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Digermyne With GeGe Single Bond-synthesis
Digermynes are a class of compounds that are regarded as the heavier digermanium analogues of alkynes. The parent member of this entire class is HGeGeH, which has only been characterized computationally, but has revealed key features of the whole class. Because of the large interatomic repulsion between two Ge atoms, only kinetically stabilized digermyne molecules can be synthesized and characterized by utilizing bulky protecting groups and appropriate synthetic methods, for example, reductive coupling of germanium(II) halides. The bonding between two Ge atoms in digermyne is different from C≡C bond in alkynes, which results in the ''trans''-bent structure of digermyne. ''Trans''-bent structure is quite common in heavier Group 14 element analogues of alkynes. The second order Jahn-Teller (SOJT) effect of digermynes gives rise to slipped π-bond and large molecular geometrical distortion. Because of the multibonded feature of digermynes and the large interatomic repulsion of t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Digermyne With GeGe Single Bond-synthesis
Digermynes are a class of compounds that are regarded as the heavier digermanium analogues of alkynes. The parent member of this entire class is HGeGeH, which has only been characterized computationally, but has revealed key features of the whole class. Because of the large interatomic repulsion between two Ge atoms, only kinetically stabilized digermyne molecules can be synthesized and characterized by utilizing bulky protecting groups and appropriate synthetic methods, for example, reductive coupling of germanium(II) halides. The bonding between two Ge atoms in digermyne is different from C≡C bond in alkynes, which results in the ''trans''-bent structure of digermyne. ''Trans''-bent structure is quite common in heavier Group 14 element analogues of alkynes. The second order Jahn-Teller (SOJT) effect of digermynes gives rise to slipped π-bond and large molecular geometrical distortion. Because of the multibonded feature of digermynes and the large interatomic repulsion of t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ag(Ar1GeGeAr1) Cation
A&G, AG, Ag or ag may refer to Businesses and organizations * A&G Railroad (former reporting mark AG) * Action Group (Nigeria), a political party during the Nigerian First Republic * Aktiengesellschaft, a German type of corporation * Assemblies of God, the world's largest Pentecostal organization * Associated Group, a Pakistani company * Astronomische Gesellschaft, a German astronomical society * IATA code for Aruba Airlines Entertainment * '' American Gladiators'' (1989–1996 TV series) * ''American Gladiators'' (2008 TV series) Government and military * Adjutant general, the Army branch responsible for personnel * Administrator-General of South West Africa, the head of government in Namibia prior to independence in 1990 * Aerographer's mate, a rating or specialty in the US Navy that deals with weather and oceanography * American Holland-class submarine (''Amerikansky Golland''), a class of Imperial Russian submarines * Army green, the color of the US Army service uni ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Addition Reaction Of Digermynes With Alcohols And Water
Addition (usually signified by the plus symbol ) is one of the four basic operations of arithmetic, the other three being subtraction, multiplication and division. The addition of two whole numbers results in the total amount or '' sum'' of those values combined. The example in the adjacent image shows a combination of three apples and two apples, making a total of five apples. This observation is equivalent to the mathematical expression (that is, "3 ''plus'' 2 is equal to 5"). Besides counting items, addition can also be defined and executed without referring to concrete objects, using abstractions called numbers instead, such as integers, real numbers and complex numbers. Addition belongs to arithmetic, a branch of mathematics. In algebra, another area of mathematics, addition can also be performed on abstract objects such as vectors, matrices, subspaces and subgroups. Addition has several important properties. It is commutative, meaning that the order of the operands ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Second Order Jahn-Teller Effect-digermyne
The second (symbol: s) is the unit of time in the International System of Units (SI), historically defined as of a day – this factor derived from the division of the day first into 24 hours, then to 60 minutes and finally to 60 seconds each (24 × 60 × 60 = 86400). The current and formal definition in the International System of Units ( SI) is more precise:The second ..is defined by taking the fixed numerical value of the caesium frequency, Δ''ν''Cs, the unperturbed ground-state hyperfine transition frequency of the caesium 133 atom, to be when expressed in the unit Hz, which is equal to s−1. This current definition was adopted in 1967 when it became feasible to define the second based on fundamental properties of nature with caesium clocks. Because the speed of Earth's rotation varies and is slowing ever so slightly, a leap second is added at irregular intervals to civil time to keep clocks in sync with Earth's rotation. Uses Analog clocks and watches often have ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Valence Bond Model Of Digermyne
Valence or valency may refer to: Science * Valence (chemistry), a measure of an element's combining power with other atoms * Degree (graph theory), also called the valency of a vertex in graph theory * Valency (linguistics), aspect of verbs relative to other parts of speech * Valence (psychology) or hedonic tone, the (emotional) value associated with an event, object or situation Places France * Valence, Charente, a commune in the Charente department * Valence, Drôme, Drôme, a commune and prefecture of the Drôme department ** University of Valence, a medieval university * Valence, Tarn-et-Garonne, a commune in the Tarn-et-Garonne department * Canton of Valence, Tarn-et-Garonne department * Arrondissement of Valence, Drôme department * Roman Catholic Diocese of Valence * Valence-d'Albigeois, in the Tarn department * Valence-en-Brie, in the Seine-et-Marne department * Valence-sur-Baïse, in the Gers department * Bourg-lès-Valence, in the Drôme department England * River ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Planar Vs Trans-bent-digermyne
Planar is an adjective meaning "relating to a plane (geometry)". Planar may also refer to: Science and technology * Planar (computer graphics), computer graphics pixel information from several bitplanes * Planar (transmission line technologies), transmission lines with flat conductors * Planar, the structure resulting from the planar process used in the manufacture of semiconductor devices, such as planar transistors * Planar graph, graph that can be drawn in the plane so that no edges cross * Planar mechanism, a system of parts whose motion is constrained to a two-dimensional plane * Planar Systems, an Oregon-headquartered manufacturer of digital displays * Zeiss Planar, photographic lens designed by Paul Rudolph at Carl Zeiss in 1896 See also * List of planar symmetry groups * Planarity, a computer puzzle game * Plane (other) * Planer (other) The term planer may refer to several types of carpentry, carpentry tools, woodworking machines or metalworking machine ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
The Synthesis Of BbtGeGeBbt-pngversion
''The'' () is a grammatical article in English, denoting persons or things already mentioned, under discussion, implied or otherwise presumed familiar to listeners, readers, or speakers. It is the definite article in English. ''The'' is the most frequently used word in the English language; studies and analyses of texts have found it to account for seven percent of all printed English-language words. It is derived from gendered articles in Old English which combined in Middle English and now has a single form used with pronouns of any gender. The word can be used with both singular and plural nouns, and with a noun that starts with any letter. This is different from many other languages, which have different forms of the definite article for different genders or numbers. Pronunciation In most dialects, "the" is pronounced as (with the voiced dental fricative followed by a schwa) when followed by a consonant sound, and as (homophone of pronoun ''thee'') when followed by a v ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alkyne
\ce \ce Acetylene \ce \ce \ce Propyne \ce \ce \ce \ce 1-Butyne In organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond. The simplest acyclic alkynes with only one triple bond and no other functional groups form a homologous series with the general chemical formula . Alkynes are traditionally known as acetylenes, although the name ''acetylene'' also refers specifically to , known formally as ethyne using IUPAC nomenclature. Like other hydrocarbons, alkynes are generally hydrophobic. Structure and bonding In acetylene, the H–C≡C bond angles are 180°. By virtue of this bond angle, alkynes are rod-like. Correspondingly, cyclic alkynes are rare. Benzyne cannot be isolated. The C≡C bond distance of 121 picometers is much shorter than the C=C distance in alkenes (134 pm) or the C–C bond in alkanes (153 pm). : The triple bond is very strong with a bond strength of 839 kJ/mol. The sigma bond contribute ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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