|
Flavan
The flavans are benzopyran derivatives that use the 2-phenyl-3,4-dihydro-2''H''-chromene skeleton. They may be found in plants. These compounds include the flavan-3-ols, flavan-4-ols and flavan-3,4-diols (leucoanthocyanidin). A ''C''-glycosidic flavan can be isolated from cocoa liquor. ''Casuarina glauca'' is an actinorhizal plant producing root nitrogen-fixing nodules infested by ''Frankia ''Frankia'' is a genus of nitrogen-fixing bacteria that live in symbiosis with actinorhizal plants, similar to the ''Rhizobium'' bacteria found in the root nodules of legumes in the family Fabaceae. ''Frankia'' also initiate the forming of root ...''. There is a regular pattern of cell layers containing flavans. References {{Aromatic-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flavan-3-ol
Flavan-3-ols (sometimes referred to as flavanols) are a subgroup of flavonoids. They are derivatives of flavans that possess a 2-phenyl-3,4-dihydro-2''H''-chromen-3-ol skeleton. Flavan-3-ols are structurally diverse and include a range of compounds, such as catechin, epicatechin gallate, epigallocatechin, epigallocatechin gallate, proanthocyanidins, theaflavins, thearubigins. They are found in most plants and have a role in plant defense. Chemical structure The single-molecule (monomer) catechin, or isomer epicatechin (see diagram), adds four hydroxyls to flavan-3-ol, making building blocks for concatenated polymers (proanthocyanidins) and higher order polymers (anthocyanidins). Flavan-3-ols possess two chiral carbons, meaning four diastereoisomers occur for each of them. They are distinguished from the yellow, ketone-containing flavonoids such as quercitin and rutin, which are called flavonols. Early use of the term bioflavonoid was imprecisely applied to include the flava ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flavan-4-ols
The flavan-4-ols (3-deoxyflavonoids) are flavone-derived alcohols and a family of flavonoids. Flavan-4-ols are colorless precursor compounds that polymerize to form red phlobaphene pigments. They can be found in the sorghum. Glycosides (abacopterins A, B, C and D together with triphyllin A and 6,8-dimethyl-7-hydroxy-4‘-methoxyanthocyanidin-5-O-β-d-glucopyranoside) can be isolated from a methanol extract of the rhizomes of ''Abacopteris penangiana''. Known flavan-4-ols * Apiforol * Luteoforol Metabolism Flavanone 4-reductase is an enzyme that uses (2''S'')-flavan-4-ol and NADP+ to produce (2''S'')-flavanone The flavanones, a type of flavonoids, are various aromatic, colorless ketones derived from flavone that often occur in plants as glycosides. List of flavanones * Blumeatin * Butin * Eriodictyol * Hesperetin * Hesperidin * Homoeriodictyol * ..., NADPH, and H+. Spectral data These compounds have absorption maxima of 564 nm. References {{flavan-4ol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flavan-3,4-diol
Leucoanthocyanidin (flavan-3,4-diols) are colorless chemical compounds related to anthocyanidins and anthocyanins. Leucoanthocyanins can be found in ''Anadenanthera peregrina'' and in several species of ''Nepenthes'' including ''Nepenthes burbidgeae, N. burbidgeae'', ''Nepenthes muluensis, N. muluensis'', ''Nepenthes rajah, N. rajah'', ''Nepenthes tentaculata, N. tentaculata'', and ''Nepenthes × alisaputrana, N. × alisaputrana''. Such compounds include: * Leucocyanidin * Leucodelphinidin * Leucofisetinidin * Leucomalvidin * Leucopelargonidin * Leucopeonidin * Leucorobinetinidin * Melacacidin * Teracacidin from ''Acacia obtusifolia'' and ''Acacia maidenii'' heartwoods Leucoanthocyanidins have been demonstrated to be intermediates in anthocyanidin biosynthesis in flowers of ''Matthiola incana''. Edgar Charles Bate-Smith, Bate-smith recommended in 1954 the use of the Forestal solvent for the isolation of leuco-anthocyanins. Metabolism Leucoanthocyanid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Leucoanthocyanidin
Leucoanthocyanidin (flavan-3,4-diols) are colorless chemical compounds related to anthocyanidins and anthocyanins. Leucoanthocyanins can be found in '' Anadenanthera peregrina'' and in several species of '' Nepenthes'' including '' N. burbidgeae'', '' N. muluensis'', '' N. rajah'', '' N. tentaculata'', and '' N. × alisaputrana''. Such compounds include: * Leucocyanidin * Leucodelphinidin * Leucofisetinidin * Leucomalvidin * Leucopelargonidin * Leucopeonidin * Leucorobinetinidin * Melacacidin * Teracacidin from '' Acacia obtusifolia'' and '' Acacia maidenii'' heartwoods Leucoanthocyanidins have been demonstrated to be intermediates in anthocyanidin biosynthesis in flowers of ''Matthiola incana''. Bate-smith recommended in 1954 the use of the Forestal solvent for the isolation of leuco-anthocyanins. Metabolism Leucoanthocyanidin dioxygenase uses flavan-3,4-diols to produce 3-hydroxyanthocyanidins. The gene encoding the enzyme (PpLDOX) ha ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Casuarina Glauca
''Casuarina glauca'', commonly known as the swamp she-oak, swamp oak, grey oak, or river oak, is a species of ''Casuarina'' native to the east coast of Australia. It is found from central Queensland south to southern New South Wales. It has become naturalised in the Everglades in Florida where it is considered a weed. Taxonomy Franz Sieber described the swamp oak as ''Casuarina glauca'' in 1826. The species name is derived from the Latin ''glauca'' "glaucous". The Kabi name for the plant, ''bilai'', was used for the town and locality of Bli Bli, Queensland. The gadigal name is ''guman''. It is closely related to ''C. cunninghamiana''. Hybrids with ''C. cunninghamiana'' subsp. ''cunninghamiana'' have been recorded where the two species co-occur, such as at Lower Portland and Wisemans Ferry. Description left, closeup of new growth, showing segmented branchlets with tiny brown teethlike leaves at nodes of segments The swamp oak grows as medium sized tree, 8–20 m high tree, or ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Benzopyran
Benzopyran is a polycyclic organic compound that results from the fusion of a benzene ring to a heterocyclic pyran ring. According to current IUPAC nomenclature, the name chromene used in previous recommendations is retained; however, systematic ‘benzo’ names, for example 2''H''-1-benzopyran, are preferred IUPAC names for chromene, isochromene, chromane, isochromane, and their chalcogen analogues. There are two isomers of benzopyran that vary by the orientation of the fusion of the two rings compared to the oxygen, resulting in 1-benzopyran (chromene) and 2-benzopyran (isochromene)—the number denotes where the oxygen atom is located by standard naphthalene-like nomenclature. Some benzopyrans have shown anticancerous activity ''in vitro''. The radical form of benzopyran is paramagnetic. The unpaired electron is delocalized over the whole benzopyran molecule, rendering it less reactive than one would expect otherwise. A similar example is the cyclopentadienyl radical. Co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cocoa Liquor
Chocolate liquor (cocoa liquor) is pure cocoa mass (cocoa paste) in solid or semi-solid form. Like the cocoa beans (nibs) from which it is produced, it contains both cocoa solids and cocoa butter in roughly equal proportion. It is produced from cocoa beans that have been fermented, dried, roasted, and separated from their skins. The beans are ground into cocoa mass (cocoa paste). The mass is melted to become the liquor, and the liquor is either separated into cocoa solids and cocoa butter, or cooled and molded into blocks of raw chocolate. Its main use (often with additional cocoa butter) is in making chocolate. The name ''liquor'' is used not in the sense of a distilled, alcoholic substance, but rather the older meaning of the word, meaning 'liquid' or 'fluid'. Chocolate liquor contains roughly 53 percent cocoa butter (fat), about 17 percent carbohydrates, 11 percent protein, 6 percent tannins, and 1.5 percent theobromine.Wolke, Robert L. (2005). '' What Einstein Told His ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Actinorhizal Plant
Actinorhizal plants are a group of angiosperms characterized by their ability to form a symbiosis with the nitrogen fixing actinomycetota ''Frankia''. This association leads to the formation of nitrogen-fixing root nodules. Classification Actinorhizal plants are dicotyledons distributed among three angiosperm orders, 8 families and 25 genera: These three orders form a single clade within the Rosids, which is a sister taxon to the other major nitrogen-fixing order, the Fabales. All actinorhizal species are trees or shrubs, except for the genus ''Datisca''. Many are common plants in temperate regions like alder, bayberry, sweetfern, Avens, mountain misery and ''Coriaria''. Some ''Elaeagnus'' species and Sea-buckthorns produce edible fruit. In tropical regions, ''Casuarinas'' are widely cultivated. Distribution and ecology Actinorhizal plants are found on all continents except for Antarctica. Their ability to form nitrogen-fixing nodules confers a selective advantage in poor soils ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Frankia
''Frankia'' is a genus of nitrogen-fixing bacteria that live in symbiosis with actinorhizal plants, similar to the ''Rhizobium'' bacteria found in the root nodules of legumes in the family Fabaceae. ''Frankia'' also initiate the forming of root nodules. This genus was originally named by Jørgen Brunchorst, in 1886 to honor the German biologist Albert Bernhard Frank. Brunchorst considered the organism he had identified to be a filamentous fungus. redefined the genus in 1970 as containing prokaryotic actinomycetes and created the family Frankiaceae within the Actinomycetales. He retained the original name of ''Frankia'' for the genus. Overview Most ''Frankia'' strains are specific to different plant species. The bacteria are filamentous and convert atmospheric nitrogen into ammonia via the enzyme nitrogenase, a process known as nitrogen fixation. They do this while living in root nodules on actinorhizal plants. The bacteria can supply most or all of the nitrogen requirement ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
