Ammonium Perchlorate
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Ammonium Perchlorate
Ammonium perchlorate ("AP") is an inorganic compound with the formula NH4 ClO4. It is a colorless or white solid that is soluble in water. It is a powerful oxidizer. Combined with a fuel, it can be used as a rocket propellant called ammonium perchlorate composite propellant. Its instability has involved it in a number of accidents, such as the PEPCON disaster. Production Ammonium perchlorate (AP) is produced by reaction between ammonia and perchloric acid. This process is the main outlet for the industrial production of perchloric acid. The salt also can be produced by salt metathesis reaction of ammonium salts with sodium perchlorate. This process exploits the relatively low solubility of NH4ClO4, which is about 10% of that for sodium perchlorate.Helmut Vogt, Jan Balej, John E. Bennett, Peter Wintzer, Saeed Akbar Sheikh, Patrizio Gallone "Chlorine Oxides and Chlorine Oxygen Acids" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH. AP crystallises as colorle ...
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Methanol
Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a light, volatile, colourless, flammable liquid with a distinctive alcoholic odour similar to that of ethanol (potable alcohol). A polar solvent, methanol acquired the name wood alcohol because it was once produced chiefly by the destructive distillation of wood. Today, methanol is mainly produced industrially by hydrogenation of carbon monoxide. Methanol consists of a methyl group linked to a polar hydroxyl group. With more than 20 million tons produced annually, it is used as a precursor to other commodity chemicals, including formaldehyde, acetic acid, methyl tert-butyl ether, methyl benzoate, anisole, peroxyacids, as well as a host of more specialised chemicals. Occurrence Small amounts of methanol are present in normal, healthy hu ...
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PEPCON Disaster
On May 4, 1988, a fire followed by several explosions occurred at the Pacific Engineering and Production Company of Nevada (PEPCON) chemical plant in Henderson, Nevada. The disaster caused two fatalities, 372 injuries, and an estimated $100 million of damage. A large portion of the Las Vegas Valley within a radius of the plant was affected, and several agencies activated disaster plans. Background The PEPCON plant, located in Henderson, Nevada, from Las Vegas, was one of only two American producers of ammonium perchlorate ("AP"), an oxidizer used in solid propellant rocket boosters, including the Space Shuttle, military weapons (SLBMs launched from nuclear submarines), and non-weaponized rocket programs (Atlas, Patriot, etc.). The other producer, Kerr-McGee, was located less than away from the PEPCON facility, within the area that suffered some blast damage. In addition to ammonium perchlorate, the plant produced other perchlorate chemicals including sodium perchlorate. The fa ...
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Amateur Rocketry
Amateur rocketry, sometimes known as experimental rocketry or amateur experimental rocketry, is a hobby in which participants experiment with fuels and make their own rocket motors, launching a wide variety of types and sizes of rockets. Amateur rocketeers have been responsible for significant research into hybrid rocket motors, and have built and flown a variety of solid, liquid, and hybrid propellant motors. History Amateur rocketry was an especially popular hobby in the late 1950s and early 1960s following the launch of Sputnik, as described in Homer Hickam's 1998 memoir ''Rocket Boys''. One of the first organizations set up in the US to engage in amateur rocketry was the Pacific Rocket Society established in California in the early 1950s. The group did their research on rockets from a launch site deep in the Mojave Desert. In the summer of 1956, 17-year-old Jimmy Blackmon of Charlotte, North Carolina, built a 6-foot rocket in his basement. The rocket was designed to be powere ...
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Space Shuttle Solid Rocket Booster
The Space Shuttle Solid Rocket Booster (SRB) was the first solid-propellant rocket to be used for primary propulsion on a vehicle used for human spaceflight. A pair of these provided 85% of the Space Shuttle's thrust at liftoff and for the first two minutes of ascent. After burnout, they were jettisoned and parachuted into the Atlantic Ocean where they were recovered, examined, refurbished, and reused. The Space Shuttle SRBs were the most powerful solid rocket motors to ever launch humans. The Space Launch System (SLS) SRBs, adapted from the shuttle, surpassed it as the most powerful solid rocket motors ever flown, after the launch of the Artemis-1 mission. Each Space Shuttle SRB provided a maximum thrust, roughly double the most powerful single-combustion chamber liquid-propellant rocket engine ever flown, the Rocketdyne F-1. With a combined mass of about , they comprised over half the mass of the Shuttle stack at liftoff. The motor segments of the SRBs were manufactured by ...
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Space Launch
Space launch is the earliest part of a flight that reaches space. Space launch involves liftoff, when a rocket or other space launch vehicle leaves the ground, floating ship or midair aircraft at the start of a flight. Liftoff is of two main types: rocket launch (the current conventional method), and non-rocket spacelaunch (where other forms of propulsion are employed, including airbreathing jet engines or other kinds). Issues with reaching space Definition of outer space Energy Therefore, by definition for spaceflight to occur, sufficient altitude is necessary. This implies a minimum gravitational potential energy needs to be overcome: for the Kármán line this is approximately 1 MJ/kg. W=mgh, m=1 kg, g=9.82 m/s2, h=105m. W=1*9.82*105≈106J/kg=1MJ/kg In practice, a higher energy than this is needed to be expended due to losses such as airdrag, propulsive efficiency, cycle efficiency of engines that are employed and gravity drag. In the past fifty years spacefl ...
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Solid-fuel Rocket
A solid-propellant rocket or solid rocket is a rocket with a rocket engine that uses solid propellants ( fuel/oxidizer). The earliest rockets were solid-fuel rockets powered by gunpowder; they were used in warfare by the Arabs, Chinese, Persians, Mongols, and Indians as early as the 13th century. All rockets used some form of solid or powdered propellant up until the 20th century, when liquid-propellant rockets offered more efficient and controllable alternatives. Solid rockets are still used today in military armaments worldwide, model rockets, solid rocket boosters and on larger applications for their simplicity and reliability. Since solid-fuel rockets can remain in storage for an extended period without much propellant degradation and because they almost always launch reliably, they have been frequently used in military applications such as missiles. The lower performance of solid propellants (as compared to liquids) does not favor their use as primary propulsion in mode ...
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Elastomer
An elastomer is a polymer with viscoelasticity (i.e. both viscosity and elasticity) and with weak intermolecular forces, generally low Young's modulus and high failure strain compared with other materials. The term, a portmanteau of ''elastic polymer'', is often used interchangeably with rubber, although the latter is preferred when referring to vulcanisates. Each of the monomers which link to form the polymer is usually a compound of several elements among carbon, hydrogen, oxygen and silicon. Elastomers are amorphous polymers maintained above their glass transition temperature, so that considerable molecular reconformation is feasible without breaking of covalent bonds. At ambient temperatures, such rubbers are thus relatively compliant ( E ≈ 3 M Pa) and deformable. Their primary uses are for seals, adhesives and molded flexible parts. Application areas for different types of rubber are manifold and cover segments as diverse as tires, soles for shoes, and damping and ...
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Pascal (unit)
The pascal (symbol: Pa) is the unit of pressure in the International System of Units (SI), and is also used to quantify internal pressure, stress, Young's modulus, and ultimate tensile strength. The unit, named after Blaise Pascal, is defined as one newton per square metre and is equivalent to 10 barye (Ba) in the CGS system. The unit of measurement called standard atmosphere (atm) is defined as 101,325 Pa. Common multiple units of the pascal are the hectopascal (1 hPa = 100 Pa), which is equal to one millibar, and the kilopascal (1 kPa = 1000 Pa), which is equal to one centibar. Meteorological observations typically report atmospheric pressure in hectopascals per the recommendation of the World Meteorological Organization, thus a standard atmosphere (atm) or typical sea-level air pressure is about 1013 hPa. Reports in the United States typically use inches of mercury or millibars (hectopascals). In Canada these reports are given in kilopascal ...
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Explosion
An explosion is a rapid expansion in volume associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Supersonic explosions created by high explosives are known as detonations and travel through shock waves. Subsonic explosions are created by low explosives through a slower combustion process known as deflagration. Causes Explosions can occur in nature due to a large influx of energy. Most natural explosions arise from volcanic or stellar processes of various sorts. Explosive volcanic eruptions occur when magma rises from below, it has very dissolved gas in it. The reduction of pressure as the magma rises and causes the gas to bubble out of solution, resulting in a rapid increase in volume. Explosions also occur as a result of impact events and in phenomena such as hydrothermal explosions (also due to volcanic processes). Explosions can also occur outside of Earth in the universe in events s ...
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Melting
Melting, or fusion, is a physical process that results in the phase transition of a substance from a solid to a liquid. This occurs when the internal energy of the solid increases, typically by the application of heat or pressure, which increases the substance's temperature to the melting point. At the melting point, the ordering of ions or molecules in the solid breaks down to a less ordered state, and the solid "melts" to become a liquid. Substances in the molten state generally have reduced viscosity as the temperature increases. An exception to this principle is the element sulfur, whose viscosity increases in the range of 160 °C to 180 °C due to polymerization. Some organic compounds melt through mesophases, states of partial order between solid and liquid. First order phase transition From a thermodynamics point of view, at the melting point the change in Gibbs free energy ''∆G'' of the substances is zero, but there are non-zero changes in the enthalpy ...
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Rhombohedron
In geometry, a rhombohedron (also called a rhombic hexahedron or, inaccurately, a rhomboid Traditionally, in two-dimensional geometry, a rhomboid is a parallelogram in which adjacent sides are of unequal lengths and angles are non-right angled. A parallelogram with sides of equal length (equilateral) is a rhombus but not a rhomboi ...) is a three-dimensional figure with six faces which are rhombus, rhombi. It is a special case of a parallelepiped where all edges are the same length. It can be used to define the rhombohedral lattice system, a Honeycomb (geometry), honeycomb with rhombohedral cells. A cube is a special case of a rhombohedron with all sides square. In general a ''rhombohedron'' can have up to three types of rhombic faces in congruent opposite pairs, ''C''''i'' symmetry, Order (group theory), order 2. Four points forming non-adjacent vertices of a rhombohedron necessarily form the four vertices of an orthocentric tetrahedron, and all orthocentric tetrahedra c ...
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Sodium Perchlorate
Sodium perchlorate is the inorganic compound with the chemical formula Na ClO4. It is a white crystalline, hygroscopic solid that is highly soluble in water and in alcohol. It is usually encountered as the monohydrate. The compound is noteworthy as the most water-soluble of the common perchlorate salts. Sodium perchlorate and other perchlorates has been found on the planet Mars, first detected by the NASA probe Phoenix in 2009. This was later confirmed by spectral analysis by the Mars Reconnaissance Orbiter in 2015 of what is thought to be brine seeps which may be the first evidence of flowing liquid water containing hydrated salts on Mars. Selected properties Its heat of formation is −382.75 kJ/mol, i.e. it is favorable for it to decompose into sodium chloride and dioxygen. It crystallizes in the rhombic crystal system. Uses Sodium perchlorate is the precursor to many other perchlorate salts, often taking advantage of their low solubility relative to NaClO4 (209 g/100 mL at ...
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