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Ferrioxalate
Ferrioxalate or trisoxalatoferrate(III) is a trivalent anion with formula . It is a transition metal complex consisting of an iron atom in the +3 oxidation state and three bidentate oxalate ions anions acting as ligands. The ferrioxalate anion gives a lime green color to salts, and in solution it is fluorescent. The anion is sensitive to light and higher-energy electromagnetic radiation, which causes the decomposition of one oxalate to carbon dioxide () and reduction of the iron(III) atom to iron(II). This property is exploited for actinometry. The most common and most-studied salt is potassium ferrioxalate, but the sodium ferrioxalate, sodium, ammonium ferrioxalate, ammonium, and lithium salts have also received some attention. Properties Stability In the absence of light or other radiation, the ferrioxalate complex is quite stable. The potassium and sodium salts and their solutions can be heated to near 100 °C for hours without significant decomposition. Molecular str ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Ferrioxalate
Potassium ferrioxalate, also called potassium trisoxalatoferrate or potassium tris(oxalato)ferrate(III) is a chemical compound with the formula []. It often occurs as the trihydrate . Both are crystalline compounds, lime green in colour.A. Saritha, B. Raju, M. Ramachary, P. Raghavaiah, and K. A. Hussain (2012) "Synthesis, crystal structure and characterization of chiral, three-dimensional anhydrous potassium tris(oxalato)ferrate(III)", ''Physica B: Condensed Matter'', volume 407, issue 21, pages 4208-4213. The compound is a salt consisting of ferrioxalate anions, , and potassium cations . The anion is a transition metal complex consisting of an iron atom in the +3 oxidation state and three bidentate oxalate ions anions acting as ligands. Potassium acts as a counterion, balancing the −3 charge of the complex. In solution, the salt dissociates to give the ferrioxalate anion, []3−, which appears fluorescent green in color. The ferrioxalate anion is quite stable in the dark ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Ferrioxalate
Sodium ferrioxalate is a chemical compound with the formula . It is also called sodium oxalatoferrate or sodium trisoxalatoferrate. The compound is a salt (chemistry), salt consisting of ferrioxalate anions, , and sodium cations . The anion is a transition metal complex consisting of an iron atom in the +3 oxidation state and three bidentate oxalate ions anions acting as ligands. The ferrioxalate anion is sensitive to light and higher-energy electromagnetic radiation, which causes the decomposition of one oxalate to carbon dioxide and reduction of the iron(III) atom to Iron(II) oxide, iron(II). Properties Solubility This compound is very soluble in hot water, (182 parts per 100 parts solvent by mass), but a lot less soluble in cold water, (32 parts per 100 parts solvent), about the solubility of sodium chloride. It is not appreciably soluble in ethanol or ethanol water mixtures which are more than 50% ethanol by mass. It is somewhat more soluble in water than the corresponding ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Valence (chemistry)
In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Description The combining capacity, or affinity of an atom of a given element is determined by the number of hydrogen atoms that it combines with. In methane, carbon has a valence of 4; in ammonia, nitrogen has a valence of 3; in water, oxygen has a valence of 2; and in hydrogen chloride, chlorine has a valence of 1. Chlorine, as it has a valence of one, can be substituted for hydrogen. Phosphorus has a valence of 5 in phosphorus pentachloride, . Valence diagrams of a compound represent the connectivity of the elements, with lines drawn between two elements, sometimes called bonds, representing a saturated valency for each element. The two tables below show some examples of different compounds, their valence diagrams, and the valences for each element of the compound. Modern definitions ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Symmetry
Molecular symmetry in chemistry describes the symmetry present in molecules and the classification of these molecules according to their symmetry. Molecular symmetry is a fundamental concept in chemistry, as it can be used to predict or explain many of a molecule's chemical properties, such as whether or not it has a dipole moment, as well as its allowed spectroscopic transitions. To do this it is necessary to use group theory. This involves classifying the states of the molecule using the irreducible representations from the character table of the symmetry group of the molecule. Symmetry is useful in the study of molecular orbitals, with applications to the Hückel method, to ligand field theory, and to the Woodward-Hoffmann rules. Many university level textbooks on physical chemistry, quantum chemistry, spectroscopy and inorganic chemistry discuss symmetry. Another framework on a larger scale is the use of crystal systems to describe crystallographic symmetry in bulk materia ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranyl Oxalate
Uranyl oxalate (UO2C2O4) is a pale yellow powdered uranyl compound. It is often encountered in industrial nuclear processes at both the front and back-end of the nuclear fuel cycle. Due to its hygroscopicity, uranyl oxalate rarely exists in the dehydrated state and is usually instead found in the trihydrate form (UO2C2O4·3H2O) at room temperature. At room temperature, the powder exhibits a monoclinic crystal structure in the ''P''21/''c'' space group. Production Uranyl oxalate trihydrate can be produced by the reaction of uranyl nitrate hexahydrate with oxalic acid. Uranyl oxalate has been used in actinometer Actinometers are instruments used to measure the heating power of radiation. They are used in meteorology to measure solar radiation as pyranometers, pyrheliometers and net radiometers. An actinometer is a chemical system or physical device which ...s. References {{Oxalates Uranyl compounds Oxalates ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photometry (optics)
Photometry is the science of the measurement of light, in terms of its perceived brightness to the human eye. It is distinct from radiometry, which is the science of measurement of radiant energy (including light) in terms of absolute power. In modern photometry, the radiant power at each wavelength is weighted by a luminosity function that models human brightness sensitivity. Typically, this weighting function is the photopic sensitivity function, although the scotopic function or other functions may also be applied in the same way. Photometry and the eye The human eye is not equally sensitive to all wavelengths of visible light. Photometry attempts to account for this by weighting the measured power at each wavelength with a factor that represents how sensitive the eye is at that wavelength. The standardized model of the eye's response to light as a function of wavelength is given by the luminosity function. The eye has different responses as a function of wavelength when it ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxidation State
In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to different atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. Conceptually, the oxidation state may be positive, negative or zero. While fully ionic bonds are not found in nature, many bonds exhibit strong ionicity, making oxidation state a useful predictor of charge. The oxidation state of an atom does not represent the "real" formal charge on that atom, or any other actual atomic property. This is particularly true of high oxidation states, where the ionization energy required to produce a multiply positive ion is far greater than the energies available in chemical reactions. Additionally, the oxidation states of atoms in a given compound may vary depending on the choice of electronegativity scale used in their calculation. Thus, the oxidation state of an atom in a compound is purely a formalism. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Redox
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate (chemistry), substrate change. Oxidation is the loss of Electron, electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they always move at the speed of light in vacuum, (or about ). The photon belongs to the class of bosons. As with other elementary particles, photons are best explained by quantum mechanics and exhibit wave–particle duality, their behavior featuring properties of both waves and particles. The modern photon concept originated during the first two decades of the 20th century with the work of Albert Einstein, who built upon the research of Max Planck. While trying to explain how matter and electromagnetic radiation could be in thermal equilibrium with one another, Planck proposed that the energy stored within a material object should be regarded as composed of an integer number of discrete, equal-sized parts. To explain the photoelectric effect, Eins ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoreduction
Light-dependent reactions is jargon for certain photochemical reactions that are involved in photosynthesis, the main process by which plants acquire energy. There are two light dependent reactions, the first occurs at photosystem II (PSII) and the second occurs at photosystem I (PSI), PSII absorbs a photon to produce a so-called high energy electron which transfers via an electron transport chain to cytochrome ''bf'' and then to PSI. The then-reduced PSI, absorbs another photon producing a more highly reducing electron, which converts NADP to NADPH. In oxygenic photosynthesis, the first electron donor is water, creating oxygen (O2) as a by-product. In anoxygenic photosynthesis various electron donors are used. Cytochrome ''b6f'' and ATP synthase work together to produce ATP (photophosphorylation) in two distinct ways. In non-cyclic photophosphorylation, cytochrome ''b6f'' uses electrons from PSII and energy from PSI to pump protons from the stroma to the lumen. The resulting ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Helical Chirality
Helical may refer to: * Helix, the mathematical concept for the shape * Helical engine, a proposed spacecraft propulsion drive * Helical spring, a coilspring * Helical plc, a British property company, once a maker of steel bar stock * Helicoil A threaded insert, also known as a threaded bushing, is a fastener element that is inserted into an object to add a threaded hole. They may be used to repair a stripped threaded hole, provide a durable threaded hole in a soft material, place a thr ..., a mechanical thread repairing insert * H-el-ical//, stage name for Hikaru, Japanese singer {{disambig ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
