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Ferromanganese Nodules
Ferromanganese nodules form in the oxidizing environment of the abyssal pelagic zone. They are the result of ion exchange reactions that precipitate ore components from the water (sedimentary) or out of the interstitial water of the sediments layers (diagenetic). The composition of Manganese-bearing minerals is dependent on how the nodules are formed; sedimentary nodules, which have a lower Mn2+ content than diagenetic, are dominated by Fe- vernadite, Mn-feroxyhyte, and asbolane-buserite while diagenetic nodules are dominated by buserite I, birnessite, todorokite Todorokite is a rare complex hydrous manganese oxide mineral with the chemical formula . It was named in 1934 for the type locality, the Todoroki mine, Hokkaido, Japan. It belongs to the prismatic class 2/m of the monoclinic crystal system, but ..., and asbolane-buserite. References * {{cite journal, last=Novikov, first=C.V., author2=Murdmaa, I.O., year=2007, title=Ion exchange properties of oceanic ferromanganese n ...
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Ferromanganese
Ferromanganese is a ferroalloy with high manganese content (high-carbon ferromanganese can contain as much as 80% Mn by weight). It is made by heating a mixture of the oxides MnO2 and Fe2O3, with carbon (usually as coal and coke) in either a blast furnace or an electric arc furnace-type system, called a submerged arc furnace. The oxides undergo carbothermal reduction in the furnaces, producing the ferromanganese. Ferromanganese is used as a deoxidizer for steel. A North American standard specification is ASTM A99. The ten grades covered under this specification includes; *Standard ferromanganese *Medium-carbon ferromanganese *Low-carbon ferromanganese A similar material is a pig iron with high content of manganese, is called spiegeleisen, or specular pig iron. History 350px, lang=en, Evolution of global manganese production, by processes. In 1856, Robert Forester Mushet "used manganese to improve the ability of steel produced by the Bessemer process to withstand rolling and f ...
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Oxidizing
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogenation, C=C (and other) bonds ar ...
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Abyssal
The abyssal zone or abyssopelagic zone is a layer of the pelagic zone of the ocean. "Abyss" derives from the Greek word , meaning bottomless. At depths of , this zone remains in perpetual darkness. It covers 83% of the total area of the ocean and 60% of Earth's surface. The abyssal zone has temperatures around through the large majority of its mass. Due to there being no light, there are no plants producing oxygen, which instead primarily comes from ice that had melted long ago from the polar regions. The water along the seafloor of this zone is actually devoid of oxygen, resulting in a death trap for organisms unable to quickly return to the oxygen-enriched water above. This region also contains a much higher concentration of nutrient salts, like nitrogen, phosphorus, and silica, due to the large amount of dead organic material that drifts down from the above ocean zones and decomposes. The water pressure can reach up to 76 megapascal. The area below the abyssal zone is the spa ...
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Pelagic Zone
The pelagic zone consists of the water column of the open ocean, and can be further divided into regions by depth (as illustrated on the right). The word ''pelagic'' is derived . The pelagic zone can be thought of as an imaginary cylinder or water column between the surface of the sea and the bottom. Conditions in the water column change with depth: pressure increases; temperature and light decrease; salinity, oxygen, micronutrients (such as iron, magnesium and calcium) all change. Marine life is affected by bathymetry (underwater topography) such as the seafloor, shoreline, or a submarine seamount, as well as by proximity to the boundary between the ocean and the atmosphere at the ocean surface, which brings light for photosynthesis, predation from above, and wind stirring up waves and setting currents in motion. The pelagic zone refers to the open, free waters away from the shore, where marine life can swim freely in any direction unhindered by topographical constraints. Th ...
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Ion Exchange
Ion exchange is a reversible interchange of one kind of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid with the reaction being used especially for softening or making water demineralised, the purification of chemicals and separation of substances. Ion exchange usually describes a process of purification of aqueous solutions using solid polymeric ion-exchange resin. More precisely, the term encompasses a large variety of processes where ions are exchanged between two electrolytes. Aside from its use to purify drinking water, the technique is widely applied for purification and separation of a variety of industrially and medicinally important chemicals. Although the term usually refers to applications of synthetic (man-made) resins, it can include many other materials such as soil. Typical ion exchangers are ion-exchange resins (functionalized porous or gel polymer), zeolites, montmorillonite, clay, and soil humus. Ion exc ...
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Precipitate
In an aqueous solution, precipitation is the process of transforming a dissolved substance into an insoluble solid from a super-saturated solution. The solid formed is called the precipitate. In case of an inorganic chemical reaction leading to precipitation, the chemical reagent causing the solid to form is called the ''precipitant''. The clear liquid remaining above the precipitated or the centrifuged solid phase is also called the 'supernate' or 'supernatant'. The notion of precipitation can also be extended to other domains of chemistry (organic chemistry and biochemistry) and even be applied to the solid phases (''e.g.'', metallurgy and alloys) when solid impurities segregate from a solid phase. Supersaturation The precipitation of a compound may occur when its concentration exceeds its solubility. This can be due to temperature changes, solvent evaporation, or by mixing solvents. Precipitation occurs more rapidly from a strongly supersaturated solution. The formati ...
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Sedimentary
Sedimentary rocks are types of rock (geology), rock that are formed by the accumulation or deposition of mineral or organic matter, organic particles at Earth#Surface, Earth's surface, followed by cementation (geology), cementation. Sedimentation is the collective name for processes that cause these particles to settle in place. The particles that form a sedimentary rock are called sediment, and may be composed of detritus (geology), geological detritus (minerals) or detritus, biological detritus (organic matter). The geological detritus originated from weathering and erosion of existing rocks, or from the solidification of molten lava blobs erupted by volcanoes. The geological detritus is transported to the place of deposition by water, wind, ice or Mass wasting, mass movement, which are called agents of denudation. Biological detritus was formed by bodies and parts (mainly shells) of dead aquatic organisms, as well as their fecal mass, suspended in water and slowly piling up on ...
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Interstitial
An interstitial space or interstice is a space between structures or objects. In particular, interstitial may refer to: Biology * Interstitial cell tumor * Interstitial cell, any cell that lies between other cells * Interstitial collagenase, enzyme that breaks the peptide bonds in collagen * Interstitial cystitis * Interstitium, the contiguous fluid-filled space existing between the skin and body organs * Interstitial fluid, a solution that bathes and surrounds the cells of multicellular animals * Interstitial granulomatous dermatitis * Interstitial infusion * Interstitial keratitis * Interstitial lung disease * Interstitial nephritis * Interstitial pregnancy Other uses To describe the spaces within particulate matter such sands, gravels, cobbles, grain, etc. that lie between the discrete particles. * Interstitial art * Interstitial condensation, in construction * Interstitial site, in chemistry * Interstitial defect, in chemistry * Interstitial television show, in televisio ...
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Sediments
Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand and silt can be carried in suspension in river water and on reaching the sea bed deposited by sedimentation; if buried, they may eventually become sandstone and siltstone (sedimentary rocks) through lithification. Sediments are most often transported by water (fluvial processes), but also wind (aeolian processes) and glaciers. Beach sands and river channel deposits are examples of fluvial transport and deposition, though sediment also often settles out of slow-moving or standing water in lakes and oceans. Desert sand dunes and loess are examples of aeolian transport and deposition. Glacial moraine deposits and till are ice-transported sediments. Classification Sediment can be classified based on its grain size, grain shape, and ...
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Feroxyhyte
Feroxyhyte is an oxide/hydroxide of iron, δ-Fe3+O(OH). Feroxyhyte crystallizes in the hexagonal system. It forms as brown rounded to concretionary masses. Feroxyhyte is opaque, magnetic, has a yellow streak, and has a relative density of 4.2. It occurs in manganese-iron nodules on the Atlantic and Pacific Ocean floors. It is also found in the Baltic, White, and Kara Seas. Forms under high pressure conditions and reverts to goethite on exposure to surface conditions. It also occurs as cement and coatings on clasts in poorly drained soils and sediments, formed by the rapid oxidation of iron(II) oxide compounds. It was first described in 1976 for an occurrence in soils at its type locality: Kolomyya, Ivano-Frankivsk Oblast, Ukraine Ukraine ( uk, Україна, Ukraïna, ) is a country in Eastern Europe. It is the second-largest European country after Russia, which it borders to the east and northeast. Ukraine covers approximately . Prior to the ongoing Russian inv . ...
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Asbolane
Asbolane is a manganese (IV) oxy-hydroxide mineral containing also cobalt, nickel, magnesium, and calcium ions. It crystallizes in the hexagonal crystal system. Its chemical formula is . Naming It is named after the Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ... word for ''"soil like soot"''. References Hydroxide minerals {{oxide-mineral-stub ...
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