Combustion Cycle
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Combustion Cycle
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. The study of combustion is known as combustion science. Combustion is often a complicated sequence of elementary radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that incandescent light in the fo ...
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Coal
Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is a type of fossil fuel, formed when dead plant matter decays into peat which is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands called coal forests that covered much of the Earth's tropical land areas during the late Carboniferous (Pennsylvanian (geology), Pennsylvanian) and Permian times. Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the Industrial Revolution. With the invention of the steam engine, coal consumption increased. In 2020, coal supplied about a quarter of the world's primary energy and over a third of its Electricity generation, electricity. Some iron and steel-maki ...
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Chemical Equilibrium
In a chemical reaction, chemical equilibrium is the state in which both the Reagent, reactants and Product (chemistry), products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the Thermodynamic system, system. This state results when the forward reaction proceeds at the same rate as the Reversible reaction, reverse reaction. The reaction rates of the forward and backward reactions are generally not zero, but they are equal. Thus, there are no net changes in the concentrations of the reactants and products. Such a state is known as dynamic equilibrium. It is the subject of study of ''equilibrium chemistry''. Historical introduction The Concept learning, concept of chemical equilibrium was developed in 1803, after Claude Louis Berthollet, Berthollet found that some chemical reactions are Reversible reaction, reversible. For any reaction mixture to exist at equilibrium, the reaction rate, ...
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Stoichiometric
Stoichiometry () is the relationships between the masses of reactants and products before, during, and following chemical reactions. Stoichiometry is based on the law of conservation of mass; the total mass of reactants must equal the total mass of products, so the relationship between reactants and products must form a ratio of positive integers. This means that if the amounts of the separate reactants are known, then the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of the products can be empirically determined, then the amount of the other reactants can also be calculated. This is illustrated in the image here, where the unbalanced equation is: : : However, the current equation is imbalanced. The reactants have 4 hydrogen and 2 oxygen atoms, while the product has 2 hydrogen and 3 oxygen. To balance the hydrogen, a coefficient of 2 is added to the product H2O, and to fix the imbalance of oxygen, it is also added ...
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Enthalpy
Enthalpy () is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant external pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work (physics), work W that was done against constant external pressure P_\text to establish the system's physical dimensions from V_\text=0 to some final volume V_\text (as W=P_\text\Delta V), i.e. to make room for it by displacing its surroundings. The pressure-volume term is very small for solids and liquids at common conditions, and fairly small for gases. Therefore, enthalpy is a stand-in for energy in chemical systems; Bond energy, bond, Lattice energy, lattice, solvation, and other chemical "energies" are actually enthalpy differences. As a state function, enthalpy depends only on the final configuration of internal e ...
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Joule Per Mole
The joule per mole (symbol: J·mol−1 or J/mol) is the unit of energy per amount of substance in the International System of Units (SI), such that energy is measured in joules, and the amount of substance is measured in moles. It is also an SI derived unit of molar thermodynamic energy defined as the energy equal to one joule in one mole of substance. For example, the Gibbs free energy of a compound in the area of thermochemistry is often quantified in units of kilojoules per mole (symbol: kJ·mol−1 or kJ/mol), with 1 kilojoule = 1000 joules. Physical quantities measured in J·mol−1 usually describe quantities of energy transferred during phase transformations or chemical reactions. Division by the number of moles facilitates comparison between processes involving different quantities of material and between similar processes involving different types of materials. The precise meaning of such a quantity is dependent on the context (what substances are involved, circums ...
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Rocket Engine
A rocket engine is a reaction engine, producing thrust in accordance with Newton's third law by ejecting reaction mass rearward, usually a high-speed Jet (fluid), jet of high-temperature gas produced by the combustion of rocket propellants stored inside the rocket. However, non-combusting forms such as cold gas thrusters and nuclear thermal rockets also exist. Rocket vehicles carry their own oxidiser, unlike most combustion engines, so rocket engines can be used in a vacuum, and they can achieve great speed, beyond escape velocity. Vehicles commonly propelled by rocket engines include missiles, Rocket-assisted projectile, artillery shells, ballistic missiles and rockets of any size, from tiny Rocket (firework), fireworks to Rocket (weapon), man-sized weapons to huge Space vehicle, spaceships. Compared to other types of jet engine, rocket engines are the lightest and have the highest thrust, but are the least propellant-efficient (they have the lowest specific impulse). The ideal ...
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Vapor
In physics, a vapor (American English) or vapour (Commonwealth English; American and British English spelling differences#-our, -or, see spelling differences) is a substance in the gas phase at a temperature lower than its critical temperature,R. H. Petrucci, W. S. Harwood, and F. G. Herring, ''General Chemistry'', Prentice-Hall, 8th ed. 2002, p. 483–86. which means that the vapor can be condensation, condensed to a liquid by increasing the pressure on it without reducing the temperature of the vapor. A vapor is different from an aerosol. An aerosol is a suspension of tiny particles of liquid, solid, or both within a gas. For example, water has a critical temperature of , which is the highest temperature at which liquid water can exist at any pressure. In the Earth's atmosphere, atmosphere at ordinary temperatures gaseous water (known as water vapor) will condense into a liquid if its partial pressure is increased sufficiently. A vapor may co-exist with a liquid (or a solid). ...
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Water
Water is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance. It is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food energy or organic micronutrients. Its chemical formula, , indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. In liquid form, is also called "water" at standard temperature and pressure. Because Earth's environment is relatively close to water's triple point, water exists on Earth as a solid, a liquid, and a gas. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice ...
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Hydrogen
Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter. Under standard conditions, hydrogen is a gas of diatomic molecules with the chemical formula, formula , called dihydrogen, or sometimes hydrogen gas, molecular hydrogen, or simply hydrogen. Dihydrogen is colorless, odorless, non-toxic, and highly combustible. Stars, including the Sun, mainly consist of hydrogen in a plasma state, while on Earth, hydrogen is found as the gas (dihydrogen) and in molecular forms, such as in water and organic compounds. The most common isotope of hydrogen (H) consists of one proton, one electron, and no neutrons. Hydrogen gas was first produced artificially in the 17th century by the reaction of acids with metals. Henry Cavendish, in 1766–1781, identified hydrogen gas as a distinct substance and discovere ...
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Smouldering
Smouldering (British English) or smoldering (American English; see spelling differences) is the slow, flameless form of combustion, sustained by the heat evolved when oxygen directly attacks the surface of a condensed-phase fuel. Many solid materials can sustain a smouldering reaction, including coal, cellulose, wood, cotton, tobacco, cannabis, peat, plant litter, humus, synthetic foams, charring polymers including polyurethane foam and some types of dust. Common examples of smouldering phenomena are the initiation of residential fires on upholstered furniture by weak heat sources (e.g., a cigarette, a short-circuited wire), and the persistent combustion of biomass behind the flaming front of wildfires. Fundamentals The fundamental difference between smouldering and flaming combustion is that smouldering occurs on the surface of the solid rather than in the gas phase. Smouldering is a surface phenomenon but can propagate to the interior of a porous fuel if it is permea ...
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Light
Light, visible light, or visible radiation is electromagnetic radiation that can be visual perception, perceived by the human eye. Visible light spans the visible spectrum and is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequency, frequencies of 750–420 terahertz (unit), terahertz. The visible band sits adjacent to the infrared (with longer wavelengths and lower frequencies) and the ultraviolet (with shorter wavelengths and higher frequencies), called collectively ''optical radiation''. In physics, the term "light" may refer more broadly to electromagnetic radiation of any wavelength, whether visible or not. In this sense, gamma rays, X-rays, microwaves and radio waves are also light. The primary properties of light are intensity (physics), intensity, propagation direction, frequency or wavelength spectrum, and polarization (waves), polarization. Its speed of light, speed in vacuum, , is one of the fundamental physi ...
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