A selenide is a chemical compound containing a

selenium Selenium is a chemical element with the symbol Se and atomic number 34. It is a nonmetal (more rarely considered a metalloid) with properties that are intermediate between the elements above and below in the periodic table, sulfur and tellurium, ...

anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...

with

oxidation number In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to different atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. Co ...

of −2 (Se²⁻), much as

sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...

does in a

sulfide Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...

. The chemistry of the selenides and sulfides is similar. Similar to

, in

aqueous solution An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be re ...

, the selenide ion, Se²⁻, is prevalent only in very basic conditions. In neutral conditions, hydrogen selenide

ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...

, HSe⁻, is most common. In acid conditions,

hydrogen selenide Hydrogen selenide is an inorganic compound with the formula H2Se. This hydrogen chalcogenide is the simplest and most commonly encountered hydride of selenium. H2Se is a colorless, flammable gas under standard conditions. It is the most toxic sel ...

, H₂Se, is formed. Some selenides are reactive to oxidation by air. Owing to the greater reducing power of selenide, metal selenides are more easily decomposed to the elements than are

s (

tellurides The telluride ion is the anion Te2− and its derivatives. It is analogous to the other chalcogenide anions, the lighter O2−, S2−, and Se2−, and the heavier Po2−. In principle, Te2− is formed by the two-e− reduction of telluri ...

are even more labile). Selenides of electropositive metals: such as aluminium selenide readily hydrolyse, even in moist air, evolving toxic hydrogen selenide gas. Pure

selenide mineral Selenide minerals are those minerals that have the selenide anion as a main component. Selenides are similar to sulfides and often grouped with them. Examples include: * achavalite * athabascaite * clausthalite * ferroselite * penroseite * ...

s are rare, instead selenium tends to partially substitute for sulfide in many

sulfide mineral The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...

s. The degree of substitution is only of commercial interest for copper sulfide ores, in which case selenium is recovered as a by-product of copper refining. Some selenide minerals include

ferroselite Orthorhombic ferroselite and its isometric polymorph dzharkenite are iron selenides of general formula FeSe2 precipitated under reducing conditions in anoxic environments. They are a source of selenium in the Rocky Mountains where selenium occ ...

and

umangite Umangite is a copper selenide mineral, Cu3 Se2, discovered in 1891. It occurs only in small grains or fine granular aggregates with other copper minerals of the sulfide group. It has a hardness of 3. It is blue-black to red-violet in color with a ...

.Bernd E. Langner "Selenium and Selenium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. .

Reactions

Alkali metal selenides react with elemental selenium to give salts of

polyselenide In chemistry, a polyselenide usually refers to anions of the formula (Sen)2-, where Se is the atomic symbol for the element selenium. Many main group and transition metals form complexes with polyselenide anions. Preparation Conceptually, polyse ...

Quantum dots

Metal selenide

quantum dot Quantum dots (QDs) are semiconductor particles a few nanometres in size, having light, optical and electronics, electronic properties that differ from those of larger particles as a result of quantum mechanics. They are a central topic in nanote ...

s and nanoparticles can be prepared by a variety of synthetic methods, many of which require high temperatures and hazardous precursor compounds. The particles can be adapted for a variety of applications by varying the ligands coordinated to the positively-charged outer layer. Many ligand-exchange reactions are available for use, trading X, L, and Z-type ligands, the mechanism for which is still under study.

Applications

Quantum dots based on metal selenides have been extensively for their distinctive spectral properties. Core-shell alloys of cadmium sulfide and selenide are of interest in imaging and

phototherapy Light therapy, also called phototherapy or bright light therapy is intentional daily exposure to direct sunlight or similar-intensity artificial light in order to treat medical disorders, especially seasonal affective disorder (SAD) and circadi ...

Examples

Gallium(II) selenide Gallium(II) selenide ( Ga Se) is a chemical compound. It has a hexagonal layer structure, similar to that of GaS. It is a photoconductor, a second harmonic generation crystal in nonlinear optics, and has been used as a far-infrared conversion mate ...

Indium(III) selenide Indium(III) selenide is a compound of indium and selenium. It has potential for use in photovoltaic devices and it has been the subject of extensive research. The two most common phases, α and β, have a layered structure, while γ is a "defect w ...

* Sodium selenide *

Cadmium selenide Cadmium selenide is an inorganic compound with the formula Cadmium, CdSelenide, Se. It is a black to red-black solid that is classified as a II-VI semiconductor of the n-type semiconductor, n-type. Much of the current research on this compound i ...

Zinc selenide Zinc selenide (ZnSe) is a light-yellow, solid compound comprising zinc (Zn) and selenium (Se). It is an intrinsic semiconductor with a band gap of about 2.70 eV at . ZnSe rarely occurs in nature, and is found in the mineral that was named af ...

Lead selenide Lead selenide (PbSe), or lead(II) selenide, a selenide of lead, is a semiconductor material. It forms cubic crystals of the NaCl structure; it has a direct bandgap of 0.27 eV at room temperature. (Note that incorrectly identifies PbSe and ...

Copper selenide Copper selenide is an inorganic binary compound consisting of copper and selenium. Its formula is sometimes described as CuSe or Cu2Se. The crystalline structure and electronic behavior is determined by its elemental composition. Stoichiometric c ...

References

External links