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Electromethanogenesis
Electromethanogenesis is a form of electrofuel production where methane is produced by direct biological conversion of electrical current and carbon dioxide. Methane producing technologies garnered interest from the scientific community prior to 2000, but electromethanogenesis did not become a significant area of interest until 2008. Publications concerning catalytic methanation have increased from 44 to over 130 since 2008. Electromethanogenesis has drawn more research due to its proposed applications. The production of methane from electrical current may provide an approach to renewable energy storage. Electrical current produced from renewable energy sources may, through electromethanogenesis, be converted into methane which may then be used as a biofuel. It may also be a useful method for the capture of carbon dioxide which may be used for air purification. In nature, methane formation occurs biotically and abiotically. Abiogenic methane is produced on a smaller scale and the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electromethanogenesis
Electromethanogenesis is a form of electrofuel production where methane is produced by direct biological conversion of electrical current and carbon dioxide. Methane producing technologies garnered interest from the scientific community prior to 2000, but electromethanogenesis did not become a significant area of interest until 2008. Publications concerning catalytic methanation have increased from 44 to over 130 since 2008. Electromethanogenesis has drawn more research due to its proposed applications. The production of methane from electrical current may provide an approach to renewable energy storage. Electrical current produced from renewable energy sources may, through electromethanogenesis, be converted into methane which may then be used as a biofuel. It may also be a useful method for the capture of carbon dioxide which may be used for air purification. In nature, methane formation occurs biotically and abiotically. Abiogenic methane is produced on a smaller scale and the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrohydrogenesis
Electrohydrogenesis or biocatalyzed electrolysis is the name given to a process for generating hydrogen gas from organic matter being decomposed by bacteria. This process uses a modified fuel cell to contain the organic matter and water. A small amount, 0.2–0.8 V of electricity is used, the original article reports an overall energy efficiency of 288% can be achieved (this is computed relative to the amount of electricity used, waste heat lowers the overall efficiency). This work was reported by Cheng and Logan. See also *Biohydrogen *Electrochemical reduction of carbon dioxide *Electromethanogenesis * Fermentative hydrogen production *Microbial fuel cell Microbial fuel cell (MFC) is a type of bioelectrochemical fuel cell system that generates electric current by diverting electrons produced from the microbial oxidation of reduced compounds (also known as fuel or electron donor) on the anode to oxid ... References External linksBiocatalyzed electrolysis{Dead link, date=A ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sabatier Reaction
The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures (optimally 300–400 °C) and pressures (perhaps 3 MPa ) in the presence of a nickel catalyst. It was discovered by the French chemists Paul Sabatier and Jean-Baptiste Senderens in 1897. Optionally, ruthenium on alumina (aluminium oxide) makes a more efficient catalyst. It is described by the following exothermic reaction. :CO2 + 4H2 -> atop 400\ ^\circ\ce\ce] CH4 + 2H2O∆''H'' = −165.0 kJ/mol There is disagreement on whether the CO2 methanation occurs by first associatively adsorbing an adatom hydrogen and forming oxygen intermediates before hydrogenation or dissociating and forming a carbonyl before being hydrogenated. : + 3H2 -> + H2O∆''H'' = −206 kJ/mol CO methanation is believed to occur through a dissociative mechanism where the carbon oxygen bond is broken before hydrogenation with an associative mechanism only being ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microbial Fuel Cell
Microbial fuel cell (MFC) is a type of bioelectrochemical fuel cell system that generates electric current by diverting electrons produced from the microbial oxidation of reduced compounds (also known as fuel or electron donor) on the anode to oxidized compounds such as oxygen (also known as oxidizing agent or electron acceptor) on the cathode through an external electrical circuit. MFCs can be grouped into two general categories: mediated and unmediated. The first MFCs, demonstrated in the early 20th century, used a mediator: a chemical that transfers electrons from the bacteria in the cell to the anode. Unmediated MFCs emerged in the 1970s; in this type of MFC the bacteria typically have electrochemically active redox proteins such as cytochromes on their outer membrane that can transfer electrons directly to the anode. In the 21st century MFCs have started to find commercial use in wastewater treatment. History The idea of using microbes to produce electricity was conceived in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrochemical Reduction Of Carbon Dioxide
The electrochemical reduction of carbon dioxide, also known as electrolysis of carbon dioxide, is the conversion of carbon dioxide () to more reduced chemical species using electrical energy. It is one possible step in the broad scheme of carbon capture and utilization, nevertheless it is deemed to be one of the most promising approaches. Electrochemical reduction of carbon dioxide represents a possible means of producing chemicals or fuels, converting carbon dioxide () to organic feedstocks such as formic acid (HCOOH), carbon monoxide (CO), methane (CH4), ethylene (C2H4) and ethanol (C2H5OH). Among the more selective metallic catalysts in this field are tin for formic acid, silver for carbon monoxide and copper for methane, ethylene or ethanol. Methanol, propanol and 1-butanol have also been produced via CO2 electrochemical reduction, albeit in small quantities. The first examples of electrochemical reduction of carbon dioxide are from the 19th century, when carbon dioxide ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bioelectrochemical Reactor
A Bioelectrochemical reactor is a type of bioreactor where bioelectrochemical processes are used to degrade/produce organic materials using microorganisms. This bioreactor has two compartments: The anode, where the oxidation reaction takes place; And the cathode, where the reduction occurs. At these sites, electrons are passed to and from microbes to power reduction of protons, breakdown of organic waste, or other desired processes. They are used in microbial electrosynthesis, environmental remediation, and electrochemical energy conversion. Examples of bioelectrochemical reactors include microbial electrolysis cells, microbial fuel cells, enzymatic biofuel cells, electrolysis cells, microbial electrosynthesis cells, and biobatteries. Principles Electron current is inherent to microbial metabolism. Microorganisms transfer electrons from an electron donor (lower potential species) to an electron acceptor (higher potential species). If the electron acceptor is an external ion ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Overpotential
In electrochemistry, overpotential is the potential difference (voltage) between a half-reaction's thermodynamically determined reduction potential and the potential at which the redox event is experimentally observed. The term is directly related to a cell's ''voltage efficiency''. In an electrolytic cell the existence of overpotential implies that the cell requires more energy than thermodynamically expected to drive a reaction. In a galvanic cell the existence of overpotential means less energy is recovered than thermodynamics predicts. In each case the extra/missing energy is lost as heat. The quantity of overpotential is specific to each cell design and varies across cells and operational conditions, even for the same reaction. Overpotential is experimentally determined by measuring the potential at which a given current density (typically small) is achieved. Thermodynamics The four possible polarities of overpotentials are listed below. * An electrolytic cell's anode ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Biotechnology
Biotechnology is the integration of natural sciences and engineering sciences in order to achieve the application of organisms, cells, parts thereof and molecular analogues for products and services. The term ''biotechnology'' was first used by Károly Ereky in 1919, meaning the production of products from raw materials with the aid of living organisms. Definition The concept of biotechnology encompasses a wide range of procedures for modifying living organisms according to human purposes, going back to domestication of animals, cultivation of the plants, and "improvements" to these through breeding programs that employ artificial selection and hybridization. Modern usage also includes genetic engineering as well as cell and tissue culture technologies. The American Chemical Society defines biotechnology as the application of biological organisms, systems, or processes by various industries to learning about the science of life and the improvement of the value of materials ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrochemistry
Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outcome of a particular chemical change, or vice versa. These reactions involve electrons moving via an electronically-conducting phase (typically an external electrical circuit, but not necessarily, as in electroless plating) between electrodes separated by an ionically conducting and electronically insulating electrolyte (or ionic species in a solution). When a chemical reaction is driven by an electrical potential difference, as in electrolysis, or if a potential difference results from a chemical reaction as in an electric battery or fuel cell, it is called an ''electrochemical'' reaction. Unlike in other chemical reactions, in electrochemical reactions electrons are not transferred directly between atoms, ions, or molecules, but via the af ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Environmental Engineering
Environmental engineering is a professional engineering discipline that encompasses broad scientific topics like chemistry, biology, ecology, geology, hydraulics, hydrology, microbiology, and mathematics to create solutions that will protect and also improve the health of living organisms and improve the quality of the environment. Environmental engineering is a sub-discipline of civil engineering and chemical engineering. While on the part of civil engineering, the Environmental Engineering is focused mainly on Sanitary Engineering. Environmental engineering is the application of scientific and engineering principles to improve and maintain the environment to: * protect human health, *protect nature's beneficial ecosystems, *and improve environmental-related enhancement of the quality of human life. Environmental engineers devise solutions for wastewater management, water and air pollution control, recycling, waste disposal, and public health. They design municipal water supply ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoelectrolysis
Photoelectrochemistry is a subfield of study within physical chemistry concerned with the interaction of light with electrochemical systems. It is an active domain of investigation. One of the pioneers of this field of electrochemistry was the German electrochemist Heinz Gerischer. The interest in this domain is high in the context of development of renewable energy conversion and storage technology. Historical approach Photoelectrochemistry has been intensively studied in the 1970-80s because of the first peak oil crisis. Because fossil fuels are non-renewable, it is necessary to develop processes to obtain renewable resources and use clean energy. Artificial photosynthesis, photoelectrochemical water splitting and regenerative solar cells are of special interest in this context. The photovoltaic effect was discovered by Alexandre Edmond Becquerel. Heinz Gerischer, H. Tributsch, AJ. Nozik, AJ. Bard, A. Fujishima, K. Honda, PE. Laibinis, K. Rajeshwar, TJ Meyer, PV. Kamat, N ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrochemical Engineering
Electrochemical engineering is the branch of chemical engineering dealing with the technological applications of electrochemical phenomena, such as electrosynthesis of chemicals, electrowinning and refining of metals, flow batteries and fuel cells, surface modification by electrodeposition, electrochemical separations and corrosion. This discipline is an overlap between electrochemistry and chemical engineering. According with the IUPAC, the term ''electrochemical engineering'' is reserved for electricity intensive processes for industrial or energy storage applications, and should not be confused with ''applied electrochemistry'', which comprises small batteries, amperometric sensors, microfluidic devices, microelectrodes, solid-state devices, voltammetry at disc electrodes, etc. More than 6% of the electricity is consumed by large-scale electrochemical operations in the US. Scope Electrochemical engineering combines the study of heterogeneous charge transfer at electrode/ele ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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