleague Ralph Pearson, he co-authored the influential monograph "Mechanisms of Inorganic Reactions", which illuminated the importance of mechanisms involving coordination compounds. This work, which integrated concepts from ligand field theory and physical organic chemistry, signaled a shift from a highly descriptive nature of coordination chemistry to a more quantitative science. Biography Giovanni Basolo and Catherina Morena Basolo immigrated from the Piedmont area of Italy to Illinois. They had three children there; the youngest w ...
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Coello, Illinois
North City is a village in Franklin County, Illinois, United States. As of the 2020 census, the population was 509. North City is also known as "Coello". The current mayor is Curtis Overton. History North City incorporated in 1915. Its name comes from two nearby coal mines which were nicknamed "New North" and "Old North." A post office, known as "Coello" after its first postmaster, Pete Coello, opened in 1918. Both "North City" and "Coello" are commonly used in the village.Franklin County, Illinois, 1818-1997' (Turner Publishing Company, 1996), pp. 12-13. Geography North City is located in western Franklin County at (37.993129, -89.065547). It is bordered to the south by the city of Christopher. Illinois Route 148 passes through the eastern side of the village, leading north to Valier, north to Sesser, and south through Christopher to Zeigler. Illinois Route 14 runs just south of North City, leading east to Benton, the Franklin County seat, and west to Du Quoin. ...
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Ligand Field Theory
Ligand field theory (LFT) describes the bonding, orbital arrangement, and other characteristics of coordination complexes. It represents an application of molecular orbital theory to transition metal complexes. A transition metal ion has nine valence atomic orbitals - consisting of five ''n''d, one (''n''+1)s, and three (''n''+1)p orbitals. These orbitals are of appropriate energy to form bonding interaction with ligands. The LFT analysis is highly dependent on the geometry of the complex, but most explanations begin by describing octahedral complexes, where six ligands coordinate to the metal. Other complexes can be described by reference to crystal field theory.G. L. Miessler and D. A. Tarr "Inorganic Chemistry" 3rd Ed, Pearson/Prentice Hall publisher, . History Ligand field theory resulted from combining the principles laid out in molecular orbital theory and crystal field theory, which describes the loss of degeneracy of metal d orbitals in transition metal complexes. John Sta ...
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United States National Academy Of Sciences
The National Academy of Sciences (NAS) is a United States nonprofit, non-governmental organization. NAS is part of the National Academies of Sciences, Engineering, and Medicine, along with the National Academy of Engineering (NAE) and the National Academy of Medicine (NAM). As a national academy, new members of the organization are elected annually by current members, based on their distinguished and continuing achievements in original research. Election to the National Academy is one of the highest honors in the scientific field. Members of the National Academy of Sciences serve '' pro bono'' as "advisers to the nation" on science, engineering, and medicine. The group holds a congressional charter under Title 36 of the United States Code. Founded in 1863 as a result of an Act of Congress that was approved by Abraham Lincoln, the NAS is charged with "providing independent, objective advice to the nation on matters related to science and technology. ... to provide scie ...
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Myoglobin
Myoglobin (symbol Mb or MB) is an iron- and oxygen-binding protein found in the cardiac and skeletal muscle tissue of vertebrates in general and in almost all mammals. Myoglobin is distantly related to hemoglobin. Compared to hemoglobin, myoglobin has a higher affinity for oxygen and does not have cooperative binding with oxygen like hemoglobin does. In humans, myoglobin is only found in the bloodstream after muscle injury. (Google books link is the 2008 edition) High concentrations of myoglobin in muscle cells allow organisms to hold their breath for a longer period of time. Diving mammals such as whales and seals have muscles with particularly high abundance of myoglobin. Myoglobin is found in Type I muscle, Type II A, and Type II B; although many texts consider myoglobin not to be found in smooth muscle, this has proved erroneous: there is also myoglobin in smooth muscle cells. Myoglobin was the first protein to have its three-dimensional structure revealed by X-ray crystal ...
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Indenyl Effect
In organometallic chemistry, a transition metal indenyl complex is a coordination compound that contains one or more indenyl ligands. The indenyl ligand is formally the anion derived from deprotonation of indene. The η5-indenyl ligand is related to the η5cyclopentadienyl anion (Cp), thus indenyl analogues of many cyclopentadienyl complexes are known. Indenyl ligands lack the 5-fold symmetry of Cp, so they exhibit more complicated geometries. Furthermore, some indenyl complexes also exist with only η3-bonding mode. The η5- and η3-bonding modes sometimes interconvert. Preparation and structure Indene is deprotonated by butyl lithium and related reagents to give the equivalent of the indenyl anion: :C9H8 + BuLi → LiC9H7 + BuH The resulting lithium indenide can be used to prepare indenyl complexes by salt metathesis reactions of metal halides. When the metal halide is easily reduced, the trimethylstannylindenyl can be used as a source of indenyl anion: :Me3SnC9H7 + ...
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Evanston, Illinois
Evanston ( ) is a city, suburb of Chicago. Located in Cook County, Illinois, United States, it is situated on the North Shore along Lake Michigan. Evanston is north of Downtown Chicago, bordered by Chicago to the south, Skokie to the west, Wilmette to the north, and Lake Michigan to the east. Evanston had a population of 78,110 . Founded by Methodist business leaders in 1857, the city was incorporated in 1863. Evanston is home to Northwestern University, founded in 1851 before the city's incorporation, one of the world's leading research universities. Today known for its socially liberal politics and ethnically diverse population, Evanston was historically a dry city, until 1972. The city uses a council–manager system of government and is a Democratic stronghold. The city is heavily shaped by the influence of Chicago, externally, and Northwestern, internally. The city and the university share a historically complex long-standing relationship. History Prior to the 1830s, ...
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Rohm & Haas
Rohm and Haas Company is a manufacturer of specialty chemicals for end use markets such as building and construction, electronic devices, packaging, household and personal care products. Headquartered in Philadelphia, the company is organized into three business groups of Specialty Materials, Performance Materials and Electronic Materials, and also has two stand-alone businesses of Powder Coatings and Salt. Formerly a Fortune 500 Company, Rohm and Haas employs more than 17,000 people in 27 countries, with its last sales revenue reported as an independent company at US$8.9 billion. Dow Chemical Company bought Rohm and Haas for $15 billion in 2009. History The company was founded in Esslingen, Germany, by Dr. Otto Röhm and Mr. Otto Haas in 1907. Haas moved to Philadelphia and began the American side of the business on September 1, 1909, from an office on Front Street, while Otto Röhm remained in Germany to run a company that would eventually become Röhm GmbH. Röhm impro ...
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World War II
World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposing military alliances: the Allies and the Axis powers. World War II was a total war that directly involved more than 100 million personnel from more than 30 countries. The major participants in the war threw their entire economic, industrial, and scientific capabilities behind the war effort, blurring the distinction between civilian and military resources. Aircraft played a major role in the conflict, enabling the strategic bombing of population centres and deploying the only two nuclear weapons ever used in war. World War II was by far the deadliest conflict in human history; it resulted in 70 to 85 million fatalities, mostly among civilians. Tens of millions died due to genocides (including the Holocaust), starvation, ma ...
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Master In Chemistry
A Master of Chemistry (or MChem) degree is a specific master's degree for courses in the field of Chemistry. United Kingdom In the UK, the M.Chem degree is an undergraduate award, available after pursuing a four-year course of study at a university. It is classed as a level 7 qualification in the National Qualifications Framework. In Scotland the M.Chem degree is a 5-year course. Structure In terms of course structure, M.Chem degrees have the same content that is usually seen in other degree programmes, i.e. lectures, laboratory work, coursework and exams each year. There are also usually one or more substantial projects undertaken in the fourth year, which may well have research elements. At the end of the second or third years, there is usually a threshold of academic performance in examinations to be reached to allow progression into the final year. Final results are awarded on the standard British undergraduate degree classification scale. Chemistry Chemistry is t ...
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Bachelor Of Education
A Bachelor of Education (B.Ed.) is an undergraduate professional degree which prepares students for work as a teacher in schools. In some countries such as Tanzania and Kenya, additional tasks like field work and research are required in order for the student to be fully qualified to teach. It may also be accompanied with or followed by tests for licenses or certifications required for teachers in some areas. Countries where colleges and universities award the degree Argentina Since the Educational Reform of 2006, a National Institute for Teacher Education (INFD) was established to develop a standard and coherent teacher training structure throughout the country. According to the Argentine Ministry of Education, the creation of the INFD has helped greatly to reform the previous system establishing a national requirement of a 5-Year National Bachelor of Education to work across the nation at public schools, while there are private universities granting a 4-Year Provincial Bachelor ...
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Southern Illinois University
Southern Illinois University is a system of public universities in the southern region of the U.S. state of Illinois. Its headquarters is in Carbondale, Illinois. Board of trustees The university is governed by the nine member SIU Board of Trustees. Seven members are appointed by the governor and confirmed by the state senate. Two members are elected by the student bodies of the Carbondale and Edwardsville campuses. Southern Illinois University Carbondale Founded in Carbondale in 1869 as Southern Illinois Normal College, Southern Illinois University Carbondale (SIUC, usually referred to as SIU) is the flagship campus of the Southern Illinois University system and is the third oldest of Illinois's twelve state universities. SIUC includes six colleges: the College of Agricultural, Life, and Physical Sciences (CALPS), the College of Arts and Media (CAM), the College of Business and Analytics (CoBA), the College of Engineering, Computing, Technology, and Mathematics (CoECTM) ...
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George B
George may refer to: People * George (given name) * George (surname) * George (singer), American-Canadian singer George Nozuka, known by the mononym George * George Washington, First President of the United States * George W. Bush, 43rd President of the United States * George H. W. Bush, 41st President of the United States * George V, King of Great Britain, Ireland, the British Dominions and Emperor of India from 1910-1936 * George VI, King of Great Britain, Ireland, the British Dominions and Emperor of India from 1936-1952 * Prince George of Wales * George Papagheorghe also known as Jorge / GEØRGE * George, stage name of Giorgio Moroder * George Harrison, an English musician and singer-songwriter Places South Africa * George, Western Cape ** George Airport United States * George, Iowa * George, Missouri * George, Washington * George County, Mississippi * George Air Force Base, a former U.S. Air Force base located in California Characters * George (Peppa Pig), a 2-year-old pig ...
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