Finishing Oil
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Finishing Oil
A finishing oil is a vegetable oil used for wood finishing. These finishes are a historical finish for wood, primarily as means of making it weather or moisture resistant. Finishing oils are easily applied, by wiping with a cloth. They are also simply made, by extraction from plant sources with relatively simple processing. Historically, both of these were considerable advantages over varnishes, that depended upon exotic imported plant resins, complex preparation and careful application with expensive brushes. The two most important finishing oils, to this day, are linseed oil and tung oil. Linseed oil is extracted from the seeds of the flax plant, already extensively grown for the production of linen. The raw oil may be used, but it cures poorly and leaves a sticky surface. Normally boiled linseed oil is used. This has been prepared beforehand by boiling with lead, in the form of lead oxide, or with manganese salts. Modern boiled oils use a lead-free metallic oil drying agent, d ...
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Vegetable Oil
Vegetable oils, or vegetable fats, are oils extracted from seeds or from other parts of fruits. Like animal fats, vegetable fats are ''mixtures'' of triglycerides. Soybean oil, grape seed oil, and cocoa butter are examples of seed oils, or fats from seeds. Olive oil, palm oil, and rice bran oil are examples of fats from other parts of fruits. In common usage, vegetable ''oil'' may refer exclusively to vegetable fats which are liquid at room temperature. Vegetable oils are usually edible. Uses In antiquity Oils extracted from plants have been used since ancient times and in many cultures. Archaeological evidence shows that olives were turned into olive oil by 6000 BCE and 4500 BCE in present-day Israel and Palestine. In addition to use as food, fats and oils (both vegetable and mineral) have long been used as fuel, typically in lamps which were a principal source of illumination in ancient times. Oils may have been used for lubrication, but there is no evidence for this. Veg ...
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Oil Drying Agent
An oil drying agent, also known as siccative, is a coordination compound that accelerates ( catalyzes) the hardening of drying oils, often as they are used in oil-based paints. This so-called "drying" (actually a chemical reaction that produces an organic plastic) occurs through free-radical chemical crosslinking of the oils. The catalysts promote this free-radical autoxidation of the oils with air. Typical oil drying agents are derived from ions of cobalt, manganese, and iron, prepared as "salts" of lipophilic carboxylic acids such as naphthenic acids, in order to give them a soap-like chemical formula and make them oil-soluble. Varieties of drying agents In technical literature, oil drying agents, such as naphthenates, are described as salts, but they are probably also non-ionic coordination complexes with structures similar to basic zinc acetate. These catalysts were traditionally hydrocarbon carboxylate chelates of lead, but due to lead's toxicity, cobalt and other elements, s ...
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Spar Varnish
Spar varnish (occasionally also called boat varnish or yacht varnish) is a wood-finishing varnish, originally developed for coating the spars of sailing ships. These formed part of the masts and rigging, and had to withstand rough condition, being flexed by the wind loads they supported, attacked by sea and bad weather, and suffering from UV degradation from long-term exposure to sunlight. The most important condition for such varnishes to resist was flexing. This required a varnish that was flexible and elastic. Without elasticity, the varnish would soon crack, allowing water to penetrate to the wood beneath. At the time, varnish production was rudimentary and had only simple materials with which to work. It pre-dated the development of modern polymer chemistry. The original sort of spar varnish was a "short oil" varnish, in which a small proportion of a finishing oil, usually boiled linseed oil, was the majority proportion of the varnish. This gave flexibility, even though its w ...
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Danish Oil
Danish oil is a wood finishing oil, often made of tung oil or polymerized linseed oil. Because there is no defined formulation, its composition varies among manufacturers. Danish oil is a hard drying oil, meaning it can polymerize into a solid form when it reacts with oxygen in the atmosphere. It can provide a hard-wearing, often water-resistant satin finish, or serve as a primer on bare wood before applying paint or varnish. It is a "long oil" finish, a mixture of oil and varnish, typically around one-third varnish and the rest oil. Uses When applied in coats over wood, Danish oil cures to a hard satin finish that resists liquid well. As the finished coating is not glossy or slippery, it is a suitable finish for items such as food utensils or tool handles, giving some additional water resistance and also leaves a dark finish to the wood. Special dyed grades are available if wood staining is also needed. Application Compared to varnish it is simple to apply, usually a course of th ...
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White Spirit
White spirit (AU, UK & Ireland)Primarily in the United Kingdom and Australia. In New Zealand "white spirit" can also refer to Coleman fuel (white gas). or mineral spirits (US, Canada), also known as mineral turpentine (AU/NZ), turpentine substitute, and petroleum spirits, is a petroleum-derived clear liquid used as a common organic solvent in painting. There are also terms for specific kinds of white spirit, including Stoddard solvent and solvent naphtha (petroleum). White spirit is often used as a paint thinner, or as a component thereof, though paint thinner is a broader category of solvent. Odorless mineral spirits (OMS) have been refined to remove the more toxic aromatic compounds, and are recommended for applications such as oil painting. A mixture of aliphatic, open-chain or alicyclic C7 to C12 hydrocarbons, white spirit is insoluble in water and is used as an extraction solvent, as a cleaning solvent, as a degreasing solvent and as a solvent in aerosols, paints, wood pres ...
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Tung Tree
''Vernicia fordii'', usually known as the tung tree (, ''tóng'') is a species of flowering plant in the spurge family native to southern China, Myanmar, and northern Vietnam. It is a small to medium-sized deciduous tree growing to 20 m tall, with a spreading crown. The bark is smooth and thin, and bleeds latex if cut. The leaves are alternate, simple, 4.5–25 cm long and 3.5–22 cm broad, heart-shaped or with three shallow, maple-like lobes, green above and below, red conspicuous glands at the base of the leaf, and with a 5.5–26 cm long petiole. The flowers are 2.5–3.5 cm diameter, with five pale pink to purple petals with streaks of darker red or purple in the throat; it is monoecious with individual flowers either male or female, but produced together in the inflorescences. The flowers appear before or with the leaves in loose, terminal clusters. The fruit is a hard, woody pear-shaped berry 4–6 cm long and 3–5 cm diameter, containing ...
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Tung Oil
Tung oil or China wood oil is a drying oil obtained by pressing the seed from the nut of the tung tree (''Vernicia fordii''). The oil and its use are believed to have originated in ancient China and appear in the writings of Confucius from about 400 BC. Tung oil hardens upon exposure to air (through polymerization), and the resulting coating is transparent and has a deep, almost wet look. Used mostly for finishing and protecting wood, after numerous coats, the finish can even look plastic-like. Related drying oils include linseed, safflower, poppy, and soybean oils. Raw tung oil tends to dry to a fine, wrinkled finish (the English name for this is gas checking); this property was used to make wrinkle finishes, usually by adding excess cobalt drier. To prevent wrinkling, the oil is heated to gas-proof it (also known as "boiled"). 'Tung oil' is often used by paint and varnish manufacturers as a generic name for any wood-finishing product that contains the real tung oil or provid ...
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Oilcloth
Oilcloth, also known as enameled cloth or American cloth, is close-woven cotton duck or linen cloth with a coating of boiled linseed oil to make it waterproof. Manufacture Boiled linseed oil was prepared by a long boiling of linseed oil with metal salts, originally lead dross. The modern oil is less toxic, but also less suitable for making oilcloth. Re-enactors may boil their own oil in the search for a correctly coloured oilcloth. Oilcloth used for weatherproofing may have used a mixture of lead and manganese salts, the sienna and umber pigments, to give a more humidity-resistant cure. The fabric was first stretched on a tenter frame and sized with animal gelatine. The oil was then applied and allowed to cure between coats. As the cure relies on oxidation by the air, thin coats and long cure times between are required. Overlaps between sheets of fresh oilcloth would amalgamate naturally when pressed together. This tendency also led to the cloth sticking together when folded. ...
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Cobalt Resinate
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal. Cobalt-based blue pigments (cobalt blue) have been used since ancient times for jewelry and paints, and to impart a distinctive blue tint to glass, but the color was for a long time thought to be due to the known metal bismuth. Miners had long used the name ''kobold ore'' (German for ''goblin ore'') for some of the blue-pigment-producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes when smelted. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the ''kobold''. Today, some cobalt is produced specifically from one of ...
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Manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of the ...
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Wood Finishing
Wood finishing refers to the process of refining or protecting a wooden surface, especially in the production of furniture where typically it represents between 5 and 30% of manufacturing costs. Finishing is the final step of the manufacturing process that gives wood surfaces desirable characteristics, including enhanced appearance and increased resistance to moisture and other environmental agents. Finishing can also make wood easier to clean and keep it sanitized, sealing pores that can be breeding grounds for bacteria. Finishing can also influence other wood properties, for example tonal qualities of musical instruments and hardness of flooring. In addition, finishing provides a way of giving low-value woods the appearance of ones that are expensive and difficult to obtain. Planning the finish Finishing of wood requires careful planning to ensure that the finished piece looks attractive, performs well in service and meets safety and environmental requirements. Planning fo ...
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Lead Oxide
Lead oxides are a group of inorganic compounds with formulas including lead (Pb) and oxygen (O). Common lead oxides include: * Lead(II) oxide, PbO, litharge (red), massicot (yellow) * Lead(II,IV) oxide, Pb3O4, minium, ''red lead'' * Lead dioxide (lead(IV) oxide), PbO2 Less common lead oxides are: * Lead(II,IV) oxide, Pb2O3, lead sesquioxide A sesquioxide is an oxide of an element (or radical), where the ratio between the number of atoms of that element and the number of atoms of oxygen is 2:3. For example, aluminium oxide and phosphorus(III) oxide are sesquioxides. Many sesquioxid ... (reddish yellow) * Pb12O19 (monoclinic, dark-brown or black crystals) * The so-called ''black lead oxide'', which is a mixture of PbO and fine-powdered metal Pb and used in the production of lead–acid batteries. {{Chemistry index Lead compounds Oxides ...
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