White spirit (AU, UK & Ireland)Primarily in the United Kingdom and Australia. In New Zealand "white spirit" can also refer to

Coleman fuel Coleman fuel, also generically sold as white gas, is a petroleum naphtha product marketed by the Coleman Company. Contents Historically called ''white gas'', it is a liquid petroleum fuel (100% light hydrotreated distillate), composed of cyclohe ...

(

white gas Coleman fuel, also generically sold as white gas, is a petroleum naphtha product marketed by the Coleman Company. Contents Historically called ''white gas'', it is a liquid petroleum fuel (100% light hydrotreated distillate), composed of cycloh ...

). or mineral spirits (US, Canada), also known as mineral turpentine (AU/NZ), turpentine substitute, and petroleum spirits, is a

petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...

-derived clear liquid used as a common organic

solvent A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for ...

in painting. There are also terms for specific kinds of white spirit, including Stoddard solvent and solvent naphtha (petroleum). White spirit is often used as a

paint thinner A paint thinner is a solvent used to thin oil-based paints. Solvents labeled "paint thinner" are usually mineral spirits having a flash point at about 40 °C (104 °F), the same as some popular brands of charcoal starter. Common solv ...

, or as a component thereof, though paint thinner is a broader category of solvent. Odorless mineral spirits (OMS) have been refined to remove the more toxic

aromatic compounds Aromatic compounds, also known as "mono- and polycyclic aromatic hydrocarbons", are organic compounds containing one or more aromatic rings. The parent member of aromatic compounds is benzene. The word "aromatic" originates from the past groupin ...

, and are recommended for applications such as

oil painting Oil painting is the process of painting with pigments with a medium of drying oil as the binder. It has been the most common technique for artistic painting on wood panel or canvas for several centuries, spreading from Europe to the rest of ...

. A mixture of

aliphatic In organic chemistry, hydrocarbons ( compounds composed solely of carbon and hydrogen) are divided into two classes: aromatic compounds and aliphatic compounds (; G. ''aleiphar'', fat, oil). Aliphatic compounds can be saturated, like hexane, or ...

, open-chain or

alicyclic In organic chemistry, an alicyclic compound contains one or more all-carbon rings which may be either saturated or unsaturated, but do not have aromatic character. Alicyclic compounds may have one or more aliphatic side chains attached. The ...

C₇ to C₁₂

hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...

s, white spirit is insoluble in water and is used as an

extraction solvent Extraction may refer to: Science and technology Biology and medicine * Comedo extraction, a method of acne treatment * Dental extraction, the surgical removal of a tooth from the mouth Computing and information science * Data extraction, the pro ...

, as a cleaning solvent, as a degreasing solvent and as a solvent in

aerosols An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthrop ...

paint Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...

wood preservatives Wood easily degrades without sufficient preservation. Apart from structural wood preservation measures, there are a number of different chemical preservatives and processes (also known as "timber treatment", "lumber treatment" or "pressure treat ...

lacquer Lacquer is a type of hard and usually shiny coating or finish applied to materials such as wood or metal. It is most often made from resin extracted from trees and waxes and has been in use since antiquity. Asian lacquerware, which may be ca ...

varnish Varnish is a clear transparent hard protective coating or film. It is not a stain. It usually has a yellowish shade from the manufacturing process and materials used, but it may also be pigmented as desired, and is sold commercially in various ...

es, and

asphalt Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term a ...

products. In western Europe about 60% of the total white spirit consumption is used in paints, lacquers and varnishes. White spirit is the most widely used solvent in the paint industry. In households, white spirit is commonly used to clean paint brushes after use, to clean auto parts and tools, as a starting fluid for charcoal grills, to remove adhesive residue from non-porous surfaces, and many other common tasks. The word "mineral" in "mineral spirits" or "mineral turpentine" is meant to distinguish it from

distilled spirits Liquor (or a spirit) is an alcoholic drink produced by distillation of grains, fruits, vegetables, or sugar, that have already gone through alcoholic fermentation. Other terms for liquor include: spirit drink, distilled beverage or hard l ...

(

alcoholic beverage An alcoholic beverage (also called an alcoholic drink, adult beverage, or a drink) is a drink that contains ethanol, a type of alcohol that acts as a drug and is produced by fermentation of grains, fruits, or other sources of sugar. The c ...

s distilled from fermented biological material) or from true

turpentine Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthene, terebinthine and (colloquially) turps) is a fluid obtained by the distillation of resin harvested from living trees, mainly pines. Mainly used as a special ...

(distilled tree resin).

Types and grades

Three different types and three different grades of white spirit exist. The ''type'' refers to whether the solvent has been subjected to

hydrodesulfurization Hydrodesulfurization (HDS) is a catalytic chemical process widely used to remove sulfur (S) from natural gas and from refined petroleum products, such as gasoline or petrol, jet fuel, kerosene, diesel fuel, and fuel oils. The purpose of remov ...

(removal of sulfur) alone (type 1), solvent extraction (type 2) or

hydrogenation Hydrogenation is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a Catalysis, catalyst such as nickel, palladium or platinum. The process is commonly employed to redox, reduce or S ...

(type 3). Each type comprises three grades: low flash grade, regular grade, and high flash grade (''flash'' refers to

flash point The flash point of a material is the "lowest liquid temperature at which, under certain standardized conditions, a liquid gives off vapours in a quantity such as to be capable of forming an ignitable vapour/air mixture". (EN 60079-10-1) The fl ...

). The grade is determined by the

crude oil Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crude ...

used as the starting material and the conditions of distillation. In addition there is type 0, which is defined as distillation fraction with no further treatment, consisting predominantly of saturated C₉ to C₁₂ hydrocarbons with a boiling range of . Stoddard solvent is a specific mixture of hydrocarbons, typically over 65% C₁₀ or higher hydrocarbons, developed in 1924 by Atlanta

dry cleaner Dry cleaning is any cleaning process for clothing and textiles using a solvent other than water. Dry cleaning still involves liquid, but clothes are instead soaked in a water-free liquid solvent. Tetrachloroethylene (perchloroethylene), known in ...

W. J. Stoddard and Lloyd E. Jackson of the

Mellon Institute of Industrial Research The Mellon Institute of Industrial Research is a former research institute in Pittsburgh, Pennsylvania, United States, which is now part of Carnegie Mellon University. It was founded in 1913 by Andrew Mellon and Richard B. Mellon as part of the ...

as a less flammable petroleum-based dry cleaning solvent than the petroleum solvents then in use. Dry cleaners began using the result of their work in 1928 and it soon became the predominant dry cleaning solvent in the United States, until the late 1950s. Turpentine substitute is generally not made to a standard and can have a wider range of components than products marketed as white spirit, which is made to a standard (in the UK,

British Standard British Standards (BS) are the standards produced by the BSI Group which is incorporated under a royal charter and which is formally designated as the national standards body (NSB) for the UK. The BSI Group produces British Standards under the a ...

BS 245, in Germany, DIN 51632). Turpentine substitute can be used for general cleaning but is not recommended for paint thinning as it may adversely affect drying times due to the less volatile components; while it may be used for brush cleaning its heavier components may leave an oily residue.

Chemical numbers

Physical properties

Type 1 white spirit is mainly used in most of Europe and Stoddard solvent is used in the US, both of which correspond to each other.

Use

Degreasing and lubricating

In industry, white spirit is used for cleaning and

degreasing Degreasing, often called defatting or fat trimming, is the removal of fatty acids from an object. In culinary science, degreasing is done with the intention of reducing the fat content of a meal. Degreasing food Degreasing is often used by diete ...

machine tools and parts, and in conjunction with

cutting oil Cutting fluid is a type of coolant and lubricant designed specifically for metalworking processes, such as machining and stamping. There are various kinds of cutting fluids, which include oils, oil-water emulsions, pastes, gels, aerosols (mists ...

as a thread cutting and

reaming A reamer is a type of rotary cutting tool used in metalworking. Precision reamers are designed to enlarge the size of a previously formed hole by a small amount but with a high degree of accuracy to leave smooth sides. There are also non-precisio ...

lubricant A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, t ...

. White spirit is commonly used for cutting fluid in ultraprecision lathes (commonly referred to as

diamond turning Diamond turning is turning using a cutting tool with a diamond tip. It is a process of mechanical machining of precision elements using lathes or derivative machine tools (e.g., turn-mills, rotary transfers) equipped with natural or synthetic d ...

machines). White spirit is used for regripping golf clubs. After the old grip is removed, the white spirit is poured into the new grip and shaken. After the white spirit is poured on, the new underlying tape and the new grip are slid on. After an hour of drying out, the new grip and club are ready to use.

Solvent and paint thinner

White Spirit is a

petroleum distillate Petrochemicals (sometimes abbreviated as petchems) are the chemical products obtained from petroleum by refining. Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or renewable sou ...

used as a

and mild

. White spirit is an inexpensive

-based replacement for the

vegetable Vegetables are parts of plants that are consumed by humans or other animals as food. The original meaning is still commonly used and is applied to plants collectively to refer to all edible plant matter, including the flowers, fruits, stems, ...

-based

. It is commonly used as a paint thinner for oil-based

and cleaning brushes, and as an

organic solvent A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for p ...

in other applications. Mineral turpentine is chemically very different from turpentine, which mainly consists of

pinene Pinene is a collection of unsaturated bicyclic monoterpenes. Two geometric isomers of pinene are found in nature, α-pinene and β-pinene. Both are chiral. As the name suggests, pinenes are found in pines. Specifically, pinene is the major compo ...

, and it has inferior solvent properties. Artists use white spirit as an alternative to turpentine since it is less flammable and less toxic. Because of interactions with pigments in

oil paints Oil paint is a type of slow-drying paint that consists of particles of pigment suspended in a drying oil, commonly linseed oil. The viscosity of the paint may be modified by the addition of a solvent such as turpentine or white spirit, and varnis ...

, artists require a higher grade of white spirit than many industrial users, including the complete absence of residual sulfur. White spirit was formerly an active ingredient in the laundry soap

Fels Naptha Fels-Naptha is an American brand of laundry soap manufactured by Summit Brands. The soap was originally created in 1893 by Fels and Company. It originally included the ingredient naphtha, effective for cleaning laundry and urushiol, an oil co ...

, used to dissolve oils and grease in laundry stains, and as a popular remedy for eliminating the irritant oil

urushiol Urushiol is an oily mixture of organic compounds with allergenic properties found in plants of the family Anacardiaceae, especially ''Toxicodendron'' ''spp.'' (e.g., poison oak, Chinese lacquer tree, poison ivy, poison sumac), ''Comocladia sp ...

in poison ivy. It was removed as a potential health risk. White spirit has a characteristic unpleasant

kerosene Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from el, κηρός (''keros'') meaning "wax", and was regi ...

-like odor. Chemical manufacturers have developed a low odor version of mineral turpentine which contains less of the highly volatile shorter hydrocarbons. Odorless mineral spirits is white spirit that has been further refined to remove the more toxic

, and is recommended for applications such as oil painting, where humans have close contact with the solvent. In

screen printing Screen printing is a printing technique where a mesh is used to transfer ink (or dye) onto a substrate, except in areas made impermeable to the ink by a blocking stencil. A blade or squeegee is moved across the screen to fill the open mes ...

(also referred to as silk-screening), white spirit is often used to clean and unclog screens after printing with oil-based textile and

plastisol A plastisol is a colloidal dispension of small polymer particles, usually polyvinyl chloride (PVC), in a liquid plasticizer. When heated to around , the plastic particles absorb the plasticizer, causing them to swell and fuse together forming a ...

inks. It is also used to thin inks used in making

monoprint Monoprinting is a type of printmaking where the intent is to make unique prints, that may explore an image serially. Other methods of printmaking create editioned multiples, the monoprint is editioned as 1 of 1. There are many techniques of mono-pr ...

s. White spirit is often used inside liquid-filled compasses and gauges. White spirits are a major ingredient in some popular automotive fuel/oil additives, such as

Marvel Mystery Oil Marvel Mystery Oil is an automotive product of the American Marvel Oil Company, founded by Burt Pierce in 1923. It is used as a fuel additive, oil additive, corrosion inhibitor, penetrating oil, and transmission leak stopper and seal relubricato ...

, as they are capable of dissolving varnish and sludge buildup.

Portable stoves

Although white spirit is used as an alternative to kerosene in

portable stove A portable stove is a cooking stove specially designed to be portable and lightweight, used in camping, picnicking, backpacking, or other use in remote locations where an easily transportable means of cooking or heating is needed. Portable stoves ...

s , this is not advisable as typical grades of white spirit have a lower flash point than kerosene. It cannot be used as an alternative to

, which is a much more volatile gasoline-like fuel.

Toxicity

White spirit is mainly classed as an irritant. It has a fairly low acute toxicity by inhalation of the vapour, dermal (touching the skin) and oral (ingestion) routes. However, acute exposure can lead to central nervous system depression resulting in lack of coordination and slowed reactions. Exposure to very high concentrations in enclosed spaces can lead to general

narcotic The term narcotic (, from ancient Greek ναρκῶ ''narkō'', "to make numb") originally referred medically to any psychoactive compound with numbing or paralyzing properties. In the United States, it has since become associated with opiates ...

effects (drowsiness, dizziness, nausea, etc.) and can eventually lead to unconsciousness. Oral ingestion presents a high aspiration hazard. Prolonged or repeated skin exposure over a long period of time can result in severe irritant

dermatitis Dermatitis is inflammation of the skin, typically characterized by itchiness, redness and a rash. In cases of short duration, there may be small blisters, while in long-term cases the skin may become thickened. The area of skin involved can v ...

, also called

contact dermatitis Contact dermatitis is a type of acute or chronic inflammation of the skin caused by exposure to chemical or physical agents. Symptoms of contact dermatitis can include itchy or dry skin, a red rash, bumps, blisters, or swelling. These rashes are ...

. Continuous exposure to an average white spirit concentration of 240 mg/m³ (40 ppm) for more than 13 years can lead to chronic

central nervous system The central nervous system (CNS) is the part of the nervous system consisting primarily of the brain and spinal cord. The CNS is so named because the brain integrates the received information and coordinates and influences the activity of all par ...

effects. Similar long-term studies have been made in which some of the observed effects included

memory impairment Amnesia is a deficit in memory caused by brain damage or disease,Gazzaniga, M., Ivry, R., & Mangun, G. (2009) Cognitive Neuroscience: The biology of the mind. New York: W.W. Norton & Company. but it can also be caused temporarily by the use ...

, poor concentration, increased

irritability Irritability (also called as crankiness) is the excitatory ability that living organisms have to respond to changes in their environment. The term is used for both the physiological reaction to stimuli and for the pathological, abnormal or excessi ...

etc. White spirit is implicated in the development of chronic toxic encephalopathy (CTE) among house painters. In severe cases CTE may lead to disability and personality changes. These effects in painters were first studied in the 1970s in the Nordic countries. Owing to the volatility and low bioavailability of its constituents, white spirit, although it is moderately toxic to aquatic organisms, is unlikely to present significant hazards to the environment. It should not however, be purposely poured down the sink or freshwater drain. People can be exposed to Stoddard solvent in the workplace by breathing it in, swallowing it, skin contact, and eye contact. The

Occupational Safety and Health Administration The Occupational Safety and Health Administration'' (OSHA ) is a large regulatory agency of the United States Department of Labor that originally had federal visitorial powers to inspect and examine workplaces. Congress established the agenc ...

(OSHA) has set the legal limit (

Permissible exposure limit The permissible exposure limit (PEL or OSHA PEL) is a legal limit in the United States for exposure of an employee to a chemical substance or physical agent such as high level noise. Permissible exposure limits are established by the Occupational ...

) for Stoddard solvent exposure in the workplace as 500 ppm (2900 mg/m³) over an 8-hour workday. The

National Institute for Occupational Safety and Health The National Institute for Occupational Safety and Health (NIOSH, ) is the United States federal agency responsible for conducting research and making recommendations for the prevention of work-related injury and illness. NIOSH is part of the C ...

(NIOSH) has set a

Recommended exposure limit A recommended exposure limit (REL) is an occupational exposure limit that has been recommended by the United States National Institute for Occupational Safety and Health. The REL is a level that NIOSH believes would be protective of worker safet ...

(REL) of 350 mg/m³ over an 8-hour workday and 1800 mg/m³ over 15 minutes. At levels of 20,000 mg/m³, Stoddard solvent is

immediately dangerous to life and health The term immediately dangerous to life or health (IDLH) is defined by the US National Institute for Occupational Safety and Health (NIOSH) as exposure to airborne contaminants that is "likely to cause death or immediate or delayed permanent advers ...

Footnotes

References

{{reflist

External links

ICPS safety sheet White Spirit (Stoddard Solvent)
–

World Health Organization The World Health Organization (WHO) is a specialized agency of the United Nations responsible for international public health. The WHO Constitution states its main objective as "the attainment by all peoples of the highest possible level of h ...

Environmental Health Criteria 187
– World Health Organization

* ttps://www.cdc.gov/niosh/npg/npgd0569.html CDC - NIOSH Pocket Guide to Chemical Hazards Household chemicals Painting materials Hydrocarbon solvents Dry cleaning Commodity chemicals da:Terpentin