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Effusion (other)
In physics and chemistry, effusion is the process in which a gas escapes from a container through a hole of diameter considerably smaller than the mean free path of the molecules. Such a hole is often described as a ''pinhole'' and the escape of the gas is due to the pressure difference between the container and the exterior. Under these conditions, essentially all molecules which arrive at the hole continue and pass through the hole, since collisions between molecules in the region of the hole are negligible. Conversely, when the diameter is larger than the mean free path of the gas, flow obeys the Sampson flow law. In medical terminology, an effusion refers to accumulation of fluid in an anatomic space, usually without loculation. Specific examples include subdural, mastoid, pericardial and pleural effusions. Etymology The word effusion derives from the Latin word, effundo, which means "shed, pour forth, pour out, utter, lavish, waste." Effusion into vacuum Effusion from ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Effusion
In physics and chemistry, effusion is the process in which a gas escapes from a container through a hole of diameter considerably smaller than the mean free path of the molecules. Such a hole is often described as a ''pinhole'' and the escape of the gas is due to the pressure difference between the container and the exterior. Under these conditions, essentially all molecules which arrive at the hole continue and pass through the hole, since collisions between molecules in the region of the hole are negligible. Conversely, when the diameter is larger than the mean free path of the gas, flow obeys the Sampson flow law. In medical terminology, an effusion refers to accumulation of fluid in an anatomic space, usually without loculation. Specific examples include subdural, mastoid, pericardial and pleural effusions. Etymology The word effusion derives from the Latin word, effundo, which means "shed, pour forth, pour out, utter, lavish, waste." Effusion into vacuum Effusion from ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kinetic Theory Of Gases
Kinetic (Ancient Greek: κίνησις “kinesis”, movement or to move) may refer to: * Kinetic theory, describing a gas as particles in random motion * Kinetic energy, the energy of an object that it possesses due to its motion Art and entertainment * Kinetic art, a form of art involving mechanical and/or random movement, including optical illusions. * ''Kinetic'', the 13th episode of the first season of the TV series ''Smallville'' * ''Kinetic'' (comics), a comic by Allan Heinberg and Kelley Pucklett * "Kinetic" (song), a song by Radiohead Companies * Kinetic Engineering Limited, Indian automotive manufacturer * Kinetic Group, Australian-based public transport company Technology * "Kinetic", Seiko's trademark for its automatic quartz technology * The ''Kinetic camera system'' by Birt Acres (1854–1918), photographer and film pioneer * Kinetic projectile Military terminology * Kinetic military action See also * * * Kinetics (other) * Dynamics (disambiguatio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Clausius–Clapeyron Relation
The Clausius–Clapeyron relation, named after Rudolf Clausius and Benoît Paul Émile Clapeyron, specifies the temperature dependence of pressure, most importantly vapor pressure, at a discontinuous phase transition between two phases of matter of a single constituent. Its relevance to meteorology and climatology is the increase of the water-holding capacity of the atmosphere by about 7% for every 1 °C (1.8 °F) rise in temperature. Definition On a pressure–temperature (''P''–''T'') diagram, the line separating the two phases is known as the coexistence curve. The Clapeyron relation gives the slope of the tangents to this curve. Mathematically, :\frac = \frac=\frac, where \mathrmP/\mathrmT is the slope of the tangent to the coexistence curve at any point, L is the specific latent heat, T is the temperature, \Delta v is the specific volume change of the phase transition, and \Delta s is the specific entropy change of the phase transition. The Clausius–Clape ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat Of Sublimation
In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid. For elemental metals, it is also equal to the standard enthalpy of formation of the gaseous metal atoms. The heat of sublimation is usually expressed in kJ/mol, although the less customary kJ/kg is also encountered. Sublimation enthalpies See also * Heat * Sublimation (chemistry) * Phase transition In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states o ... * Clausius-Clapeyron equation References {{DEFAULTSORT:Enthalpy Of Sublimation Enthalpy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sublimation (phase Transition)
Sublimation is the transition of a substance directly from the solid to the gas state, without passing through the liquid state. Sublimation is an endothermic process that occurs at temperatures and pressures below a substance's triple point in its phase diagram, which corresponds to the lowest pressure at which the substance can exist as a liquid. The reverse process of sublimation is deposition or desublimation, in which a substance passes directly from a gas to a solid phase. Sublimation has also been used as a generic term to describe a solid-to-gas transition (sublimation) followed by a gas-to-solid transition ( deposition). While vaporization from liquid to gas occurs as evaporation from the surface if it occurs below the boiling point of the liquid, and as boiling with formation of bubbles in the interior of the liquid if it occurs at the boiling point, there is no such distinction for the solid-to-gas transition which always occurs as sublimation from the surface. At ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vapor Pressure
Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's evaporation rate. It relates to the tendency of particles to escape from the liquid (or a solid). A substance with a high vapor pressure at normal temperatures is often referred to as '' volatile''. The pressure exhibited by vapor present above a liquid surface is known as vapor pressure. As the temperature of a liquid increases, the kinetic energy of its molecules also increases. As the kinetic energy of the molecules increases, the number of molecules transitioning into a vapor also increases, thereby increasing the vapor pressure. The vapor pressure of any substance increases non-linearly with temperature according ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Knudsen Cell
In crystal growth, a Knudsen cell is an effusion evaporator source for relatively low partial pressure elementary sources (e.g. Ga, Al, Hg, As). Because it is easy to control the temperature of the evaporating material in Knudsen cells, they are commonly used in molecular-beam epitaxy. Development The Knudsen effusion cell was developed by Martin Knudsen (1871-1949). A typical Knudsen cell contains a crucible (made of pyrolytic boron nitride, quartz, tungsten or graphite), heating filaments (often made of metal tantalum), water cooling system, heat shields, and an orifice shutter. Vapor pressure measurement The Knudsen cell is used to measure the vapor pressures of a solid with very low vapor pressure. Such a solid forms a vapor at low pressure by sublimation. The vapor slowly effuses through the pinhole, and the loss of mass is proportional to the vapor pressure and can be used to determine this pressure.Peter Atkins and Julio de Paula, ''Physical Chemistry'' (8th ed., W.H.Freem ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thomas Graham (chemist)
Thomas Graham (21 December 1805 – 16 September 1869) was a British chemist known for his pioneering work in dialysis and the diffusion of gases. He is regarded as one of the founders of colloid chemistry. Life Graham was born in Glasgow, and educated at the High School of Glasgow. Graham's father was a successful textile manufacturer, and wanted his son to enter into the Church of Scotland. Instead, defying his father's wishes, Graham became a student at the University of Glasgow in 1819. There he developed a strong interest in chemistry, studying under Professor Thomas Thomson, who was impressed and influenced by the young man. He left the University after receiving his MA in 1824. He later studied medicine at the University of Edinburgh and then briefly taught chemistry at the Glasgow University Portland Street Medical School. In 1828 he was elected an Honorary Fellow of the Royal Society of Edinburgh, his proposer was Edward Turner. He won the Society's Keith Medal for ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Graham's Law
Graham's law of effusion (also called Graham's law of diffusion) was formulated by Scottish physical chemist Thomas Graham (chemist), Thomas Graham in 1848.Keith J. Laidler and John M. Meiser, ''Physical Chemistry'' (Benjamin/Cummings 1982), pp. 18–19 Graham found experimentally that the rate of effusion of a gas is inversely proportional to the square root of the molar mass of its particles. This formula is stated as: :=\sqrt, where: :Rate1 is the rate of effusion for the first gas. (volume or number of moles per unit time). :Rate2 is the rate of effusion for the second gas. :''M1'' is the molar mass of gas 1 :''M2'' is the molar mass of gas 2. Graham's law states that the rate of diffusion or of effusion of a gas is inversely proportional to the square root of its molecular weight. Thus, if the molecular weight of one gas is four times that of another, it would diffuse through a porous plug or escape through a small pinhole in a vessel at half the rate of the other (heavi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Absolute Temperature
Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics. Historically, thermodynamic temperature was defined by Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are now understood as manifestations of the kinetic energy of free motion of microscopic particles such as atoms, molecules, and electrons. From the thermodynamic viewpoint, for historical reasons, because of how it is defined and measured, this microscopic kinetic definition is regarded as an "empirical" temperature. It was adopted because in practice it can generally be measured more precisely than can Kelvin's thermodynamic temperature. A thermodynamic temperature reading of zero is of particular importance for the third law of thermodynamics. By convention, it is reported on the ''Kelvin scale'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Peter Atkins
Peter William Atkins (born 10 August 1940) is an English chemist and a Fellow of Lincoln College at the University of Oxford. He retired in 2007. He is a prolific writer of popular chemistry textbooks, including ''Physical Chemistry'', ''Inorganic Chemistry'', and ''Molecular Quantum Mechanics''. Atkins is also the author of a number of popular science books, including ''Atkins' Molecules'', ''Galileo's Finger: The Ten Great Ideas of Science'' and ''On Being''. Career Atkins left school (Dr Challoner's Grammar School, Amersham) at fifteen and took a job at Monsanto as a laboratory assistant. He studied for A-levels by himself and gained a place, following a last-minute interview, at the University of Leicester. Atkins studied chemistry there, obtaining a BSc degree in chemistry, and a PhD degree in 1964 for research into electron spin resonance spectroscopy, and other aspects of theoretical chemistry. Atkins then took a postdoctoral position at UCLA as a Harkness Fellow of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Maxwell–Boltzmann Distribution
In physics (in particular in statistical mechanics), the Maxwell–Boltzmann distribution, or Maxwell(ian) distribution, is a particular probability distribution named after James Clerk Maxwell and Ludwig Boltzmann. It was first defined and used for describing particle speeds in idealized gases, where the particles move freely inside a stationary container without interacting with one another, except for very brief collisions in which they exchange energy and momentum with each other or with their thermal environment. The term "particle" in this context refers to gaseous particles only (atoms or molecules), and the system of particles is assumed to have reached thermodynamic equilibrium.''Statistical Physics'' (2nd Edition), F. Mandl, Manchester Physics, John Wiley & Sons, 2008, The energies of such particles follow what is known as Maxwell–Boltzmann statistics, and the statistical distribution of speeds is derived by equating particle energies with kinetic energy. Mathematica ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
