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Frank–Caro Process
The Frank–Caro process, also called cyanamide process, is the nitrogen fixation reaction of calcium carbide with nitrogen gas in a reactor vessel at about 1,000 °C. The reaction is exothermic and self-sustaining once the reaction temperature is reached. Originally the reaction took place in large steel cylinders with an electrical resistance element providing initial heat to start the reaction. Modern production uses rotating ovens. The synthesis produces a solid mixture of calcium cyanamide (CaCN2), also known as nitrolime, and carbon. :CaC2 + N2 → CaCN2 + C History The Frank–Caro process was the first commercial process that was used worldwide to fix atmospheric nitrogen. The product was used as fertilizer and commercially known as ''Lime-Nitrogen''. ''Nitrolim'' or ''Kalkstickstoff'' in German. The method was developed by the German chemists Adolph Frank and Nikodem Caro between 1895 and 1899. In its first decades, the world market for inorganic fertilizer was ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calcium Cyanamide
Calcium cyanamide is the inorganic compound with the formula CaCN2. It is the calcium salt of the cyanamide () anion. This chemical is used as fertilizer and is commercially known as nitrolime. It was first synthesized in 1898 by Adolph Frank and Nikodem Caro (Frank–Caro process). History In their search for a new process for producing cyanides for cyanide leaching of gold, Frank and Caro discovered the ability of alkaline earth carbides to absorb atmospheric nitrogen at high temperatures. Fritz Rothe, a colleague of Frank and Caro, succeeded in 1898 in overcoming problems with the use of calcium carbide and clarified that at around 1,100 °C not calcium cyanide but calcium cyanamide is formed in the reaction. In fact, the initial target product sodium cyanide can also be obtained from calcium cyanamide by melting it with sodium chloride in the presence of carbon: : CaCN2 + 2 NaCl + C → 2 NaCN + CaCl2 Frank and Caro developed this reaction for a large-scale ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bromberg
Bydgoszcz ( , , ; german: Bromberg) is a city in northern Poland, straddling the meeting of the River Vistula with its left-bank tributary, the Brda. With a city population of 339,053 as of December 2021 and an urban agglomeration with more than 470,000 inhabitants, Bydgoszcz is the eighth-largest city in Poland. It is the seat of Bydgoszcz County and the co-capital, with Toruń, of the Kuyavian-Pomeranian Voivodeship. The city is part of the Bydgoszcz–Toruń metropolitan area, which totals over 850,000 inhabitants. Bydgoszcz is the seat of Casimir the Great University, University of Technology and Life Sciences and a conservatory, as well as the Medical College of Nicolaus Copernicus University in Toruń. It also hosts the Pomeranian Philharmonic concert hall, the Opera Nova opera house, and Bydgoszcz Airport. Being between the Vistula and Oder (Odra in Polish) rivers, and by the Bydgoszcz Canal, the city is connected via the Noteć, Warta, Elbe and German canals with th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyanamides
Cyanamide is an organic compound with the formula C N2 H2. This white solid is widely used in agriculture and the production of pharmaceuticals and other organic compounds. It is also used as an alcohol-deterrent drug. The molecule features a nitrile group attached to an amino group. Derivatives of this compound are also referred to as cyanamides, the most common being calcium cyanamide (CaCN2). Tautomers and self-condensations Containing both a nucleophilic and electrophilic site within the same molecule, cyanamide undergoes various reactions with itself. Cyanamide exists as two tautomers, one with the connectivity N≡C–NH2 and the other with the formula HN=C=NH ("carbodiimide" tautomer). The N≡C–NH2 form dominates, but in a few reactions (e.g. silylation) the diimide form appears to be important. Cyanamide dimerizes to give 2-cyanoguanidine (dicyandiamide). This dimerization is disfavored by acids and is inhibited by low temperatures. The cyclic trimer is called mel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Water Gas
Water gas is a kind of fuel gas, a mixture of carbon monoxide and hydrogen. It is produced by "alternately hot blowing a fuel layer okewith air and gasifying it with steam". The caloric yield of this is about 10% of a modern syngas plant. Further making this technology unattractive, its precursor coke is expensive, whereas syngas uses cheaper precursor, mainly methane from natural gas. Production Synthesis gas is made by passing steam over a red-hot carbon fuel such as coke: : (ΔH = +131 kJ/mol) The reaction is endothermic, so the fuel must be continually re-heated to maintain the reaction. To do this, an air stream, which alternates with the vapor stream, is introduced to combust some of the carbon: : (ΔH = -393 kJ/mol) Theoretically, to make 6 L of water gas, 5 L of air is required. Alternatively, to prevent contamination with nitrogen, energy can be provided by using pure oxygen to burn carbon into carbon monoxide. : (ΔH = -221 kJ/mol) In this case, 1&nbs ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Linde–Frank–Caro Process
The Linde–Frank–Caro process is a method for hydrogen production by removing hydrogen and carbon dioxide from water gas by condensation. The process was invented in 1909 by Adolf Frank and developed with Carl von Linde and Heinrich Caro. p. 30. Process description Water gas is compressed to 20 and pumped into the Linde-Frank-Caro reactor. A water column removes most of the carbon dioxide and . Tubes with |
Haber–Bosch Process
The Haber process, also called the Haber–Bosch process, is an artificial nitrogen fixation process and is the main industrial procedure for the production of ammonia today. It is named after its inventors, the German chemists Fritz Haber and Carl Bosch, who developed it in the first decade of the 20th century. The process converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using a metal catalyst under high temperatures and pressures: : \ce \quad \Delta H^\circ = -91.8~\text Though this reaction is exothermic (i.e. it releases energy, albeit not very much), it results in a decrease in entropy, which is the central reason why it is very challenging to carry out. Before the development of the Haber process, it had been difficult to produce ammonia on an industrial scale, with early methods, such as the Birkeland–Eyde process and the Frank–Caro process, all highly inefficient. During World War I, the Haber process provided Germany with a sou ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Birkeland–Eyde Process
The Birkeland–Eyde process was one of the competing industrial processes in the beginning of nitrogen-based fertilizer production. It is a multi-step nitrogen fixation reaction that uses electrical arcs to react atmospheric nitrogen (N2) with oxygen (O2), ultimately producing nitric acid (HNO3) with water. The resultant nitric acid was then used as a source of nitrate (NO3−) in the reaction HNO3 + H2O -> H3O+ + NO3- which may take place in the presence of water or another proton acceptor. It was developed by Norwegian industrialist and scientist Kristian Birkeland along with his business partner Sam Eyde in 1903, based on a method used by Henry Cavendish in 1784. A factory based on the process was built in Rjukan and Notodden in Norway, combined with the building of large hydroelectric power facilities. The Birkeland–Eyde process is relatively inefficient in terms of energy consumption. Therefore, in the 1910s and 1920s, it was gradually replaced in Norway by a combination ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Odda Process
The nitrophosphate process (also known as the Odda process) is a method for the industrial production of nitrogen fertilizers invented by Erling Johnson in the municipality of Odda, Norway around 1927. The process involves acidifying phosphate rock with dilute nitric acid to produce a mixture of phosphoric acid and calcium nitrate. :Ca5(PO4)3OH + 10 HNO3 → 3 H3PO4 + 5 Ca(NO3)2 + H2O The mixture is cooled to below 0 °C, where the calcium nitrate crystallizes and can be separated from the phosphoric acid. :2 H3PO4 + 3 Ca(NO3)2 + 12 H2O → 2 H3PO4 + 3 Ca(NO3)2·4H2O The resulting calcium nitrate produces nitrogen fertilizer. The filtrate is composed mainly of phosphoric acid with some nitric acid and traces of calcium nitrate, and this is neutralized with ammonia to produce a compound fertilizer. :Ca(NO3)2 + 4 H3PO4 + 8 NH3 → CaHPO4 + 2 NH4NO3 + 3(NH4)2HPO4 If potassium chloride or potassium sulfate is added, the result will be NPK fertilizer. The process was an inn ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Haber Process
The Haber process, also called the Haber–Bosch process, is an artificial nitrogen fixation process and is the main industrial procedure for the production of ammonia today. It is named after its inventors, the German chemists Fritz Haber and Carl Bosch, who developed it in the first decade of the 20th century. The process converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using a metal catalyst under high temperatures and pressures: : \ce \quad \Delta H^\circ = -91.8~\text Though this reaction is exothermic (i.e. it releases energy, albeit not very much), it results in a decrease in entropy, which is the central reason why it is very challenging to carry out. Before the development of the Haber process, it had been difficult to produce ammonia on an industrial scale, with early methods, such as the Birkeland–Eyde process and the Frank–Caro process, all highly inefficient. During World War I, the Haber process provided Germany with a so ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
UNESCO World Heritage List
A World Heritage Site is a landmark or area with legal protection by an international convention administered by the United Nations Educational, Scientific and Cultural Organization (UNESCO). World Heritage Sites are designated by UNESCO for having cultural, historical, scientific or other form of significance. The sites are judged to contain "cultural and natural heritage around the world considered to be of outstanding value to humanity". To be selected, a World Heritage Site must be a somehow unique landmark which is geographically and historically identifiable and has special cultural or physical significance. For example, World Heritage Sites might be ancient ruins or historical structures, buildings, cities, deserts, forests, islands, lakes, monuments, mountains, or wilderness areas. A World Heritage Site may signify a remarkable accomplishment of humanity, and serve as evidence of our intellectual history on the planet, or it might be a place of great natural beauty. As ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Knapsack, Germany
Knapsack is a locality of Hürth, Rhine-Erft district, North Rhine-Westphalia, Germany. On Wednesday 17 October 2007, King Harald of Norway opened Statkraft's first gas power plant at Knapsack in Germany. The plant will have an installed capacity of 800 MW. History Knapsack, its first documentary mention in 1566, started to emerge into a notable village after 1900 due to establishment and development of industry (1906 the Knapsack-Griesheim AG, later part of the Hoechst AG; 1913 construction of the brown coal power plant Goldenberg-Werk) During World War II the RAF bombed the Knapsack power-station several times. The first raid was a low-level daylight raid on 12 August 1941 by 54 Bristol Blenheims under the command of Wing Commander Nichol of No. 114 Squadron RAF. The Blenheims hit their targets (the Goldenberg Power Station in Knapsack and the Fortuna Power Station in Quadrath) but twelve of the Blenheims were lost during the raid, 22 percent of those that took part whi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Poland
Poland, officially the Republic of Poland, is a country in Central Europe. It is divided into 16 administrative provinces called voivodeships, covering an area of . Poland has a population of over 38 million and is the fifth-most populous member state of the European Union. Warsaw is the nation's capital and largest metropolis. Other major cities include Kraków, Wrocław, Łódź, Poznań, Gdańsk, and Szczecin. Poland has a temperate transitional climate and its territory traverses the Central European Plain, extending from Baltic Sea in the north to Sudeten and Carpathian Mountains in the south. The longest Polish river is the Vistula, and Poland's highest point is Mount Rysy, situated in the Tatra mountain range of the Carpathians. The country is bordered by Lithuania and Russia to the northeast, Belarus and Ukraine to the east, Slovakia and the Czech Republic to the south, and Germany to the west. It also shares maritime boundaries with Denmark and Sweden. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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