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Crystal Systems
In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices. Space groups are classified into crystal systems according to their point groups, and into lattice systems according to their Bravais lattices. Crystal systems that have space groups assigned to a common lattice system are combined into a crystal family. The seven crystal systems are triclinic, monoclinic, orthorhombic, tetragonal, trigonal, hexagonal, and cubic. Informally, two crystals are in the same crystal system if they have similar symmetries (albeit there are many exceptions). Classifications Crystals can be classified in three ways: lattice systems, crystal systems and crystal families. The various classifications are often confused: in particular the trigonal crystal system is often confused with the rhombohedral lattice system, and the term "crystal system" is sometimes used to mean "lattice ...
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Carbon Lattice Diamond
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes up only about 0.025 percent of Earth's crust. Three isotopes occur naturally, C and C being stable, while C is a radionuclide, decaying with a half-life of about 5,730 years. Carbon is one of the few elements known since antiquity. Carbon is the 15th most abundant element in the Earth's crust, and the fourth most abundant element in the universe by mass after hydrogen, helium, and oxygen. Carbon's abundance, its unique diversity of organic compounds, and its unusual ability to form polymers at the temperatures commonly encountered on Earth, enables this element to serve as a common element of all known life. It is the second most abundant element in the human body by mass (about 18.5%) after oxygen. The atoms of carbon can bond t ...
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Hanksite
Hanksite is a sulfate mineral, distinguished as one of only a handful that contain both carbonate and sulfate ion groups. It has the chemical formula Sodium, Na22Potassium, K(Sulfate, SO4)9(Carbonate, CO3)2Chlorine, Cl. Occurrence It was first described in 1888 for an occurrence in Searles Lake, California, and named for American geologist Henry Garber Hanks. Hanksite is normally found in crystal form as evaporite deposits. Hanksite crystals are large but not complex in structure. It is often found in Searles Lake, Soda Lake (San Luis Obispo County), Soda Lake, Mono Lake, and in Death Valley. At its deposits in San Bernardino County, California hanksite is commonly found beneath the surface embedded in mud or in drill cores (Palache et al., 1960). It is associated with halite, borax, trona and aphthitalite at the Searles Lake locality. It is also associated with borax mining in the Soda Lake area. Physical characteristics Hanksite can be colorless, white, gray, green or yellow an ...
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Chirality (chemistry)
In chemistry, a molecule or ion is called chiral () if it cannot be superposed on its mirror image by any combination of rotation (geometry), rotations, translation (geometry), translations, and some Conformational isomerism, conformational changes. This geometric property is called chirality (). The terms are derived from Ancient Greek χείρ (''cheir'') 'hand'; which is the canonical example of an object with this property. A chiral molecule or ion exists in two stereoisomers that are mirror images of each other, called enantiomers; they are often distinguished as either "right-handed" or "left-handed" by their absolute configuration or some other criterion. The two enantiomers have the same chemical properties, except when reacting with other chiral compounds. They also have the same physics, physical properties, except that they often have opposite optical activity, optical activities. A homogeneous mixture of the two enantiomers in equal parts is said to be racemic mixtu ...
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Triclinic Crystal System
180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal is described by vectors of unequal length, as in the orthorhombic system. In addition, the angles between these vectors must all be different and may not include 90°. The triclinic lattice is the least symmetric of the 14 three-dimensional Bravais lattices. It has (itself) the minimum symmetry all lattices have: points of inversion at each lattice point and at 7 more points for each lattice point: at the midpoints of the edges and the faces, and at the center points. It is the only lattice type that itself has no mirror planes. Crystal classes The triclinic crystal system class names, examples, Schönflies notation, Hermann-Mauguin notation, point groups, International Tables for Crystallography space group number, orbifold, type, and sp ...
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Group Theory
In abstract algebra, group theory studies the algebraic structures known as group (mathematics), groups. The concept of a group is central to abstract algebra: other well-known algebraic structures, such as ring (mathematics), rings, field (mathematics), fields, and vector spaces, can all be seen as groups endowed with additional operation (mathematics), operations and axioms. Groups recur throughout mathematics, and the methods of group theory have influenced many parts of algebra. Linear algebraic groups and Lie groups are two branches of group theory that have experienced advances and have become subject areas in their own right. Various physical systems, such as crystals and the hydrogen atom, and Standard Model, three of the four known fundamental forces in the universe, may be modelled by symmetry groups. Thus group theory and the closely related representation theory have many important applications in physics, chemistry, and materials science. Group theory is also ce ...
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Symmetry Number
The symmetry number or symmetry order of an object is the number of different but indistinguishable (or equivalent) arrangements (or views) of the object, that is, it is the order of its symmetry group. The object can be a molecule, crystal lattice, lattice, tiling, or in general any kind of mathematical object that admits symmetries. In statistical thermodynamics, the symmetry number corrects for any overcounting of equivalent molecular conformations in the partition function. In this sense, the symmetry number depends upon how the partition function is formulated. For example, if one writes the partition function of ethane so that the integral includes full rotation of a methyl, then the 3-fold rotational symmetry of the methyl group contributes a factor of 3 to the symmetry number; but if one writes the partition function so that the integral includes only one rotational energy well of the methyl, then the methyl rotation does not contribute to the symmetry number. Symmetry ...
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Coxeter Notation
In geometry, Coxeter notation (also Coxeter symbol) is a system of classifying symmetry groups, describing the angles between fundamental reflections of a Coxeter group in a bracketed notation expressing the structure of a Coxeter-Dynkin diagram, with modifiers to indicate certain subgroups. The notation is named after H. S. M. Coxeter, and has been more comprehensively defined by Norman Johnson. Reflectional groups For Coxeter groups, defined by pure reflections, there is a direct correspondence between the bracket notation and Coxeter-Dynkin diagram. The numbers in the bracket notation represent the mirror reflection orders in the branches of the Coxeter diagram. It uses the same simplification, suppressing 2s between orthogonal mirrors. The Coxeter notation is simplified with exponents to represent the number of branches in a row for linear diagram. So the ''A''''n'' group is represented by ''n''−1 to imply ''n'' nodes connected by ''n−1'' order-3 branches. Exampl ...
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Orbifold Notation
In geometry, orbifold notation (or orbifold signature) is a system, invented by the mathematician William Thurston and promoted by John Conway, for representing types of symmetry groups in two-dimensional spaces of constant curvature. The advantage of the notation is that it describes these groups in a way which indicates many of the groups' properties: in particular, it follows William Thurston in describing the orbifold obtained by taking the quotient of Euclidean space by the group under consideration. Groups representable in this notation include the point groups on the sphere (S^2), the frieze groups and wallpaper groups of the Euclidean plane (E^2), and their analogues on the hyperbolic plane (H^2). Definition of the notation The following types of Euclidean transformation can occur in a group described by orbifold notation: * reflection through a line (or plane) * translation by a vector * rotation of finite order around a point * infinite rotation around a line in 3- ...
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Hermann–Mauguin Notation
In geometry, Hermann–Mauguin notation is used to represent the symmetry elements in point groups, plane groups and space groups. It is named after the German crystallographer Carl Hermann (who introduced it in 1928) and the French mineralogist Charles-Victor Mauguin (who modified it in 1931). This notation is sometimes called international notation, because it was adopted as standard by the ''International Tables For Crystallography'' since their first edition in 1935. The Hermann–Mauguin notation, compared with the Schoenflies notation, is preferred in crystallography because it can easily be used to include translational symmetry elements, and it specifies the directions of the symmetry axes. Point groups Rotation axes are denoted by a number ''n'' — 1, 2, 3, 4, 5, 6, 7, 8 ... (angle of rotation ''φ'' = ). For improper rotations, Hermann–Mauguin symbols show rotoinversion axes, unlike Schoenflies and Shubnikov notations, that shows rotation-reflection axes ...
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Schönflies Notation
The Schoenflies (or Schönflies) notation, named after the German mathematician Arthur Moritz Schoenflies, is a notation primarily used to specify point groups in three dimensions. Because a point group alone is completely adequate to describe the symmetry of a molecule, the notation is often sufficient and commonly used for spectroscopy. However, in crystallography, there is additional translational symmetry, and point groups are not enough to describe the full symmetry of crystals, so the full space group is usually used instead. The naming of full space groups usually follows another common convention, the Hermann–Mauguin notation, also known as the international notation. Although Schoenflies notation without superscripts is a pure point group notation, optionally, superscripts can be added to further specify individual space groups. However, for space groups, the connection to the underlying symmetry elements is much more clear in Hermann–Mauguin notation, so the latter not ...
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Point Group
In geometry, a point group is a mathematical group of symmetry operations (isometries in a Euclidean space) that have a fixed point in common. The coordinate origin of the Euclidean space is conventionally taken to be a fixed point, and every point group in dimension ''d'' is then a subgroup of the orthogonal group O(''d''). Point groups are used to describe the symmetries of geometric figures and physical objects such as molecules. Each point group can be represented as sets of orthogonal matrices ''M'' that transform point ''x'' into point ''y'' according to Each element of a point group is either a rotation (determinant of ''M'' = 1), or it is a reflection or improper rotation (determinant of ''M'' = −1). The geometric symmetries of crystals are described by space groups, which allow translations and contain point groups as subgroups. Discrete point groups in more than one dimension come in infinite families, but from the crystallographic restriction theorem and ...
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Cubic Crystal System
In crystallography, the cubic (or isometric) crystal system is a crystal system where the Crystal_structure#Unit_cell, unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc, and alternatively called Close-packing_of_equal_spheres, ''cubic close-packed'' or ccp) Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive_cell, primitive unit cells often are not. Bravais lattices The three Bravais lattices in the cubic crystal system are: The primitive cubic lattice (cP) consists of one Lattice_(group), lattice point on each corner of the cube; this means each simple cubic unit cell has in total one latt ...
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