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Aluminosilicates
Aluminosilicate minerals ( IMA symbol: Als) are minerals composed of aluminium, silicon, and oxygen, plus countercations. They are a major component of kaolin and other clay minerals. Andalusite, kyanite, and sillimanite are naturally occurring aluminosilicate minerals that have the composition Al2 Si O5. The triple point of the three polymorphs is located at a temperature of and a pressure of . These three minerals are commonly used as index minerals in metamorphic rocks. Naturally occurring microporous, hydrous aluminosilicate minerals are referred to as zeolites. Feldspar is a common tectosilicate aluminosilicate mineral made of potassium, sodium, and calcium cations surrounded by a negatively charged network of silicon, aluminium and oxygen atoms. The catalyst silica-alumina is an amorphous substance which is not an aluminosilicate compound. Aluminosilicate glasses There exist a wide variety of glass types. The characteristics of these different types depend on t ...
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Calcium Aluminosilicate
Calcium aluminosilicate, an aluminosilicate compound with calcium cations, most typically has formula CaAl2Si2O8. In minerals, as a feldspar, it can be found as anorthite, an end-member of the plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ... series. Uses As a food additive, it is sometimes designated E556. It is known to the FDA as, at under 2% by weight, an anti-caking agent for table salt, and as an ingredient in vanilla powder. References Aluminosilicates Calcium compounds E-number additives {{Inorganic-compound-stub ...
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Kaolin
Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina () octahedra. Rocks that are rich in kaolinite are known as kaolin () or china clay. Kaolin is occasionally referred to by the antiquated term lithomarge, from the Ancient Greek ''litho-'' and Latin ''marga'', meaning 'stone of marl'. Presently the name lithomarge can refer to a compacted, massive form of kaolin. The name ''kaolin'' is derived from Gaoling (), a Chinese village near Jingdezhen in southeastern China's Jiangxi Province. The name entered English in 1727 from the French version of the word: , following François Xavier d'Entrecolles's reports on the making of Jingdezhen porcelain. Kaolinite has a low shrink–swell capacity and a low cation-exchange capacity (1–15 meq/100 g). It is a soft, eart ...
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Zeolite
Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These positive ions can be exchanged for others in a contacting electrolyte solution. exchanged zeolites are particularly useful as solid acid catalysts. The term ''zeolite'' was originally coined in 1756 by Swedish mineralogist Axel Fredrik Cronstedt, who observed that rapidly heating a material, believed to have been stilbite, produced large amounts of steam from water that had been adsorbed by the material. Based on this, he called the material ''zeolite'', from the Greek , meaning "to boil" and , meaning "stone". Zeolites occur naturally but are also produced industrially on a large scale. , 253 unique zeolite frameworks have been identified, and over 40 naturally occurring zeolite frameworks are known. Every new zeolite structure tha ...
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Silicate Minerals
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous earth. General structure A silicate mineral is genera ...
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Geopolymer Cement
Geopolymer cement is a binding system that hardens at room temperature. It is a more environmentally friendly alternative to conventional Portland cement. It relies on minimally processed natural materials or industrial byproducts to significantly reduce the carbon footprint of cement production, while also being highly resistant to many common concrete durability issues. Geopolymer cements exist which may cure more rapidly than Portland-based cements. Production Production of geopolymer cement requires an aluminosilicate precursor material such as metakaolin or fly ash, a user-friendly alkaline reagent (for example, sodium or potassium soluble silicates with a molar ratio MR SiO2:M2O ≥ 1.65, M being Na or K) and water (See the definition for "user-friendly" reagent below). Room temperature hardening is more readily achieved with the addition of a source of calcium cations, often blast furnace slag. Geopolymer cements can be formulated to cure more rapidly than Portland-bas ...
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Aluminium Silicate
Aluminium silicate (or aluminum silicate) is a name commonly applied to chemical compounds which are derived from aluminium oxide, Al2O3 and silicon dioxide, SiO2 which may be anhydrous or hydrated, naturally occurring as minerals or synthetic. Their chemical formulae are often expressed as xAl2O3·ySiO2·zH2O. It is known as E number E559. Examples * Al2SiO5, (Al2O3·SiO2), which occurs naturally as the minerals andalusite, kyanite and sillimanite which have different crystal structures. * Al2Si2O5(OH)4, (Al2O3·2SiO2·2H2O), which occurs naturally as the mineral kaolinite and is also called aluminium silicate dihydrate.Handbook of Inorganic Compounds, Dale L. Perry, Taylor & Francis, 2011, It is a fine white powder and is used as a filler in paper and rubber and also used in paints. * Al2Si2O7, (Al2O3·2SiO2), called metakaolinite, formed from kaolin by heating at . * Al6Si2O13, (3Al2O3·2SiO2), the mineral mullite, the only thermodynamically stable intermediate phase in ...
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Chemically Strengthened Glass
Chemically strengthened glass is a type of glass that has increased strength as a result of a post-production chemical process. When broken, it still shatters in long pointed splinters similar to float glass. For this reason, it is not considered a safety glass and must be laminated if a safety glass is required. However, chemically strengthened glass is typically six to eight times the strength of float glass. The most common trademark for this kind of glass is Gorilla glass. The glass is chemically strengthened by a surface finishing process. Glass is submersed in a bath containing a potassium salt (typically potassium nitrate) at about . This causes sodium ions in the glass surface to be replaced by potassium ions from the bath solution. These potassium ions are larger than the sodium ions and therefore wedge into the gaps left by the smaller sodium ions when they migrate to the potassium nitrate solution. This replacement of ions causes the surface of the glass to be i ...
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Halogen Lamps
A halogen lamp (also called tungsten halogen, quartz-halogen, and quartz iodine lamp) is an incandescent lamp consisting of a tungsten filament sealed in a compact transparent envelope that is filled with a mixture of an inert gas and a small amount of a halogen, such as iodine or bromine. The combination of the halogen gas and the tungsten filament produces a halogen-cycle chemical reaction, which redeposits evaporated tungsten on the filament, increasing its life and maintaining the clarity of the envelope. This allows the filament to operate at a higher temperature than a standard incandescent lamp of similar power and operating life; this also produces light with higher luminous efficacy and color temperature. The small size of halogen lamps permits their use in compact optical systems for projectors and illumination. The small glass envelope may be enclosed in a much larger outer glass bulb, which has a lower temperature, protects the inner bulb from contamination, an ...
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Glass-to-metal Seal
Glass-to-metal seals are a very important element of the construction of vacuum tubes, electric discharge tubes, incandescent light bulbs, glass encapsulated semiconductor diodes, reed switches, pressure tight glass windows in metal cases, Vacuum Insulating Glass (Vacuum Glass) and metal or ceramic packages of electronic components. Properly done, such a seal is Hermetic seal, hermetic (vacuum tight, good electrical insulation, special optical properties e.g. UV lamps). To achieve such a seal, two properties must hold: # The molten glass must be capable of wetting the metal, in order to form a tight bond, and # The thermal expansion of the glass and metal must be closely matched so that the seal remains solid as the assembly cools. Thinking for example about a metal wire in a glass bulb sealing, the metal glass contact can break if coefficients of thermal expansion (CTE) are not well aligned. For the case that the CTE of the metal is larger than the CTE of the glass, the sealing s ...
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Molybdenum
Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals have been known throughout history, but the element was discovered (in the sense of differentiating it as a new entity from the mineral salts of other metals) in 1778 by Carl Wilhelm Scheele. The metal was first isolated in 1781 by Peter Jacob Hjelm. Molybdenum does not occur naturally as a free metal on Earth; it is found only in various oxidation states in minerals. The free element, a silvery metal with a grey cast, has the sixth-highest melting point of any element. It readily forms hard, stable carbides in alloys, and for this reason most of the world production of the element (about 80%) is used in steel alloys, including high-strength alloys and superalloys. Most molybdenum compounds have low solubility ...
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Electrode
An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or air). Electrodes are essential parts of batteries that can consist of a variety of materials depending on the type of battery. The electrophore, invented by Johan Wilcke, was an early version of an electrode used to study static electricity. Anode and cathode in electrochemical cells Electrodes are an essential part of any battery. The first electrochemical battery made was devised by Alessandro Volta and was aptly named the Voltaic cell. This battery consisted of a stack of copper and zinc electrodes separated by brine-soaked paper disks. Due to fluctuation in the voltage provided by the voltaic cell it wasn't very practical. The first practical battery was invented in 1839 and named the Daniell cell after John Frederic Daniell. Still making use of the zinc–copper electrode combination. Since then many more batteries ha ...
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Glass Transition
The glass–liquid transition, or glass transition, is the gradual and reversible transition in amorphous materials (or in amorphous regions within semicrystalline materials) from a hard and relatively brittle "glassy" state into a viscous or rubbery state as the temperature is increased. ISO 11357-2: Plastics – Differential scanning calorimetry – Part 2: Determination of glass transition temperature (1999). An amorphous solid that exhibits a glass transition is called a glass. The reverse transition, achieved by supercooling a viscous liquid into the glass state, is called vitrification. The glass-transition temperature ''T''g of a material characterizes the range of temperatures over which this glass transition occurs (as an experimental definition, typically marked as 100 s of relaxation time). It is always lower than the melting temperature, ''T''m, of the crystalline state of the material, if one exists. Hard plastics like polystyrene and poly(methyl methacrylate) ...
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