3-deoxyflavonoids
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3-deoxyflavonoids
The flavan-4-ols (3-deoxyflavonoids) are flavone-derived alcohols and a family of flavonoids. Flavan-4-ols are colorless precursor compounds that polymerize to form red phlobaphene pigments. They can be found in the sorghum. Glycosides (abacopterins A, B, C and D together with triphyllin A and 6,8-dimethyl-7-hydroxy-4‘-methoxyanthocyanidin-5-O-β-d-glucopyranoside) can be isolated from a methanol extract of the rhizomes of ''Abacopteris penangiana''. Known flavan-4-ols * Apiforol * Luteoforol Metabolism Flavanone 4-reductase is an enzyme that uses (2''S'')-flavan-4-ol and NADP+ to produce (2''S'')-flavanone The flavanones, a type of flavonoids, are various aromatic, colorless ketones derived from flavone that often occur in plants as glycosides. List of flavanones * Blumeatin * Butin * Eriodictyol * Hesperetin * Hesperidin * Homoeriodictyol * Iso ..., NADPH, and H+. Spectral data These compounds have absorption maxima of 564 nm. References {{flavan-4ol
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Phlobaphene
Phlobaphenes (or phlobaphens, CAS No.:71663-19-9) are reddish, alcohol-soluble and water-insoluble phenolic substances. They can be extracted from plants, or be the result from treatment of tannin extracts with mineral acids (tanner's red). The name ''phlobaphen'' come from the Greek and Latin roots in English, Greek roots φλoιὀς (''phloios'') meaning Bark (botany), bark and βαφή (''baphe'') meaning dye. No biological activities have currently been reported for phlobaphenes. Phlobaphenes from Crataegus, hawthorn fruits (''Fructus Crataegi'') may have a specific action on the coronary circulation. They are converted into humins in soils. Naturally formed phlobaphenes Natural phlobaphenes are the common Bark (botany), bark, pericarp, Corncob, cob glume and seed#Seed structure, seed coat (''testa'') plant pigment, pigments. They have not been found in flowers, unless the brown and black pigments in the involucrum of certain compositae are found to be of the phlobaphene typ ...
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Flavone
Flavone is an organic compound with the formula . A white solid, flavone is a derivative of chromone with a phenyl (Ph) substituent adjacent to the ether group. The compound is of little direct practical importance, but susbstituted derivatives, the flavones and flavonoids are a large class of nutritionally important natural products. Flavone can be prepared in the laboratory by cyclization of 2-hydroxacetophenone. Isomeric with flavone is isoflavone, where the phenyl group is adjacent to the ketone In organic chemistry, a ketone is a functional group with the structure R–C(=O)–R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group –C(=O)– (which contains a carbon-oxygen double bo .... References {{Flavones ...
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Alcohol (chemistry)
In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl () functional group bound to a saturated carbon atom. The term ''alcohol'' originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. An important class of alcohols, of which methanol and ethanol are the simplest examples, includes all compounds which conform to the general formula . Simple monoalcohols that are the subject of this article include primary (), secondary () and tertiary () alcohols. The suffix ''-ol'' appears in the IUPAC chemical name of all substances where the hydroxyl group is the functional group with the highest priority. When a higher priority group is present in the compound, the prefix ''hydroxy-'' is used in its IUPAC name. The suffix ''-ol'' in non-IUPAC names (such as paracetamol or cholesterol) also typically indicates that the substance is an alcohol. However, some compou ...
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Methanol
Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical and the simplest aliphatic alcohol, with the formula C H3 O H (a methyl group linked to a hydroxyl group, often abbreviated as MeOH). It is a light, volatile, colourless, flammable liquid with a distinctive alcoholic odour similar to that of ethanol (potable alcohol). A polar solvent, methanol acquired the name wood alcohol because it was once produced chiefly by the destructive distillation of wood. Today, methanol is mainly produced industrially by hydrogenation of carbon monoxide. Methanol consists of a methyl group linked to a polar hydroxyl group. With more than 20 million tons produced annually, it is used as a precursor to other commodity chemicals, including formaldehyde, acetic acid, methyl tert-butyl ether, methyl benzoate, anisole, peroxyacids, as well as a host of more specialised chemicals. Occurrence Small amounts of methanol are present in normal, healthy hu ...
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Abacopteris Penangiana
''Menisciopsis penangiana'' is a fern species in the genus '' Menisciopsis''. It has many synonyms, including ''Abacopteris penangiana'' and ''Pronephrium penangianum''. Flavan-4-ols glycosides, abacopterins A, B, C and D together with triphyllin A and 6,8-dimethyl-7-hydroxy-4‘-methoxyanthocyanidin-5-O-β-d-glucopyranoside, can be isolated from a methanol extract of the rhizomes of ''M. penangiana''.Flavan-4-ol Glycosides from the Rhizomes of ''Abacopteris penangiana''. Zhao Zhongxiang, Ruan Jinlan, Jin Jing, Zou Jian, Zhou Daonian, Fang Wei and Zeng Fanbo, J. Nat. Prod., 2006, 69 (2), pp 265–268 References External links * * Thelypteridaceae {{Polypodiales-stub ...
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Apiforol
Apiforol is a chemical compound belonging to the flavan-4ol class of flavonoids. Metabolism Flavanone 4-reductase is an enzyme transforming naringenin into apiforol. This enzyme can be found in ''Columnea hybrida'', in ''Malus domestica'', in ''Pyrus communis'', in '' Sinningia cardinalis'', and in ''Zea mays Maize ( ; ''Zea mays'' subsp. ''mays'', from es, maíz after tnq, mahiz), also known as corn (North American and Australian English), is a cereal grain first domesticated by indigenous peoples in southern Mexico about 10,000 years ago. Th ...''. References Flavan-4-ols Resorcinols {{phenol-stub ...
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