Ashoverite
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Ashoverite
Ashoverite is one of three polymorphs of zinc hydroxide, Zn(OH)2. It is a rare mineral first found in a limestone quarry near Ashover, Derbyshire, England, in 1988. It has also been found in the Harz mountain range in Germany, and in Namibia. The mineral was discovered after samples of the polymorph sweetite were sent to labs by S. A. Rust. Some specimens contained what appeared to be baryte Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ... but, which on further examination, were found to be a previously undescribed mineral. References Handbook of MineralogyAshoverite Mineral Data
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Zinc Hydroxide
Zinc hydroxide Zn( OH)2 is an inorganic chemical compound. It also occurs naturally as 3 rare minerals: wülfingite (orthorhombic), ashoverite and sweetite (both tetragonal). Like the hydroxides of other metals, such as lead, aluminium, beryllium, tin and chromium, Zinc hydroxide (and Zinc oxide), is amphoteric. Thus it will dissolve readily in a dilute solution of a strong acid, such as HCl, and also in a solution of an alkali such as sodium hydroxide. Preparation It can be prepared by adding sodium hydroxide solution, but not in excess, to a solution of any zinc salt. A white precipitate will be seen: :Zn2+ + 2 OH− → Zn(OH)2. Zn2+ is known to form hexa-aqua ions at high water concentrations and tetra-aqua ions at low concentrations of water Sze, Yu-Keung, and Donald E. Irish. "Vibrational spectral studies of ion-ion and ion-solvent interactions. I. Zinc nitrate in water." Journal of Solution Chemistry 7.6 (1978): 395-415. and, thus, this reaction may be better writt ...
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Sweetite
Sweetite has a general formula of Zn(OH)2. The name is given after a curator of mineral department of The British Museum, Jessie May Sweet (1901–1979). It occurs in an oxidized vein in limestone bedrock with galena, ashoverite, wülfingite, anglesite, cerussite, hydrocerussite, litharge, fluorite, palygorskite and calcite. Sweetite is tetragonal In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the cube becomes a rectangular prism with a square ..., which means crystallographically it contains one axis of unequal length and two axes of equal length. The angles between three of the axes are all 90°. It belongs to the space group 4/m. Some crystals show evidence of a basal plane and a few are tabular. In terms of its optical properties, sweetite has two indices of refraction, 1.635 along the ordinary ray and 1.628 along the extraordin ...
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Polymorphism (materials Science)
In materials science, polymorphism describes the existence of a solid material in more than one form or crystal structure. Polymorphism is a form of isomerism. Any crystalline material can exhibit the phenomenon. Allotropy refers to polymorphism for chemical elements. Polymorphism is of practical relevance to pharmaceuticals, agrochemicals, pigments, dyestuffs, foods, and explosives. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure." According to McCrone, polymorphs are "different in crystal structure but identical in the liquid or vapor states." Materials with two polymorphs are called dimorphic, with three polymorphs, trimorphic, etc. Examples Many compounds exhibit polymorphism. It has been claimed that "every compound has different polymorphic forms, and that, in general, the n ...
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Ashover
Ashover is a village and civil parish in the English county of Derbyshire. It is in the North East Derbyshire district of the county. The population of the civil parish taken at the 2011 Census was 1,905. It sits in a valley, not far from the town of Matlock and the Peak District national park. The centre of the village is a conservation area. The River Amber flows through the village. Although Ashover is a small settlement, the actual ward boundaries of the village extend for many miles, including the nearby settlements of Alicehead, Alton, Ashover Hay, Farhill, Kelstedge, Littlemoor, Milltown, Spitewinter, Stone Edge and Uppertown. The two major roads, running through the parish, are the A632 from Matlock to Chesterfield, and the A615 from Matlock to Alfreton. The area along that part of the A615 is named Doehole. Slack is a small hamlet, within the parish, which is south west of Kelstedge on the A632; nearby to there, on Robridding Road (off Wirestone Lane), is the Eddles ...
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Derbyshire
Derbyshire ( ) is a ceremonial county in the East Midlands, England. It includes much of the Peak District National Park, the southern end of the Pennine range of hills and part of the National Forest. It borders Greater Manchester to the north-west, West Yorkshire to the north, South Yorkshire to the north-east, Nottinghamshire to the east, Leicestershire to the south-east, Staffordshire to the west and south-west and Cheshire to the west. Kinder Scout, at , is the highest point and Trent Meadows, where the River Trent leaves Derbyshire, the lowest at . The north–south River Derwent is the longest river at . In 2003, the Ordnance Survey named Church Flatts Farm at Coton in the Elms, near Swadlincote, as Britain's furthest point from the sea. Derby is a unitary authority area, but remains part of the ceremonial county. The county was a lot larger than its present coverage, it once extended to the boundaries of the City of Sheffield district in South Yorkshire where it cov ...
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Harz
The Harz () is a highland area in northern Germany. It has the highest elevations for that region, and its rugged terrain extends across parts of Lower Saxony, Saxony-Anhalt, and Thuringia. The name ''Harz'' derives from the Middle High German word ''Hardt'' or ''Hart'' (hill forest). The name ''Hercynia'' derives from a Celtic name and could refer to other mountain forests, but has also been applied to the geology of the Harz. The Brocken is the highest summit in the Harz with an elevation of above sea level. The Wurmberg () is the highest peak located entirely within the state of Lower Saxony. Geography Location and extent The Harz has a length of , stretching from the town of Seesen in the northwest to Eisleben in the east, and a width of . It occupies an area of , and is divided into the Upper Harz (''Oberharz'') in the northwest, which is up to 800 m high, apart from the 1,100 m high Brocken massif, and the Lower Harz (''Unterharz'') in the east which is up to aroun ...
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Germany
Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated between the Baltic and North seas to the north, and the Alps to the south; it covers an area of , with a population of almost 84 million within its 16 constituent states. Germany borders Denmark to the north, Poland and the Czech Republic to the east, Austria and Switzerland to the south, and France, Luxembourg, Belgium, and the Netherlands to the west. The nation's capital and most populous city is Berlin and its financial centre is Frankfurt; the largest urban area is the Ruhr. Various Germanic tribes have inhabited the northern parts of modern Germany since classical antiquity. A region named Germania was documented before AD 100. In 962, the Kingdom of Germany formed the bulk of the Holy Roman Empire. During the 16th ce ...
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Namibia
Namibia (, ), officially the Republic of Namibia, is a country in Southern Africa. Its western border is the Atlantic Ocean. It shares land borders with Zambia and Angola to the north, Botswana to the east and South Africa to the south and east. Although Kazungula, it does not border Zimbabwe, less than 200 metres (660 feet) of the Botswanan right bank of the Zambezi, Zambezi River separates the two countries. Namibia gained independence from South Africa on 21 March 1990, following the Namibian War of Independence. Its capital and largest city is Windhoek. Namibia is a member state of the United Nations (UN), the Southern African Development Community (SADC), the African Union (AU) and the Commonwealth of Nations. The driest country in sub-Saharan Africa, Namibia has been inhabited since pre-historic times by the San people, San, Damara people, Damara and Nama people. Around the 14th century, immigration, immigrating Bantu peoples arrived as part of the Bantu expansion. Since ...
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Baryte
Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), anglesite (lead sulfate), and anhydrite (calcium sulfate). Baryte and celestine form a solid solution (Ba,Sr)SO4. Names and history The radiating form, sometimes referred to as ''Bologna Stone'', attained some notoriety among alchemists for specimens found in the 17th century near Bologna by Vincenzo Casciarolo. These became phosphorescent upon being calcined. Carl Scheele determined that baryte contained a new element in 1774, but could not isolate barium, only barium oxide. Johan Gottlieb Gahn also isolated barium oxide two years later in similar studies. Barium was first isolated by electrolysis of molten barium salts in 1808 by Sir Humphry Davy in England. The American Petroleum Institute specification API 13/ISO 13500, which gove ...
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Zinc Minerals
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic table. In some respects, zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size.The elements are from different metal groups. See periodic table. Zinc is the 24th most abundant element in Earth's crust and has five stable isotopes. The most common zinc ore is sphalerite (zinc blende), a zinc sulfide mineral. The largest workable lodes are in Australia, Asia, and the United States. Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity ( electrowinning). Zinc is an essential trace element for humans, animals, plants and for microorganisms and is necessary for prenatal and postnatal development. It is the seco ...
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Hydroxide Minerals
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides: *XO **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite ***Bromellite ***Tenorite ***Litharge * **Cuprite **Ice * **Hematite group ***Corundum ***Hematite ***Ilmenite * **Rutile group ***Rutile ***Pyrolusite ***Cassiterite **Baddeleyite **Uraninite **Thorianite * **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite ***Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite ** Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz Classification -04- Oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify ...
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Tetragonal Minerals
In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the cube becomes a rectangular prism with a square base (''a'' by ''a'') and height (''c'', which is different from ''a''). Bravais lattices There are two tetragonal Bravais lattices: the primitive tetragonal and the body-centered tetragonal. The base-centered tetragonal lattice is equivalent to the primitive tetragonal lattice with a smaller unit cell, while the face-centered tetragonal lattice is equivalent to the body-centered tetragonal lattice with a smaller unit cell. Crystal classes The point groups that fall under this crystal system are listed below, followed by their representations in international notation, Schoenflies notation, orbifold notation, Coxeter notation and mineral examples.Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Manual of Mineralogy'', 20th ed., p ...
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