Fluorotelomers
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Fluorotelomers
Fluorotelomers are fluorocarbon-based oligomers, or telomers, synthesized by telomerization. Some fluorotelomers and fluorotelomer-based chemical compound, compounds are a source of environmentally persistent perfluorinated carboxylic acids such as Perfluorooctanoic acid, PFOA and Perfluorononanoic acid, PFNA, while others are under extended investigation. Types There are many broad categories of fluorotelomers: * Fluorotelomer alcohols (FTOH) * Fluorotelomer ethoxylates (FTEO) * Fluorotelomer fumarates * Fluorotelomer methacrylates (FTMAC) * Fluorotelomer sulphonates (FTS) Manufacture In the Radical (chemistry), radical telomerization of fluorotelomer molecules, a variety of fluorinated alkenes can serve as Saturated and unsaturated compounds, unsaturated taxogens including tetrafluoroethylene, vinylidene fluoride, chlorotrifluoroethylene, and hexafluoropropene. However, many fluorotelomers, such as fluorotelomer alcohols, are fluorocarbon-based because they are synthesized from t ...
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Fluorotelomer Fumarate
Fluorotelomers are fluorocarbon-based oligomers, or telomers, synthesized by telomerization. Some fluorotelomers and fluorotelomer-based chemical compound, compounds are a source of environmentally persistent perfluorinated carboxylic acids such as Perfluorooctanoic acid, PFOA and Perfluorononanoic acid, PFNA, while others are under extended investigation. Types There are many broad categories of fluorotelomers: * Fluorotelomer alcohols (FTOH) * Fluorotelomer ethoxylates (FTEO) * Fluorotelomer fumarates * Fluorotelomer methacrylates (FTMAC) * Fluorotelomer sulphonates (FTS) Manufacture In the Radical (chemistry), radical telomerization of fluorotelomer molecules, a variety of fluorinated alkenes can serve as Saturated and unsaturated compounds, unsaturated taxogens including tetrafluoroethylene, vinylidene fluoride, chlorotrifluoroethylene, and hexafluoropropene. However, many fluorotelomers, such as fluorotelomer alcohols, are fluorocarbon-based because they are synthesized from t ...
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Fluorotelomer Methacrylate
Fluorotelomers are fluorocarbon-based oligomers, or telomers, synthesized by telomerization. Some fluorotelomers and fluorotelomer-based chemical compound, compounds are a source of environmentally persistent perfluorinated carboxylic acids such as Perfluorooctanoic acid, PFOA and Perfluorononanoic acid, PFNA, while others are under extended investigation. Types There are many broad categories of fluorotelomers: * Fluorotelomer alcohols (FTOH) * Fluorotelomer ethoxylates (FTEO) * Fluorotelomer fumarates * Fluorotelomer methacrylates (FTMAC) * Fluorotelomer sulphonates (FTS) Manufacture In the Radical (chemistry), radical telomerization of fluorotelomer molecules, a variety of fluorinated alkenes can serve as Saturated and unsaturated compounds, unsaturated taxogens including tetrafluoroethylene, vinylidene fluoride, chlorotrifluoroethylene, and hexafluoropropene. However, many fluorotelomers, such as fluorotelomer alcohols, are fluorocarbon-based because they are synthesized from t ...
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Fluorotelomer Ethoxylate
Fluorotelomers are fluorocarbon-based oligomers, or telomers, synthesized by telomerization. Some fluorotelomers and fluorotelomer-based compounds are a source of environmentally persistent perfluorinated carboxylic acids such as PFOA and PFNA, while others are under extended investigation. Types There are many broad categories of fluorotelomers: * Fluorotelomer alcohols (FTOH) * Fluorotelomer ethoxylates (FTEO) * Fluorotelomer fumarates * Fluorotelomer methacrylates (FTMAC) * Fluorotelomer sulphonates (FTS) Manufacture In the radical telomerization of fluorotelomer molecules, a variety of fluorinated alkenes can serve as unsaturated taxogens including tetrafluoroethylene, vinylidene fluoride, chlorotrifluoroethylene, and hexafluoropropene. However, many fluorotelomers, such as fluorotelomer alcohols, are fluorocarbon-based because they are synthesized from tetrafluoroethylene. In addition to alcohols, synthetic products include fluorotelomer iodides, olefins, and acrylate mo ...
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Fluorotelomer Sulphonate
Fluorotelomers are fluorocarbon-based oligomers, or telomers, synthesized by telomerization. Some fluorotelomers and fluorotelomer-based compounds are a source of environmentally persistent perfluorinated carboxylic acids such as PFOA and PFNA, while others are under extended investigation. Types There are many broad categories of fluorotelomers: * Fluorotelomer alcohols (FTOH) * Fluorotelomer ethoxylates (FTEO) * Fluorotelomer fumarates * Fluorotelomer methacrylates (FTMAC) * Fluorotelomer sulphonates (FTS) Manufacture In the radical telomerization of fluorotelomer molecules, a variety of fluorinated alkenes can serve as unsaturated taxogens including tetrafluoroethylene, vinylidene fluoride, chlorotrifluoroethylene, and hexafluoropropene. However, many fluorotelomers, such as fluorotelomer alcohols, are fluorocarbon-based because they are synthesized from tetrafluoroethylene. In addition to alcohols, synthetic products include fluorotelomer iodides, olefins, and acrylate m ...
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Perfluorooctanoic Acid
Perfluorooctanoic acid (PFOA; conjugate base perfluorooctanoate; also known colloquially as C8, for its 8 carbon chain structure) is a perfluorinated carboxylic acid produced and used worldwide as an industrial surfactant in chemical processes and as a material feedstock. PFOA is considered a surfactant, or fluorosurfactant, due to its chemical structure, which consists of a perfluorinated, ''n''-octyl "tail group" and a carboxylate "head group". The head group can be described as hydrophilic while the fluorocarbon tail is both hydrophobic and lipophobic. The tail group is inert and does not interact strongly with polar or non-polar chemical moieties; the head group is reactive and interacts strongly with polar groups, specifically water. The "tail" is hydrophobic due to being non-polar and lipophobic because fluorocarbons are less susceptible to the London dispersion force than hydrocarbons. PFOA is one of many synthetic organofluorine compounds collectively known as per- and po ...
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Acrylate
Acrylates (IUPAC: prop-2-enoates) are the salts, esters, and conjugate bases of acrylic acid. The acrylate ion is the anion C H2=CHC OO−. Often, acrylate refers to esters of acrylic acid, the most common member being methyl acrylate. These acrylates contain vinyl groups. These compounds are of interest because they are bifunctional: the vinyl group is susceptible to polymerization and the carboxylate group carries myriad functionalities. Modified acrylates are also numerous, some examples being methacrylates (CH2=C(CH3)CO2R) and cyanoacrylates (CH2=C(CN)CO2R). Acrylate can also refer to polyacrylates prepared through the polymerization of the vinyl groups of acrylate monomers. File:Acrylate-anion.svg, The acrylate anion File:Trimethylolpropane triacrylate.svg, Trimethylolpropane triacrylate (TMPTA), a trifunctional acrylate ester File:Methylacrylat.svg, Methyl acrylate, an acrylic ester File:Hexandioldiacrylat.svg, Hexandiol diacrylate, a bifunctional acrylate File:Methyl-meth ...
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Monomer
In chemistry, a monomer ( ; ''mono-'', "one" + '' -mer'', "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or three-dimensional network in a process called polymerization. Classification Monomers can be classified in many ways. They can be subdivided into two broad classes, depending on the kind of the polymer that they form. Monomers that participate in condensation polymerization have a different stoichiometry than monomers that participate in addition polymerization: : Other classifications include: *natural vs synthetic monomers, e.g. glycine vs caprolactam, respectively *polar vs nonpolar monomers, e.g. vinyl acetate vs ethylene, respectively *cyclic vs linear, e.g. ethylene oxide vs ethylene glycol, respectively The polymerization of one kind of monomer gives a homopolymer. Many polymers are copolymers, meaning that they are derived from two different monomers. In the case of condensation polymerizations, the r ...
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Polymer
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros'' ...
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Lipophobicity
Lipophobicity, also sometimes called lipophobia (from the Greek λιποφοβία from λίπος ''lipos'' "fat" and φόβος ''phobos'' "fear"), is a chemical property of chemical compounds which means "fat rejection", literally "fear of fat". Lipophobic compounds are those not soluble in lipids or other non-polar solvents. From the other point of view, they do not absorb fats. "Oleophobic" (from the Latin ''oleum'' "oil", Greek ελαιοφοβικό ''eleophobico'' from έλαιο ''eleo'' "oil" and φόβος ''phobos'' "fear") refers to the physical property of a molecule that is seemingly repelled from oil. (Strictly speaking, there is no repulsive force involved; it is an absence of attraction.) The most common lipophobic substance is water. Fluorocarbons are also lipophobic/oleophobic in addition to being hydrophobic. Uses A lipophobic coating has been used on the touchscreens of Apple's iPhones since the 3GS, their iPads, Nokia's N9 and Lumia devices, the HTC HD2 ...
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Metabolized
Metabolism (, from el, μεταβολή ''metabolē'', "change") is the set of life-sustaining chemical reactions in organisms. The three main functions of metabolism are: the conversion of the energy in food to energy available to run cellular processes; the conversion of food to building blocks for proteins, lipids, nucleic acids, and some carbohydrates; and the elimination of metabolic wastes. These enzyme-catalyzed reactions allow organisms to grow and reproduce, maintain their structures, and respond to their environments. The word metabolism can also refer to the sum of all chemical reactions that occur in living organisms, including digestion and the transportation of substances into and between different cells, in which case the above described set of reactions within the cells is called intermediary (or intermediate) metabolism. Metabolic reactions may be categorized as ''catabolic'' – the ''breaking down'' of compounds (for example, of glucose to pyruvate by cel ...
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