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Carpacin
Carpacin is a naturally occurring organic compound first isolated from the Carpano tree (an unidentified ''Cinnamomum'' species of the family Lauraceae which is native to Bougainville Island), from which it derives its name. It is also found in essential oils of the genus ''Crowea''. Carpacin is a biosynthetic precursor of the more complex lignan-dimer, carpanone. It is classified as a phenylpropanoid. Carpacin has been prepared synthetically from sesamol and has been studied for potential use as an insecticide and inhibitor of carcinogenesis Carcinogenesis, also called oncogenesis or tumorigenesis, is the formation of a cancer, whereby normal cells are transformed into cancer cells. The process is characterized by changes at the cellular, genetic, and epigenetic levels and abnor .... References {{Phenylpropene Phenylpropenes O-methylated phenylpropanoids Benzodioxoles ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carpanone
Carpanone is a naturally occurring lignan-type natural product most widely known for the remarkably complex way nature prepares it, and the similarly remarkable success that an early chemistry group, that of Orville L. Chapman, had at mimicking nature's pathway.C.W. Lindsley, C.R. Hopkins & G.A. Sulikowski, 2011, Biomimetic synthesis of lignans, In "Biomimetic Organic Synthesis" (E. Poupon & B. Nay, Eds.), Weinheim: Wiley-VCH, , se accessed 4 June 2014.O.L. Chapman, M.R. Engel, J.P. Springer & J.C. Clardy, 1971, Total synthesis of carpanone, ''J. Am. Chem. Soc.'' 93:6697–6698. Carpanone is an organic compound first isolated from the carpano trees (''Cinnamomum sp.'') of Bougainville Island by Brophy and coworkers, trees from which the natural product derives its name.F. Liron, F. Fontana, J.-O. Zirimwabagabo, G. Prestat, J. Rajabi, C. La Rosa & G. Poli, 2009, A New Cross-Coupling-Based Synthesis of Carpanone, Org. Lett., 11(19):4378–4381, DOI: 10.1021/ol9017326, see o acces ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organic Compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, hydrogen cyanide), are not classified as organic compounds and are considered inorganic. Other than those just named, little consensus exists among chemists on precisely which carbon-containing compounds are excluded, making any rigorous definition of an organic compound elusive. Although organic compounds make up only a small percentage of Earth's crust, they are of central importance because all known life is based on organic compounds. Living t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cinnamomum
''Cinnamomum'' is a genus of evergreen aromatic trees and shrubs belonging to the laurel family, Lauraceae. The species of ''Cinnamomum'' have aromatic oils in their leaves and bark. The genus contains approximately 250 species, distributed in tropical and subtropical regions of South Asia, Southeast Asia, East Asia, Oceania, and Australasia. The genus includes a great number of economically important trees. Habitat This genus is present in the Himalayas and other mountain areas and is present in tropical and subtropical montane rainforests, in the weed-tree forests, in valleys, and mixed forests of coniferous and deciduous broad-leaved trees, from southern China, India, and Southeast Asia. Some species, such as ''Cinnamomum camphora'', tolerate drought. Characteristics All species tested so far are diploid, with the total number of chromosomes being 24. This Lauraceae genus comprises approximately 250 trees and shrubs and most are aromatic. Some trees produce sprouts. The thick ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lauraceae
Lauraceae, or the laurels, is a plant family that includes the true laurel and its closest relatives. This family comprises about 2850 known species in about 45 genera worldwide (Christenhusz & Byng 2016 ). They are dicotyledons, and occur mainly in warm temperate and tropical regions, especially Southeast Asia and South America. Many are aromatic evergreen trees or shrubs, but some, such as ''Sassafras'', are deciduous, or include both deciduous and evergreen trees and shrubs, especially in tropical and temperate climates. The genus ''Cassytha'' is unique in the Lauraceae in that its members are parasitic vines. Most laurels are highly-poisonous. Overview The family has a worldwide distribution in tropical and warm climates. The Lauraceae are important components of tropical forests ranging from low-lying to montane. In several forested regions, Lauraceae are among the top five families in terms of the number of species present. The Lauraceae give their name to habitats know ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bougainville Island
Bougainville Island (Tok Pisin: ''Bogenvil'') is the main island of the Autonomous Region of Bougainville, which is part of Papua New Guinea. It was previously the main landmass in the German Empire-associated North Solomons. Its land area is . The population of the whole province, including nearby islets such as the Carterets, is approximately 300,000 (2019 census). The highest point is Mount Balbi, on the main island, at . The much smaller Buka Island, , lies to the north, across the wide Buka Strait. Even though the strait is narrow, there is no bridge across it, but there is a regular ferry service between the key settlements on either side. The main airport (or airstrip) in the north is in the town of Buka. Bougainville is the largest island in the Solomon Islands archipelago. Most of the islands in this archipelago (which are primarily concentrated in the southern and eastern portions of it) are part of the politically independent Solomon Islands. Two of these islands ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Essential Oil
An essential oil is a concentrated hydrophobic liquid containing volatile (easily evaporated at normal temperatures) chemical compounds from plants. Essential oils are also known as volatile oils, ethereal oils, aetheroleum, or simply as the oil of the plant from which they were extracted, such as oil of clove. An essential oil is essential in the sense that it contains the essence of the plant's fragrance—the characteristic fragrance of the plant from which it is derived. The term "essential" used here does ''not'' mean indispensable or usable by the human body, as with the terms essential amino acid or essential fatty acid, which are so called because they are nutritionally required by a living organism. Essential oils are generally extracted by distillation, often by using steam. Other processes include expression, solvent extraction, '' sfumatura'', absolute oil extraction, resin tapping, wax embedding, and cold pressing. They are used in perfumes, cosmetics, soaps, air ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crowea
''Crowea'' is a genus of small evergreen shrubs in the family Rutaceae, sometimes known as waxflowers. There are three species and many subspecies and cultivars, all of which are popular as ornamentals because of their abundant, attractive flowers which often occur during autumn and winter. ''Crowea'' species are all endemic to Australia, where they occur in Victoria, New South Wales and Western Australia. Description Croweas are evergreen shrubs to about 1.5 m tall. The leaves are simple, glabrous and, as with other members of the Rutaceae, have oil glands and are aromatic. The flowers occur singly in the axils of the leaves, are pink and star-shaped have five petals, five sepals and ten stamens in two rings around the ovary. ''Crowea'' are closely related, and the flowers similar in appearance to those of other member of the family Rutaceae, especially ''Philotheca'', ''Eriostemon'' and ''Boronia''. Taxonomy and naming The genus was described and named by James Edward Smith i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Biosynthesis
Biosynthesis is a multi-step, enzyme-catalyzed process where substrates are converted into more complex products in living organisms. In biosynthesis, simple compounds are modified, converted into other compounds, or joined to form macromolecules. This process often consists of metabolic pathways. Some of these biosynthetic pathways are located within a single cellular organelle, while others involve enzymes that are located within multiple cellular organelles. Examples of these biosynthetic pathways include the production of lipid membrane components and nucleotides. Biosynthesis is usually synonymous with anabolism. The prerequisite elements for biosynthesis include: precursor compounds, chemical energy (e.g. ATP), and catalytic enzymes which may require coenzymes (e.g.NADH, NADPH). These elements create monomers, the building blocks for macromolecules. Some important biological macromolecules include: proteins, which are composed of amino acid monomers joined via peptide bon ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lignan
The lignans are a large group of low molecular weight polyphenols found in plants, particularly seeds, whole grains, and vegetables. The name derives from the Latin word for "wood". Lignans are precursors to phytoestrogens. They may play a role as antifeedants in the defense of seeds and plants against herbivores. Biosynthesis and metabolism Lignans and lignin differ in their molecular weight, the former being small and soluble in water, the latter being high polymers that are undigestable. Both are polyphenolic substances derived by oxidative coupling of monolignols. Thus, most lignans feature a C18 cores, resulting from the dimerization of C9 precursors. The coupling of the lignols occurs at C8. Eight classes of lignans are: "furofuran, furan, dibenzylbutane, dibenzylbutyrolactone, aryltetralin, arylnaphthalene, dibenzocyclooctadiene, and dibenzylbutyrolactol." Many lignans are metabolized by mammalian gut microflora, producing so-called enterolignans. Food sources Flax s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phenylpropanoid
The phenylpropanoids are a diverse family of organic compounds that are synthesized by plants from the amino acids phenylalanine and tyrosine. Their name is derived from the six-carbon, aromatic phenyl group and the three-carbon propene tail of coumaric acid, which is the central intermediate in phenylpropanoid biosynthesis. From 4-coumaroyl-CoA emanates the biosynthesis of myriad natural products including lignols (precursors to lignin and lignocellulose), flavonoids, isoflavonoids, coumarins, aurones, stilbenes, catechin, and phenylpropanoids. The coumaroyl component is produced from cinnamic acid. Phenylpropanoids are found throughout the plant kingdom, where they serve as essential components of a number of structural polymers, provide protection from ultraviolet light, defend against herbivores and pathogens, and also mediate plant-pollinator interactions as floral pigments and scent compounds. Hydroxycinnamic acids Phenylalanine is first converted to cinnamic aci ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sesamol
Sesamol is a natural organic compound which is a component of sesame seeds and sesame oil, with anti- inflammatory, antioxidant, antidepressant and neuroprotective properties. It is a white crystalline solid that is a derivative of phenol. It is sparingly soluble in water, but miscible with most oils. It can be produced by organic synthesis from heliotropine. Sesamol has been found to be an antioxidant that may prevent the spoilage of oils. It also may prevent the spoilage of oils by acting as an antifungal. It can be used in the synthesis of paroxetine. Sesamol's molecular targets and mechanism of action, at least for its antidepressant-like effects, is found to be through the brain nerve growth factor (NGF) and endocannabinoid signalling under the regulatory drive of the CB1 receptors. Alexander Shulgin used sesamol in his book PiHKAL to make MMDA-2 MMDA-2 (2-methoxy-4,5-methylenedioxyamphetamine) is a psychedelic drug of the amphetamine class. It is closely relate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Insecticide
Insecticides are substances used to kill insects. They include ovicides and larvicides used against insect eggs and larvae, respectively. Insecticides are used in agriculture, medicine, industry and by consumers. Insecticides are claimed to be a major factor behind the increase in the 20th-century's agricultural productivity. Nearly all insecticides have the potential to significantly alter ecosystems; many are toxic to humans and/or animals; some become concentrated as they spread along the food chain. Insecticides can be classified into two major groups: systemic insecticides, which have residual or long term activity; and contact insecticides, which have no residual activity. The mode of action describes how the pesticide kills or inactivates a pest. It provides another way of classifying insecticides. Mode of action can be important in understanding whether an insecticide will be toxic to unrelated species, such as fish, birds and mammals. Insecticides may be repellent ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
