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Color Coupler
Dye coupler is present in chromogenic film and paper used in photography, primarily color photography. When a color developer reduces ionized (exposed) silver halide crystals, the developer is oxidized, and the oxidized molecules react with dye coupler molecules to form a dye ''in situ.'' The silver image is removed by subsequent bleach and fix processes, so the final image will consist of the dye image. Dye coupler technology has seen considerable advancement since the beginning of modern color photography. Major film and paper manufacturers have continually improved the stability of the image dye by improving couplers, particularly since the 1980s, so that archival properties of images are enhanced in newer color papers and films. Generally speaking, dye couplers for paper use are given more emphasis on the image permanence than those for film use, but some modern films (such as Fujichrome Provia Provia is a brandname for a pair of daylight-balanced color reversal films ...
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Chromogen
In chemistry, the term chromogen refers to a colourless (or faintly coloured) chemical compound that can be converted by chemical reaction into a compound which can be described as "coloured". There is no universally agreed definition of the term. Various dictionaries give the following definitions: * A substance capable of conversion into a pigment or dye. * Any substance that can become a pigment or coloring matter, a substance in organic fluids that forms colored compounds when oxidized, or a compound, not itself a dye, that can become a dye. * Any substance, itself without color, giving origin to a coloring matter. In biochemistry the term has a rather different meaning. The following are found in various dictionaries. * A precursor of a biochemical pigment * A pigment-producing microorganism * Any of certain bacteria that produce a pigment * A strongly pigmented or pigment-generating organelle, organ, or microorganism. Applications in chemistry *In chromogenic photography, f ...
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Photographic Film
Photographic film is a strip or sheet of transparent film base coated on one side with a gelatin photographic emulsion, emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the crystals determine the sensitivity, contrast, and image resolution, resolution of the film. The emulsion will gradually darken if left exposed to light, but the process is too slow and incomplete to be of any practical use. Instead, a very short exposure (photography), exposure to the image formed by a camera lens is used to produce only a very slight chemical change, proportional to the amount of light absorbed by each crystal. This creates an invisible latent image in the emulsion, which can be chemically photographic processing, developed into a visible photograph. In addition to visible light, all films are sensitive to ultraviolet light, X-rays, gamma rays, and particle radiation, high-energy particles. Unmodified silver halide crys ...
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Photographic Paper
Photographic paper is a paper coated with a light-sensitive chemical formula, like photographic film, used for making photographic prints. When photographic paper is exposed to light, it captures a latent image that is then developed to form a visible image; with most papers the image density from exposure can be sufficient to not require further development, aside from fixing and clearing, though latent exposure is also usually present. The light-sensitive layer of the paper is called the emulsion. The most common chemistry was based on silver halide (the focus of this page) but other alternatives have also been used. The print image is traditionally produced by interposing a photographic negative between the light source and the paper, either by direct contact with a large negative (forming a contact print) or by projecting the shadow of the negative onto the paper (producing an enlargement). The initial light exposure is carefully controlled to produce a gray scale image on th ...
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Photography
Photography is the art, application, and practice of creating durable images by recording light, either electronically by means of an image sensor, or chemically by means of a light-sensitive material such as photographic film. It is employed in many fields of science, manufacturing (e.g., photolithography), and business, as well as its more direct uses for art, film and video production, recreational purposes, hobby, and mass communication. Typically, a lens is used to focus the light reflected or emitted from objects into a real image on the light-sensitive surface inside a camera during a timed exposure. With an electronic image sensor, this produces an electrical charge at each pixel, which is electronically processed and stored in a digital image file for subsequent display or processing. The result with photographic emulsion is an invisible latent image, which is later chemically "developed" into a visible image, either negative or positive, depending on the purp ...
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Color Photography
Color photography is photography that uses media capable of capturing and reproducing colors. By contrast, black-and-white or gray-monochrome photography records only a single channel of luminance (brightness) and uses media capable only of showing shades of gray. In color photography, electronic sensors or light-sensitive chemicals record color information at the time of exposure. This is usually done by analyzing the spectrum of colors into three channels of information, one dominated by red, another by green and the third by blue, in imitation of the way the normal human eye senses color. The recorded information is then used to reproduce the original colors by mixing various proportions of red, green and blue light ( RGB color, used by video displays, digital projectors and some historical photographic processes), or by using dyes or pigments to remove various proportions of the red, green and blue which are present in white light ( CMY color, used for prints on paper a ...
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Redox
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate (chemistry), substrate change. Oxidation is the loss of Electron, electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogen ...
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Silver Halide
A silver halide (or silver salt) is one of the chemical compounds that can form between the element silver (Ag) and one of the halogens. In particular, bromine (Br), chlorine (Cl), iodine (I) and fluorine (F) may each combine with silver to produce silver bromide (AgBr), silver chloride (AgCl), silver iodide (AgI), and three forms of silver fluoride, respectively. As a group, they are often referred to as the silver halides, and are often given the pseudo-chemical notation AgX. Although most silver halides involve silver atoms with oxidation states of +1 (Ag+), silver halides in which the silver atoms have oxidation states of +2 (Ag2+) are known, of which silver(II) fluoride is the only known stable one. Silver halides are light-sensitive chemicals, and are commonly used in photographic film and paper. Applications Light sensitivity Silver halides are used in photographic film and photographic paper, including graphic art film and paper, where silver halide crystals in g ...
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Bleach
Bleach is the generic name for any chemical product that is used industrially or domestically to remove color (whitening) from a fabric or fiber or to clean or to remove stains in a process called bleaching. It often refers specifically, to a dilute solution of sodium hypochlorite, also called "liquid bleach". Many bleaches have broad spectrum bactericidal properties, making them useful for disinfecting and sterilizing. They are used in swimming pool sanitation to control bacteria, viruses, and algae, and in many places where sterile conditions are required. They are also used in many industrial processes, notably in the bleaching of wood pulp. Bleaches also have other minor uses like removing mildew, killing weeds, and increasing the longevity of cut flowers. Bleaches work by reacting with many colored organic compounds, such as natural pigments, and turning them into colorless ones. While most bleaches are oxidizing agents (chemicals that can remove electrons from other ...
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Photographic Fixer
Photographic fixer is a mix of chemicals used in the final step in the photographic processing of film or paper. The fixer stabilises the image, removing the unexposed silver halide remaining on the photographic film or photographic paper, leaving behind the reduced metallic silver that forms the image. By fixation, the film or paper is insensitive to further action by light. Without fixing, the remaining silver halide would darken and cause fogging of the image. Fixation is commonly achieved by treating the film or paper with a solution of thiosulfate salt. Popular salts are sodium thiosulfate—commonly called hypo—and ammonium thiosulfate—commonly used in modern rapid fixer formulae. Fixation involves these chemical reactions (X = halide, typically Br−):Karlheinz Keller et al. "Photography" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. :AgX + 2 S2O32− → g(S2O3)2sup>3− + X− :AgX + 3 S2O32− → g(S2O3)3sup>5∠...
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Archive
An archive is an accumulation of historical records or materials – in any medium – or the physical facility in which they are located. Archives contain primary source documents that have accumulated over the course of an individual or organization's lifetime, and are kept to show the function of that person or organization. Professional archivists and historians generally understand archives to be records that have been naturally and necessarily generated as a product of regular legal, commercial, administrative, or social activities. They have been metaphorically defined as "the secretions of an organism", and are distinguished from documents that have been consciously written or created to communicate a particular message to posterity. In general, archives consist of records that have been selected for permanent or long-term preservation on grounds of their enduring cultural, historical, or evidentiary value. Archival records are normally unpublished and almost alway ...
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Fujifilm
, trading as Fujifilm, or simply Fuji, is a Japanese multinational conglomerate headquartered in Tokyo, Japan, operating in the realms of photography, optics, office and medical electronics, biotechnology, and chemicals. The offerings from the company that started as a manufacturer of photographic films, which it still produces, include: document solutions, medical imaging and diagnostics equipment, cosmetics, pharmaceutical drugs, regenerative medicine, stem cells, biologics manufacturing, magnetic tape data storage, optical films for flat-panel displays, optical devices, photocopiers and printers, digital cameras, color films, color paper, photofinishing and graphic arts equipment and materials. Fujifilm is part of the Sumitomo Mitsui Financial Group financial conglomerate (''keiretsu''). History 20th century Fuji Photo Film Co., Ltd. was established in 1934 as a subsidiary of Daicel with the aim of producing photographic films. Over the following 10 years, the comp ...
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Provia
Provia is a brandname for a pair of daylight-balanced color reversal films (slide film) produced by the Japanese film company Fujifilm. It is currently available in one speed, 100/21°, marketed as Fujichrome Provia 100F Professional DP III'',. An additional speed of 400/27°, marketed as Fujichrome Provia 400X Professional XP'', was previously available. Details Provia 100F DP IIIwas developed to replace Provia 100 DP IIand Provia 400X XPwas developed to replace Provia 400F HP III improving on colour image storage permanence and colour fading resistance. Provia has less saturated colors and contrast compared to Velvia. Provia 100F DP IIIis available in 135 and 120 formats, as well as rolls and various sheet sizes. Provia 400X was only available in 135 and 120 formats prior to discontinuation. Both films have the ability to be pushed/pulled from −1/2 stop to +2 stops. Provia is also a favored film for cross processing. Neither film requires reciprocity compensation ...
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