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Ethylene Glycol Dinitrate
Ethylene glycol dinitrate, abbreviated EGDN and NGC, also known as Nitroglycol, is a colorless, oily, explosive liquid obtained by nitration, nitrating ethylene glycol. It is similar to nitroglycerine in both manufacture and properties, though it is more volatile and less viscosity, viscous. Unlike nitroglycerine, the chemical has a perfect oxygen balance, meaning that its ideal exothermic decomposition would completely convert it to low energy carbon dioxide, water, and nitrogen gas, with no excess unreacted substances, without needing to react with anything else. History and production Pure EGDN was first produced by the Belgian chemist Louis Henry (1834–1913) in 1870 by dropping a small amount of ethylene glycol into a mixture of nitric acid, nitric and sulfuric acids cooled to 0 °C. The previous year, Friedrich August Kekulé von Stradonitz, August Kekulé had produced EGDN by the nitration of ethylene, but this was actually contaminated with beta-nitroethyl nitrate. ...
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Metre Per Second
The metre per second is the unit of both speed (a scalar (physics), scalar quantity) and velocity (a Vector (mathematics and physics), vector quantity, which has direction and magnitude) in the International System of Units (SI), equal to the speed of a body covering a distance of one metre in a time of one second. The International System of Units, SI unit symbols are m/s, m·s−1, m s−1, or . Sometimes it is abbreviated as "mps". Conversions is equivalent to: : = 3.6 kilometres per hour, km/h (exactly) : ≈ 3.2808 feet per second (approximately) : ≈ 2.2369 miles per hour (approximately) : ≈ 1.9438 knot (unit), knots (approximately) 1 feet per second, foot per second = (exactly) 1 miles per hour, mile per hour = (exactly) 1 kilometres per hour, km/h = (exactly) Relation to other measures The benz, named in honour of Karl Benz, has been proposed as a name for one metre per second. Although it has seen some support as a practical unit, primarily from German ...
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Potassium Hydroxide
Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which exploit its caustic nature and its reactivity toward acids. An estimated 700,000 to 800,000 tonnes were produced in 2005. KOH is noteworthy as the precursor to most soft and liquid soaps, as well as numerous potassium-containing chemicals. It is a white solid that is dangerously corrosive. Properties and structure KOH exhibits high thermal stability. Because of this high stability and relatively low melting point, it is often melt-cast as pellets or rods, forms that have low surface area and convenient handling properties. These pellets become tacky in air because KOH is hygroscopic. Most commercial samples are ca. 90% pure, the remainder being water and carbonates. Its dissolution in water is strongly exothermic. Concentrated aqueous solut ...
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Xylitol Pentanitrate
Xylitol pentanitrate (XPN) is a nitrated ester primary explosive first synthesized in 1891 by Gabriel Bertrand. Law enforcement has taken an interest in XPN along with erythritol tetranitrate (ETN) and pentaerythritol tetranitrate (PETN) due to their ease of synthesis, which makes them accessible to amateur chemists and terrorists.{{Cite journal, last1=Dong, first1=Jun, last2=Yan, first2=Qi-Long, last3=Liu, first3=Pei-Jin, last4=He, first4=Wei, last5=Qi, first5=Xiao-Fei, last6=Zeman, first6=Svatopluk, date=2018, title=The correlations among detonation velocity, heat of combustion, thermal stability and decomposition kinetics of nitric esters, url=http://link.springer.com/10.1007/s10973-017-6706-5, journal=Journal of Thermal Analysis and Calorimetry, language=en, volume=131, issue=2, pages=1391–1403, doi=10.1007/s10973-017-6706-5, s2cid=102678177 , issn=1388-6150 Properties At room temperature XPN exists as a white crystalline solid. When heated to 163 °C, liquid xylitol ...
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Erythritol Tetranitrate
Erythritol tetranitrate (ETN) is an explosive compound chemically similar to PETN, though it is thought to be slightly more sensitive to friction and impact. Like many nitrate esters, ETN acts as a vasodilator, and was the active ingredient in the original " sustained release" tablets, made under a process patent in the early 1950s, called " nitroglyn". Ingesting ETN or prolonged skin contact can lead to absorption and what is known as a "nitro headache". Properties ETN has a relatively high velocity of detonation of 8206 m/s at a density of 1.7219 (±0.0025) g/cm3. It is white in color and odorless. ETN is commonly cast into mixtures with other high explosives. It is somewhat sensitive to shock and friction, so care needs to be taken while handling. ETN dissolves readily in acetone and other ketone solvents. The impact and friction sensitivity is slightly higher than the sensitivity of pentaerythritol tetranitrate (PETN). The sensitivity of melt cast and pressed ...
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Methyl Nitrate
Methyl nitrate is the methyl ester of nitric acid and has the chemical formula CH3NO3. It is a colourless explosive volatile liquid. Synthesis It can be produced by the condensation of nitric acid and methanol: :CH3OH + HNO3 → CH3NO3 + H2O A newer method uses methyl iodide and silver nitrate: CH3I + AgNO3 → CH3NO3 + AgI Methyl nitrate can be produced on a laboratory or industrial scale either through the distillation of a mixture of methanol and nitric acid, or by the nitration of methanol by a mixture of sulfuric and nitric acids. The first procedure is not preferred due to the great explosion danger presented by the methyl nitrate vapour. The second procedure is essentially identical to that of making nitroglycerin. However, the process is usually run at a slightly higher temperature and the mixture is stirred mechanically on an industrial scale instead of with compressed air. Explosive properties Methyl nitrate is a sensitive explosive. When ignited it burns extremel ...
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Vasodilator
Vasodilation is the widening of blood vessels. It results from relaxation of smooth muscle cells within the vessel walls, in particular in the large veins, large arteries, and smaller arterioles. The process is the opposite of vasoconstriction, which is the narrowing of blood vessels. When blood vessels dilate, the flow of blood is increased due to a decrease in vascular resistance and increase in cardiac output. Therefore, dilation of arterial blood vessels (mainly the arterioles) decreases blood pressure. The response may be intrinsic (due to local processes in the surrounding tissue) or extrinsic (due to hormones or the nervous system). In addition, the response may be localized to a specific organ (depending on the metabolic needs of a particular tissue, as during strenuous exercise), or it may be systemic (seen throughout the entire systemic circulation). Endogenous substances and drugs that cause vasodilation are termed vasodilators. Such vasoactivity is necessary for ...
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Polyol
In organic chemistry, a polyol is an organic compound containing multiple hydroxyl groups (). The term "polyol" can have slightly different meanings depending on whether it is used in food science or polymer chemistry. Polyols containing two, three and four hydroxyl groups are diols, triols, and tetrols, respectively. Classification Polyols may be classified according to their chemistry. Some of these chemistries are polyether, polyester, polycarbonate and also acrylic polyols. Polyether polyols may be further subdivided and classified as polyethylene oxide or polyethylene glycol (PEG), polypropylene glycol (PPG) and Polytetrahydrofuran or PTMEG. These have 2, 3 and 4 carbons respectively per oxygen atom in the repeat unit. Polycaprolactone polyols are also commercially available. There is also an increasing trend to use biobased (and hence renewable) polyols. Uses Polyether polyols have numerous uses. As an example, polyurethane foam is a big user of polyether polyols. Polye ...
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Nitroglycerin
Nitroglycerin (NG), (alternative spelling of nitroglycerine) also known as trinitroglycerin (TNG), nitro, glyceryl trinitrate (GTN), or 1,2,3-trinitroxypropane, is a dense, colorless, oily, explosive liquid most commonly produced by nitrating glycerol with white fuming nitric acid under conditions appropriate to the formation of the nitric acid ester. Chemically, the substance is an organic nitrate compound rather than a nitro compound, but the traditional name is retained. Invented in 1847 by Ascanio Sobrero, nitroglycerin has been used ever since as an active ingredient in the manufacture of explosives, namely dynamite, and as such it is employed in the construction, demolition, and mining industries. Since the 1880s, it has been used by militaries as an active ingredient and gelatinizer for nitrocellulose in some solid propellants such as cordite and ballistite. It is a major component in double-based smokeless propellants used by reloaders. Combined with nitrocellulose, hund ...
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DMDNB
DMDNB, or also DMNB, chemically 2,3-dimethyl-2,3-dinitrobutane, is a volatile organic compound used as a detection taggant for explosives, mostly in the United States where it is virtually the only such taggant in use. Dogs are very sensitive to it and can detect as little as 0.5 parts per billion in the air, as can specialised ion mobility spectrometers. Its presence allows more reliable explosive detection Explosive detection is a non-destructive inspection process to determine whether a container contains explosive material. Explosive detection is commonly used at airports, ports and for border control. Detection tools Colorimetrics & automate .... References Explosive chemicals {{DEFAULTSORT:Dmdnb Nitro compounds Explosive detection ...
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Explosive Detection
Explosive detection is a non-destructive inspection process to determine whether a container contains explosive material. Explosive detection is commonly used at airports, ports and for border control. Detection tools Colorimetrics & automated colorimetrics The use of colorimetric test kits for explosive detection is one of the most established, simplest, and most widely used methods for the detection of explosives. Colorimetric detection of explosives involves applying a chemical reagent to an unknown material or sample and observing a color reaction. Common color reactions are known and indicate to the user if there is an explosive material present and in many cases the group of explosives from which the material is derived. The major groups of explosives are nitroaromatic, nitrate ester, and nitramine explosives, as well as inorganic nitrate-based explosives. Other groups include chlorates and peroxides which are not nitro based explosives. Since explosives usually contain ...
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Semtex
Semtex is a general-purpose plastic explosive containing RDX and Pentaerythritol tetranitrate, PETN. It is used in commercial blasting, demolition, and in certain military applications. Semtex was developed and manufactured in Czechoslovakia, originally under the name B 1 and then under the "Semtex" designation since 1964, labeled as ''SEMTEX 1A'', since 1967 as ''SEMTEX H'', and since 1987 as ''SEMTEX 10''. Originally developed for Czechoslovak military use and export, Semtex eventually became popular with paramilitary groups and rebels or terrorism, terrorists because prior to 2000 it was extremely difficult to detect, as in the case of Pan Am Flight 103. Composition The composition of the two most common variants differ according to their use. The 1A (or 10) variant is used for drilling and blasting, mining, and is based mostly on crystalline Pentaerythritol tetranitrate, PETN. The versions 1AP and 2P are formed as hexagonal Explosive booster, booster charges; a special assem ...
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Plastic Explosive
Plastic explosive is a soft and hand-moldable solid form of explosive material. Within the field of explosives engineering, plastic explosives are also known as putty explosives or blastics. Plastic explosives are especially suited for explosive demolition. Common plastic explosives include Semtex and C-4. The first manufactured plastic explosive was gelignite in 1875, invented by Alfred Nobel. Usage Plastic explosives are especially suited for explosive demolition of obstacles and fortifications by engineers, combat engineers and criminals as they can be easily formed into the best shapes for cutting structural members and have a high enough velocity of detonation and density for metal cutting work. An early use of plastic explosives was in the warhead of the Petard demolition mortar of the British Armoured Vehicle Royal Engineers (AVRE); said mortar was used to destroy concrete fortifications encountered during Operation Overlord (D-Day). The original use of Nobel 808 s ...
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