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Calcium Sulfate
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsum. It has many uses in industry. All forms are white solids that are poorly soluble in water.Franz Wirsching "Calcium Sulfate" in Ullmann's Encyclopedia of Industrial Chemistry, 2012 Wiley-VCH, Weinheim. Calcium sulfate causes permanent hardness in water. Hydration states and crystallographic structures The compound exists in three levels of hydration corresponding to different crystallographic structures and to minerals: * (anhydrite): anhydrous state. The structure is related to that of zirconium orthosilicate (zircon): is 8-coordinate, is tetrahedral, O is 3-coordinate. * (gypsum and selenite (mineral)): dihydrate. * (bassanite): hemihydrate, also known as plaster of Paris. S ...
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Plaster Of Paris
Plaster is a building material used for the protective or decorative coating of walls and ceilings and for moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of buildings, while "render" commonly refers to external applications. Another imprecise term used for the material is stucco, which is also often used for plasterwork that is worked in some way to produce relief decoration, rather than flat surfaces. The most common types of plaster mainly contain either gypsum, lime, or cement,Franz Wirsching "Calcium Sulfate" in Ullmann's Encyclopedia of Industrial Chemistry, 2012 Wiley-VCH, Weinheim. but all work in a similar way. The plaster is manufactured as a dry powder and is mixed with water to form a stiff but workable paste immediately before it is applied to the surface. The reaction with water liberates heat through crystallization and the hydrated plaster then hardens. Plaster can be relatively easily worked wit ...
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Selenite (mineral)
Selenite, satin spar, desert rose, gypsum flower are crystal habit varieties of the mineral gypsum. All varieties of gypsum, including selenite and alabaster, are composed of calcium sulfate dihydrate (meaning that it has two molecules of water), with the chemical formula CaSO4·2H2O. Selenite contains no significant selenium – The similar names both derive from Greek ( 'Moon') Some of the largest crystals ever found are of selenite, the largest specimen found in the Naica Mine's Cave of the Crystals being 12 metres long and weighing 55 tons. History and etymology "Selenite" is mostly synonymous with gypsum, but from the 15th century, it has named the transparent variety that occurs in crystals or crystalline masses. The name derives through Middle English from Latin , ultimately from Greek (, ). It got this name because people historically believed the mineral waxed and waned with the cycles of the Moon.
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Aluminothermic Reaction
Aluminothermic reactions are exothermic chemical reactions using aluminum as the reducing agent at high temperature. The process is industrially useful for production of alloys of iron. The most prominent example is the thermite reaction between iron oxides and aluminum to produce iron itself: : Fe2O3 + 2 Al → 2 Fe + Al2O3 This specific reaction is however not relevant to the most important application of aluminothermic reactions, the production of ferroalloys. For the production of iron, a cheaper reducing agent, coke, is used instead via the carbothermic reaction. History Aluminothermy started from the experiments of Russian scientist Nikolay Beketov at the University of Kharkiv in Ukraine, who proved that aluminum restored metals from their oxides under high temperatures. The reaction was first used for the carbon-free reduction of metal oxides. The reaction is highly exothermic, but it has a high activation energy since strong interatomic bonds in the solids m ...
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Oxidizing Agent
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or "Electron acceptor, accepts"/"receives" an electron from a (called the , , or ). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an Redox, oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen ...
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Steel
Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant typically need an additional 11% chromium. Because of its high tensile strength and low cost, steel is used in buildings, infrastructure, tools, ships, trains, cars, machines, electrical appliances, weapons, and rockets. Iron is the base metal of steel. Depending on the temperature, it can take two crystalline forms (allotropic forms): body-centred cubic and face-centred cubic. The interaction of the allotropes of iron with the alloying elements, primarily carbon, gives steel and cast iron their range of unique properties. In pure iron, the crystal structure has relatively little resistance to the iron atoms slipping past one another, and so pure iron is quite ductile, or soft and easily formed. In steel, small amounts of carbon, other ...
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Wood
Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin that resists compression. Wood is sometimes defined as only the secondary xylem in the stems of trees, or it is defined more broadly to include the same type of tissue elsewhere such as in the roots of trees or shrubs. In a living tree it performs a support function, enabling woody plants to grow large or to stand up by themselves. It also conveys water and nutrients between the leaves, other growing tissues, and the roots. Wood may also refer to other plant materials with comparable properties, and to material engineered from wood, or woodchips or fiber. Wood has been used for thousands of years for fuel, as a construction material, for making tools and weapons, furniture and paper. More recently it emerged as a feedstock for the productio ...
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Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While the activation energy must be overcome to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. Combustion is often a complicated sequence of elementary radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that incandescent light in the form of either glowing or a flame is produced. A ...
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Framing (construction)
Framing, in construction, is the fitting together of pieces to give a structure support and shape. Framing materials are usually wood, engineered wood, or structural steel. The alternative to framed construction is generally called ''mass wall'' construction, where horizontal layers of stacked materials such as log building, masonry, rammed earth, adobe, etc. are used without framing. Building framing is divided into two broad categories, heavy-frame construction (heavy framing) if the vertical supports are few and heavy such as in timber framing, pole building framing, or steel framing; or light-frame construction (light-framing) if the supports are more numerous and smaller, such as balloon, platform, or light-steel framing. Light-frame construction using standardized dimensional lumber has become the dominant construction method in North America and Australia due to the economy of the method; use of minimal structural material allows builders to enclose a large area at mini ...
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Drywall
Drywall (also called plasterboard, dry lining, wallboard, sheet rock, gypsum board, buster board, custard board, and gypsum panel) is a panel made of calcium sulfate dihydrate (gypsum), with or without additives, typically extruded between thick sheets of facer and backer paper, used in the construction of interior walls and ceilings. The plaster is mixed with fiber (typically paper, glass wool, or a combination of these materials); plasticizer, foaming agent; and additives that can reduce mildew, flammability, and water absorption. In the middle of the 20th century, drywall construction became prevalent in North America as a time- and labor-saving alternative to lath and plaster. History The first plasterboard plant in the UK was opened in 1888 in Rochester, Kent. Sackett Board was invented in 1894 by Augustine Sackett and Fred Kane, graduates of Rensselaer Polytechnic Institute. It was made by layering plaster within four plies of wool felt paper. Sheets were thick with o ...
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Endothermic
In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. p. 617. In such a process, a closed system usually absorbs thermal energy from its surroundings, which is heat transfer into the system. Thus, an endothermic reaction generally leads to an increase in the temperature of the system and a decrease in that of the surroundings. It may be a chemical process, such as dissolving ammonium nitrate () in water (), or a physical process, such as the melting of ice cubes. The term was coined by 19th-century French chemist Marcellin Berthelot. The opposite of an endothermic process is an exothermic process, one that releases or "gives out" energy, usually in the form of heat and sometimes as electrical energy. Thus in each term (endothermic and exothermic) the prefix refers to where heat (or electrical ...
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Solubility
In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubility of a substance in a specific solvent is generally measured as the concentration of the solute in a saturated solution, one in which no more solute can be dissolved. At this point, the two substances are said to be at the solubility equilibrium. For some solutes and solvents, there may be no such limit, in which case the two substances are said to be " miscible in all proportions" (or just "miscible"). The solute can be a solid, a liquid, or a gas, while the solvent is usually solid or liquid. Both may be pure substances, or may themselves be solutions. Gases are always miscible in all proportions, except in very extreme situations,J. de Swaan Arons and G. A. M. Diepen (1966): "Gas—Gas Equilibria". ''Journal of Chemical Physics'', ...
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Mineral Hydration
In chemistry, mineral hydration is an inorganic chemical reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, usually called a ''hydrate''. In geological terms, the process of mineral hydration is known as ''retrograde alteration'' and is a process occurring in retrograde metamorphism. It commonly accompanies metasomatism and is often a feature of wall rock alteration around ore bodies. Hydration of minerals occurs generally in concert with hydrothermal circulation which may be driven by tectonic or igneous activity. Processes There are two main ways in which minerals hydrate. One is conversion of an oxide to a double hydroxide, as with the hydration of calcium oxide—CaO—to calcium hydroxide—Ca(OH)2, the other is with the incorporation of water molecules directly into the crystalline structure of a new mineral. The later process is exhibited in the hydration of feldspars to clay minerals, garnet to chlorite, or kyanite to m ...
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