Borate Selenide
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Borate Selenide
Selenide borates, officially known as borate selenides, are chemical mixed anion compounds Mixed anion compounds, heteroanionic materials or mixed anion materials are chemical compounds containing cations and more than one kind of anion. The compounds contain a single phase, rather than just a mixture. Use in materials science By havin ... that contain any kind of borate and selenide ions. They are distinct from selenoborates in which selenium atoms replace oxygen in borates. There are also analogous borate sulfides, with sulfur ions instead of selenium. List References {{Borates Borates Selenides Mixed anion compounds ...
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Mixed Anion Compounds
Mixed anion compounds, heteroanionic materials or mixed anion materials are chemical compounds containing cations and more than one kind of anion. The compounds contain a single phase, rather than just a mixture. Use in materials science By having more than one anion, many more compounds can be made, and properties tuned to desirable values. In terms of optics, properties include laser damage threshold, refractive index, birefringence, absorption particularly in the ultraviolet or near infrared, non-linearity. Mechanical properties can include ability to grow a large crystal, ability to form a thin layer, strength, or brittleness. Thermal properties can include melting point, thermal stability, phase transition temperatures, Thermal expansion coefficient. For electrical properties, electric conductivity, band gap, superconducting transition temperature piezoelectricity, pyroelectricity, ferromagnetism, dielectric constant, charge-density wave transition can be adjus ...
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Borate
A borate is any of several boron oxyanions, negative ions consisting of boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt with such anions, such as sodium metaborate, and disodium tetraborate . The name also refers to certain functional groups in molecules consisting of boron and oxygen, and esters with such groups, such as triethyl orthoborate . Natural occurrence Borate ions occur, alone or with other anions, in many borate and borosilicate minerals such as borax, boracite, ulexite (boronatrocalcite) and colemanite. Borates also occur in seawater, where they make an important contribution to the absorption of low frequency sound in seawater. Borates also occur in plants, including almost all fruits. Anions The main borate anions are: * tetrahydroxyborate , found in sodium tetrahydroxyborate . * orthoborate , found in trisodium orthoborate * perborate , as in sodium perborate * metaborate or , found in sodium metaborate * diborate , f ...
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Selenide
A selenide is a chemical compound containing a selenium anion with oxidation number of −2 (Se2−), much as sulfur does in a sulfide. The chemistry of the selenides and sulfides is similar. Similar to sulfide, in aqueous solution, the selenide ion, Se2−, is prevalent only in very basic conditions. In neutral conditions, hydrogen selenide ion, HSe−, is most common. In acid conditions, hydrogen selenide, H2Se, is formed. Some selenides are reactive to oxidation by air. Owing to the greater reducing power of selenide, metal selenides are more easily decomposed to the elements than are sulfides (tellurides are even more labile). Selenides of electropositive metals: such as aluminium selenide readily hydrolyse, even in moist air, evolving toxic hydrogen selenide gas. Pure selenide minerals are rare, instead selenium tends to partially substitute for sulfide in many sulfide minerals. The degree of substitution is only of commercial interest for copper sulfide ores, in which case ...
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Borate Sulfide
Borate sulfides are chemical mixed anion compounds that contain any kind of borate and sulfide ions. They are distinct from thioborates in which sulfur atoms replace oxygen in borates. There are also analogous borate selenide Selenide borates, officially known as borate selenides, are chemical mixed anion compounds Mixed anion compounds, heteroanionic materials or mixed anion materials are chemical compounds containing cations and more than one kind of anion. The compo ...s, with selenium ions instead of sulfur. List References {{Reflist Borates Sulfides Mixed anion compounds ...
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Borates
A borate is any of several boron oxyanions, negative ions consisting of boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt with such anions, such as sodium metaborate, and disodium tetraborate . The name also refers to certain functional groups in molecules consisting of boron and oxygen, and esters with such groups, such as triethyl orthoborate . Natural occurrence Borate ions occur, alone or with other anions, in many borate and borosilicate minerals such as borax, boracite, ulexite (boronatrocalcite) and colemanite. Borates also occur in seawater, where they make an important contribution to the absorption of low frequency sound in seawater. Borates also occur in plants, including almost all fruits. Anions The main borate anions are: * tetrahydroxyborate , found in sodium tetrahydroxyborate . * orthoborate , found in trisodium orthoborate * perborate , as in sodium perborate * metaborate or , found in sodium metaborate * diborate , f ...
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Selenides
A selenide is a chemical compound containing a selenium anion with oxidation number of −2 (Se2−), much as sulfur does in a sulfide. The chemistry of the selenides and sulfides is similar. Similar to sulfide, in aqueous solution, the selenide ion, Se2−, is prevalent only in very basic conditions. In neutral conditions, hydrogen selenide ion, HSe−, is most common. In acid conditions, hydrogen selenide, H2Se, is formed. Some selenides are reactive to oxidation by air. Owing to the greater reducing power of selenide, metal selenides are more easily decomposed to the elements than are sulfides (tellurides are even more labile). Selenides of electropositive metals: such as aluminium selenide readily hydrolyse, even in moist air, evolving toxic hydrogen selenide gas. Pure selenide minerals are rare, instead selenium tends to partially substitute for sulfide in many sulfide minerals. The degree of substitution is only of commercial interest for copper sulfide ores, in which case ...
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