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Calculated Carbon Aromaticity Index
The calculated carbon aromaticity index (CCAI) is an index of the ignition quality of residual fuel oil. The running of all internal combustion engines is dependent on the ignition quality of the fuel. For spark-ignition engines the fuel has an octane rating. For diesel engines it depends on the type of fuel, for distillate fuels the cetane numbers are used. Cetane numbers are tested using a special test engine and the existing engine was not made for residual fuels. For residual fuel oil two other empirical indexes are used: CCAI and Calculated Ignition Index (CII). Both CCAI and CII are calculated from the density and kinematic viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the int ... of the fuel. Definition Formula for CCAI: CCAI=D-140.7 \log (\log (V+0.85))-80.6-210 \ln \ ...
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Internal Combustion Engines
An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal combustion engine, the expansion of the high-temperature and high-pressure gases produced by combustion applies direct force to some component of the engine. The force is typically applied to pistons ( piston engine), turbine blades (gas turbine), a rotor (Wankel engine), or a nozzle ( jet engine). This force moves the component over a distance, transforming chemical energy into kinetic energy which is used to propel, move or power whatever the engine is attached to. This replaced the external combustion engine for applications where the weight or size of an engine was more important. The first commercially successful internal combustion engine was created by Étienne Lenoir around 1860, and the first modern internal combustion engine, know ...
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Spark-ignition
A spark-ignition engine (SI engine) is an internal combustion engine, generally a petrol engine, where the combustion process of the air-fuel mixture is ignited by a spark from a spark plug. This is in contrast to compression-ignition engines, typically diesel engines, where the heat generated from compression together with the injection of fuel is enough to initiate the combustion process, without needing any external spark. Fuels Spark-ignition engines are commonly referred to as "gasoline engines" in North America, and "petrol engines" in Britain and the rest of the world. Spark-ignition engines can (and increasingly are) run on fuels other than petrol/gasoline, such as autogas ( LPG), methanol, ethanol, bioethanol, compressed natural gas (CNG), hydrogen, and (in drag racing) nitromethane. Working cycle The working cycle of both spark-ignition and compression-ignition engines may be either two-stroke or four-stroke. A four-stroke spark-ignition engine is an Otto cycle en ...
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Octane Rating
An octane rating, or octane number, is a standard measure of a fuel's ability to withstand compression in an internal combustion engine without detonating. The higher the octane number, the more compression the fuel can withstand before detonating. Octane rating does not relate directly to the power output or the energy content of the fuel per unit mass or volume, but simply indicates gasoline's capability against compression. Whether or not a higher octane fuel improves or impairs an engine's performance depends on the design of the engine. In broad terms, fuels with a higher octane rating are used in higher-compression gasoline engines, which may yield higher power for these engines. Such higher power comes from the fuel's higher compression by the engine design, and not directly from the gasoline. In contrast, fuels with lower octane (but higher cetane numbers) are ideal for diesel engines because diesel engines (also called compression-ignition engines) do not compress the fue ...
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Diesel Engine
The diesel engine, named after Rudolf Diesel, is an internal combustion engine in which ignition of the fuel is caused by the elevated temperature of the air in the cylinder due to mechanical compression; thus, the diesel engine is a so-called compression-ignition engine (CI engine). This contrasts with engines using spark plug-ignition of the air-fuel mixture, such as a petrol engine (gasoline engine) or a gas engine (using a gaseous fuel like natural gas or liquefied petroleum gas). Diesel engines work by compressing only air, or air plus residual combustion gases from the exhaust (known as exhaust gas recirculation (EGR)). Air is inducted into the chamber during the intake stroke, and compressed during the compression stroke. This increases the air temperature inside the cylinder to such a high degree that atomised diesel fuel injected into the combustion chamber ignites. With the fuel being injected into the air just before combustion, the dispersion of the fuel is une ...
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Cetane Number
Cetane number (cetane rating) is an indicator of the combustion speed of diesel fuel and compression needed for ignition. It plays a similar role for diesel as octane rating does for gasoline. The CN is an important factor in determining the quality of diesel fuel, but not the only one; other measurements of diesel fuel's quality include (but are not limited to) energy content, density, lubricity, cold-flow properties and sulphur content.Werner Dabelstein, Arno Reglitzky, Andrea Schütze and Klaus Reders "Automotive Fuels" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2007, Wiley-VCH, Weinheim. Definition The cetane number (or CN) of a fuel is defined by finding a blend of cetane and isocetane with the same ignition delay. Cetane has a cetane number defined to be 100, while isocetane's measured cetane number is 15, replacing the former reference fuel alpha-methylnaphthalene, which was assigned a cetane number of 0. Once the blend is known, the cetane number is calculate ...
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Calculated Ignition Index
The Calculated Ignition Index (CII) is an index of the ignition quality of residual fuel oil. The running of all internal combustion engines is dependent on the ignition quality of the fuel. For spark-ignition engines the fuel has an octane rating. For diesel engines it depends on the type of fuel, for distillate fuels the cetane numbers are used. Cetane numbers are tested using a special test engine and the existing engine was not made for residual fuels. For residual fuel oil two other empirical indexes are used CII and Calculated Carbon Aromaticity Index (CCAI). Both CII and CCAI are calculated from the density and kinematic viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the int ... of the fuel. Definition Formula for CII: CII = (270.795 + 0.1038T)-0.254565D+23.708 \log \log ...
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Density
Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematically, density is defined as mass divided by volume: : \rho = \frac where ''ρ'' is the density, ''m'' is the mass, and ''V'' is the volume. In some cases (for instance, in the United States oil and gas industry), density is loosely defined as its weight per unit volume, although this is scientifically inaccurate – this quantity is more specifically called specific weight. For a pure substance the density has the same numerical value as its mass concentration. Different materials usually have different densities, and density may be relevant to buoyancy, purity and packaging. Osmium and iridium are the densest known elements at standard conditions for temperature and pressure. To simplify comparisons of density across different s ...
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Viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the internal frictional force between adjacent layers of fluid that are in relative motion. For instance, when a viscous fluid is forced through a tube, it flows more quickly near the tube's axis than near its walls. Experiments show that some stress (such as a pressure difference between the two ends of the tube) is needed to sustain the flow. This is because a force is required to overcome the friction between the layers of the fluid which are in relative motion. For a tube with a constant rate of flow, the strength of the compensating force is proportional to the fluid's viscosity. In general, viscosity depends on a fluid's state, such as its temperature, pressure, and rate of deformation. However, the dependence on some of these properties is ...
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