Uranyl oxalate (UO₂C₂O₄) is a pale yellow powdered

uranyl The uranyl ion is an oxycation of uranium in the oxidation state +6, with the chemical formula . It has a linear structure with short U–O bonds, indicative of the presence of multiple bonds between uranium and oxygen. Four or more ligands may ...

compound. It is often encountered in industrial

nuclear process In nuclear physics and nuclear chemistry, a nuclear reaction is a process in which two nuclei, or a nucleus and an external subatomic particle, collide to produce one or more new nuclides. Thus, a nuclear reaction must cause a transformation ...

es at both the front and back-end of the

nuclear fuel cycle The nuclear fuel cycle, also called nuclear fuel chain, is the progression of nuclear fuel through a series of differing stages. It consists of steps in the ''front end'', which are the preparation of the fuel, steps in the ''service period'' in w ...

. Due to its

hygroscopicity Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substanc ...

, uranyl oxalate rarely exists in the dehydrated state and is usually instead found in the trihydrate form (UO₂C₂O₄·3H₂O) at room temperature. At room temperature, the powder exhibits a

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...

crystal structure in the ''P''2₁/''c''

space group In mathematics, physics and chemistry, a space group is the symmetry group of an object in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of an object that leave it unchan ...

Production

Uranyl oxalate trihydrate can be produced by the reaction of

uranyl nitrate Uranyl nitrate is a water-soluble yellow uranium salt with the formula . The hexa-, tri-, and dihydrates are known. The compound is mainly of interest because it is an intermediate in the preparation of nuclear fuels. Uranyl nitrate can be prepa ...

hexahydrate with

oxalic acid Oxalic acid is an organic acid with the systematic name ethanedioic acid and formula . It is the simplest dicarboxylic acid. It is a white crystalline solid that forms a colorless solution in water. Its name comes from the fact that early inve ...

. Uranyl oxalate has been used in

actinometer Actinometers are instruments used to measure the heating power of radiation. They are used in meteorology to measure solar radiation as pyranometers, pyrheliometers and net radiometers. An actinometer is a chemical system or physical device which ...

References

{{Oxalates Uranyl compounds Oxalates