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Enthalpy–entropy Chart
An enthalpy–entropy chart, also known as the ''H''–''S'' chart or Mollier diagram, plots the total heat against entropy, describing the enthalpy of a thermodynamic system. A typical chart covers a pressure range of 0.01–1000 bar, and temperatures up to 800 degrees Celsius. It shows enthalpy H in terms of internal energy U, pressure p and volume V using the relationship H = U + pV \,\! (or, in terms of specific enthalpy, specific entropy and specific volume, h = u + pv \! ). History The diagram was created in 1904, when Richard Mollier plotted the total heat against entropy . At the 1923 Thermodynamics Conference held in Los Angeles it was decided to name, in his honor, as a "Mollier diagram" any thermodynamic diagram using the enthalpy as one of its axes. Details On the diagram, lines of constant pressure, constant temperature and volume are plotted, so in a two-phase region, the lines of constant pressure and temperature coincide. Thus, coordinates on the diagram ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isobaric Process
In thermodynamics, an isobaric process is a type of thermodynamic process in which the pressure of the system stays constant: Δ''P'' = 0. The heat transferred to the system does work, but also changes the internal energy (''U'') of the system. This article uses the physics sign convention for work, where positive work is work done by the system. Using this convention, by the first law of thermodynamics, : Q = \Delta U + W\, where ''W'' is work, ''U'' is internal energy, and ''Q'' is heat. Pressure-volume work by the closed system is defined as: :W = \int \! p \,dV \, where Δ means change over the whole process, whereas ''d'' denotes a differential. Since pressure is constant, this means that : W = p \Delta V\, . Applying the ideal gas law, this becomes : W = n\,R\,\Delta T with ''R'' representing the gas constant, and ''n'' representing the amount of substance, which is assumed to remain constant (e.g., there is no phase transition during a chemical rea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the firs ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phase Diagram
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, volume, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium. Overview Common components of a phase diagram are ''lines of equilibrium'' or ''phase boundaries'', which refer to lines that mark conditions under which multiple phases can coexist at equilibrium. Phase transitions occur along lines of equilibrium. Metastable phases are not shown in phase diagrams as, despite their common occurrence, they are not equilibrium phases. Triple points are points on phase diagrams where lines of equilibrium intersect. Triple points mark conditions at which three different phases can coexist. For example, the water phase diagram has a triple point corresponding to the single temperature and pressure at which solid, liquid, and gaseous water can coexist in a stab ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Contour Line
A contour line (also isoline, isopleth, or isarithm) of a function of two variables is a curve along which the function has a constant value, so that the curve joins points of equal value. It is a plane section of the three-dimensional graph of the function f(x,y) parallel to the (x,y)-plane. More generally, a contour line for a function of two variables is a curve connecting points where the function has the same particular value. In cartography, a contour line (often just called a "contour") joins points of equal elevation (height) above a given level, such as mean sea level. A contour map is a map illustrated with contour lines, for example a topographic map, which thus shows valleys and hills, and the steepness or gentleness of slopes. The contour interval of a contour map is the difference in elevation between successive contour lines. The gradient of the function is always perpendicular to the contour lines. When the lines are close together the magnitude of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Diagrams
Thermodynamic diagrams are diagrams used to represent the thermodynamic states of a material (typically fluid) and the consequences of manipulating this material. For instance, a temperature–entropy diagram ( T–s diagram) may be used to demonstrate the behavior of a fluid as it is changed by a compressor. Overview Especially in meteorology they are used to analyze the actual state of the atmosphere derived from the measurements of radiosondes, usually obtained with weather balloons. In such diagrams, temperature and humidity values (represented by the dew point) are displayed with respect to pressure. Thus the diagram gives at a first glance the actual atmospheric stratification and vertical water vapor distribution. Further analysis gives the actual base and top height of convective clouds or possible instabilities in the stratification. By assuming the energy amount due to solar radiation it is possible to predict the 2 m (6.6 ft) temperature, humidity, and wind dur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Psychrometric Chart
Psychrometrics (or psychrometry, ; also called hygrometry) is the field of engineering concerned with the physical and thermodynamic properties of gas-vapor mixtures. Common applications Although the principles of psychrometry apply to any physical system consisting of gas-vapor mixtures, the most common system of interest is the mixture of water vapor and air, because of its application in heating, ventilation, and air-conditioning and meteorology. In human terms, our thermal comfort is in large part a consequence of not just the temperature of the surrounding air, but (because we cool ourselves via perspiration) the extent to which that air is saturated with water vapor. Many substances are hygroscopic, meaning they attract water, usually in proportion to the relative humidity or above a critical relative humidity. Such substances include cotton, paper, cellulose, other wood products, sugar, calcium oxide (burned lime) and many chemicals and fertilizers. Industries that us ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Malt
Malt is germinated cereal grain that has been dried in a process known as " malting". The grain is made to germinate by soaking in water and is then halted from germinating further by drying with hot air. Malted grain is used to make beer, whisky, malted milk, malt vinegar, confections such as Maltesers and Whoppers, flavored drinks such as Horlicks, Ovaltine, and Milo, and some baked goods, such as malt loaf, bagels, and Rich Tea biscuits. Malted grain that has been ground into a coarse meal is known as "sweet meal". Malting grain develops the enzymes (α-amylase, β-amylase) required for modifying the grains' starches into various types of sugar, including monosaccharide glucose, disaccharide maltose, trisaccharide maltotriose, and higher sugars called maltodextrines. It also develops other enzymes, such as proteases, that break down the proteins in the grain into forms that can be used by yeast. The point at which the malting process is stopped affects the sta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermal Power Station
A thermal power station is a type of power station in which heat energy is converted to electrical energy. In a steam-generating cycle heat is used to boil water in a large pressure vessel to produce high-pressure steam, which drives a steam turbine connected to an electrical generator. The low-pressure exhaust from the turbine enters a steam condenser where it is cooled to produce hot condensate which is recycled to the heating process to generate more high pressure steam. This is known as a Rankine cycle. The design of thermal power stations depends on the intended energy source: fossil fuel, nuclear and geothermal power, solar energy, biofuels, and waste incineration are all used. Certain thermal power stations are also designed to produce heat for industrial purposes; for district heating; or desalination of water, in addition to generating electrical power. Fuels such as natural gas or oil can also be burnt directly in gas turbines ( internal combustion). These p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Colloid
A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend the definition to include substances like aerosols and gels. The term colloidal suspension refers unambiguously to the overall mixture (although a narrower sense of the word '' suspension'' is distinguished from colloids by larger particle size). A colloid has a dispersed phase (the suspended particles) and a continuous phase (the medium of suspension). The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre. Some colloids are translucent because of the Tyndall effect, which is the scattering of light by particles in the colloid. Other colloids may be opaque or have a slight color. Colloidal suspensions are the subject of interface and colloid science. This field of study was introduced in 1845 by Ital ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Steam Turbine
A steam turbine is a machine that extracts thermal energy from pressurized steam and uses it to do mechanical work on a rotating output shaft. Its modern manifestation was invented by Charles Parsons in 1884. Fabrication of a modern steam turbine involves advanced metalwork to form high-grade steel alloys into precision parts using technologies that first became available in the 20th century; continued advances in durability and efficiency of steam turbines remains central to the energy economics of the 21st century. The steam turbine is a form of heat engine that derives much of its improvement in thermodynamic efficiency from the use of multiple stages in the expansion of the steam, which results in a closer approach to the ideal reversible expansion process. Because the turbine generates rotary motion, it can be coupled to a generator to harness its motion into electricity. Such turbogenerators are the core of thermal power stations which can be fueled by fossil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rankine Cycle
The Rankine cycle is an idealized thermodynamic cycle describing the process by which certain heat engines, such as steam turbines or reciprocating steam engines, allow mechanical work to be extracted from a fluid as it moves between a heat source and heat sink. The Rankine cycle is named after William John Macquorn Rankine, a Scottish polymath professor at Glasgow University. Heat energy is supplied to the system via a boiler where the working fluid (typically water) is converted to a high pressure gaseous state (steam) in order to turn a turbine. After passing over the turbine the fluid is allowed to condense back into a liquid state as waste heat energy is rejected before being returned to boiler, completing the cycle. Friction losses throughout the system are often neglected for the purpose of simplifying calculations as such losses are usually much less significant than thermodynamic losses, especially in larger systems. Description The Rankine cycle closely describes the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
