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Breath-figure Self-assembly
] Breath-figure self-assembly is the self-assembly process of formation of honeycomb micro-scaled polymer patterns by the condensation of water droplets. "Breath-figure" refers to the fog that forms when water vapor contacts a cold surface. In the modern era systematic study of the process of breath-figures water condensation was carried out by Aitken and Rayleigh, among others. Half a century later the interest to the breath-figure formation was revived in a view of study of atmospheric processes, and in particular the extended study of a dew formation which turned out to be a complicated physical process. The experimental and theoretical study of dew formation has been carried out by Beysens. Thermodynamic and kinetic aspects of dew formation, which are crucial for understanding of formation of breath-figures inspired polymer patterns will be addressed further in detail. Breakthrough in the application of the breath-figures patterns was achieved in 1994–1995 when Widawski, Fr ...
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Nucleation
In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled (at atmospheric pressure) below 0°C, it will tend to freeze into ice, but volumes of water cooled only a few degrees below 0°C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay. Nucleation is a common mechanism which generates first-order phase transitions, and it is the start of the process of forming a new thermodynamic phase. In contrast, new phases at continuous phase transitions start to form immedi ...
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Droplet Cluster
Droplet cluster is a self-assembled levitating monolayer of microdroplets usually arranged into a hexagonally ordered structure over a locally heated thin (about 1 mm) layer of water. The droplet cluster is typologically similar to colloidal crystals. The phenomenon was observed for the first time in 2004, and it has been extensively studied after that. Growing condensing droplets with a typical diameter of 0.01 mm – 0.2 mm levitate at an equilibrium height, where their weight is equilibrated by the drag force of the ascending air-vapor jet rising over the heated spot. At the same time, the droplets are dragged towards the center of the heated spot; however, they do not merge, forming an ordered hexagonal (densest packed) pattern due to an aerodynamic repulsive pressure force from gas flow between the droplets. The spot is usually heated by a laser beam or another source of heat to 60 °C – 95 °C, although the phenomenon was observed also at tem ...
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Marangoni Effect
The Marangoni effect (also called the Gibbs–Marangoni effect) is the mass transfer along an interface between two phases due to a gradient of the surface tension. In the case of temperature dependence, this phenomenon may be called thermo-capillary convection (or Bénard–Marangoni convection). History This phenomenon was first identified in the so-called "tears of wine" by physicist James Thomson (Lord Kelvin's brother) in 1855. The general effect is named after Italian physicist Carlo Marangoni, who studied it for his doctoral dissertation at the University of Pavia and published his results in 1865. A complete theoretical treatment of the subject was given by J. Willard Gibbs in his work ''On the Equilibrium of Heterogeneous Substances'' (1875-8). Mechanism Since a liquid with a high surface tension pulls more strongly on the surrounding liquid than one with a low surface tension, the presence of a gradient in surface tension will naturally cause the liquid to flow away fr ...
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Self-assembly
Self-assembly is a process in which a disordered system of pre-existing components forms an organized structure or pattern as a consequence of specific, local interactions among the components themselves, without external direction. When the constitutive components are molecules, the process is termed molecular self-assembly. Self-assembly can be classified as either static or dynamic. In ''static'' self-assembly, the ordered state forms as a system approaches equilibrium, reducing its free energy. However, in ''dynamic'' self-assembly, patterns of pre-existing components organized by specific local interactions are not commonly described as "self-assembled" by scientists in the associated disciplines. These structures are better described as "self-organized", although these terms are often used interchangeably. Self-assembly in chemistry and materials science Self-assembly in the classic sense can be defined as ''the spontaneous and reversible organization of molec ...
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Circa
Circa is a word of Latin origin meaning 'approximately'. Circa or CIRCA may also refer to: * CIRCA (art platform), art platform based in London * Circa (band), a progressive rock supergroup * Circa (company), an American skateboard footwear company * Circa (contemporary circus), an Australian contemporary circus company * Circa District, Abancay Province, Peru * Circa, a disc-binding notebook system * Circa Theatre, in Wellington, New Zealand * Clandestine Insurgent Rebel Clown Army, a UK activist group * Circa News, an online news and entertainment service * Circa Complex, twin skyscrapers in Los Angeles, California * ''Circa'' (album), an album by Michael Cain * Circa Resort & Casino Circa Resort & Casino is a casino and hotel resort in downtown Las Vegas, Nevada, on the Fremont Street Experience. The property was previously occupied by the Las Vegas Club hotel-casino, the Mermaids Casino, and the Glitter Gulch strip club. Ci ...
, a hotel in downtown Las Vegas ...
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Spin-coating
Spin coating is a procedure used to deposit uniform thin films onto flat substrates. Usually a small amount of coating material is applied on the center of the substrate, which is either spinning at low speed or not spinning at all. The substrate is then rotated at speed up to 10,000 rpm to spread the coating material by centrifugal force. A machine used for spin coating is called a spin coater, or simply spinner. Rotation is continued while the fluid spins off the edges of the substrate, until the desired thickness of the film is achieved. The applied solvent is usually volatile, and simultaneously evaporates. The higher the angular speed of spinning, the thinner the film. The thickness of the film also depends on the viscosity and concentration of the solution, and the solvent. Pioneering theoretical analysis of spin coating was undertaken by Emslie et al., and has been extended by many subsequent authors (including Wilson et al., who studied the rate of spreading in spin coati ...
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Dip-coating
image:Dip coating.svg, A schematic of the continuous dip coating process. Roll of coarse cloth Cloth Bath Liquid material Rollers Oven Scrapers Excess liquid falls back A coating remains on the fabric cloth. Dip coating is an industrial coating process which is used, for example, to manufacture bulk products such as coated fabrics and condoms and specialised coatings for example in the biomedical field. Dip coating is also commonly used in academic research, where many chemical and nano material engineering research projects use the dip coating technique to create thin-film coatings. The earliest dip-coated products may have been candles. For flexible laminar substrates such as fabrics, dip coating may be performed as a continuous roll-to-roll process. For coating a 3D object, it may simply be inserted and removed from the bath of coating. For condom-making, a former is dipped into the coating. For some products, such as early methods of making candles, the process is re ...
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Condensation
Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to liquid water when in contact with a liquid or solid surface or cloud condensation nuclei within the atmosphere. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition. Initiation Condensation is initiated by the formation of atomic/molecular clusters of that species within its gaseous volume—like rain drop or snow flake formation within clouds—or at the contact between such gaseous phase and a liquid or solid surface. In clouds, this can be catalyzed by water-nucleating proteins, produced by atmospheric microbes, which are capable of binding gaseous or liquid water molecules. Reversibility scenarios A few distinct reversibility scenarios emerge here with respect to the n ...
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Evaporation
Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidity affects rate of evaporation of water. When the molecules of the liquid collide, they transfer energy to each other based on how they collide. When a molecule near the surface absorbs enough energy to overcome the vapor pressure, it will escape and enter the surrounding air as a gas. When evaporation occurs, the energy removed from the vaporized liquid will reduce the temperature of the liquid, resulting in evaporative cooling. On average, only a fraction of the molecules in a liquid have enough heat energy to escape from the liquid. The evaporation will continue until an equilibrium is reached when the evaporation of the liquid is equal to its condensation. In an enclosed environment, a liquid will evaporate until the surrounding air is ...
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Varied Breath Figure Patterns
Variation or Variations may refer to: Science and mathematics * Variation (astronomy), any perturbation of the mean motion or orbit of a planet or satellite, particularly of the moon * Genetic variation, the difference in DNA among individuals or the differences between populations ** Human genetic variation, genetic differences in and among populations of humans * Magnetic variation, difference between magnetic north and true north, measured as an angle * ''p''-variation in mathematical analysis, a family of seminorms of functions * Coefficient of variation in probability theory and statistics, a standardized measure of dispersion of a probability distribution or frequency distribution * Total variation in mathematical analysis, a way of quantifying the change in a function over a subset of \mathbb^n or a measure space * Calculus of variations in mathematical analysis, a method of finding maxima and minima of functionals Arts * Variation (ballet) or pas seul, solo dance ...
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Condensation
Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to liquid water when in contact with a liquid or solid surface or cloud condensation nuclei within the atmosphere. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition. Initiation Condensation is initiated by the formation of atomic/molecular clusters of that species within its gaseous volume—like rain drop or snow flake formation within clouds—or at the contact between such gaseous phase and a liquid or solid surface. In clouds, this can be catalyzed by water-nucleating proteins, produced by atmospheric microbes, which are capable of binding gaseous or liquid water molecules. Reversibility scenarios A few distinct reversibility scenarios emerge here with respect to the n ...
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