3-Methylcatechol
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3-Methylcatechol
3-Methylcatechol is a chemical compound, a methylbenzenediol. Metabolism The enzyme 1,2-dihydroxy-6-methylcyclohexa-3,5-dienecarboxylate dehydrogenase uses 1,2-dihydroxy-6-methylcyclohexa-3,5-dienecarboxylate and NAD+ to produce 3-methylcatechol, NADH and CO2. The isofunctional enzymes of catechol 1,2-dioxygenase from species of '' Acinetobacter'', '' Pseudomonas'', ''Nocardia'', '' Alcaligenes'' and ''Corynebacterium'' oxidize 3-methylcatechol according to both the intradiol and extradiol cleavage patterns. However, the enzyme preparations from '' Brevibacterium'' and ''Arthrobacter'' have only the intradiol cleavage activity.Extradiol Cleavage of 3-Methylcatechol by Catechol 1,2-Dioxygenase from Various Microorganisms. C. T. Hou, R. Patel and M. O. Lillard, Appl. Environ. Microbiol., March 1977, volume 33, issue 3, pages 725-727abstract Related compounds The 3-methylcatechol structural motif is rare in natural products. Known examples include calopin and a δ- lacton ...
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Methylbenzenediol
Methylbenzenediol, also known as dihydroxytoluene, may refer to: * 3-Methylcatechol (3-methylbenzene-1,2-diol or 2,3-dihydroxytoluene) * 4-Methylcatechol (4-methylbenzene-1,2-diol or 3,4-dihydroxytoluene) * 2-methylbenzene-1,3-diol * 4-methylbenzene-1,3-diol * Orcinol (5-methylbenzene-1,3-diol or 3,5-dihydroxytoluene) * 2-methylbenzene-1,4-diol * 3-methylbenzene-1,4-diol See also * Cresol (methylphenol, hydroxytoluene) * Trihydroxytoluene Dihydroxytoluene may refer to: * 2,3,4-trihydroxytoluene (caricaphenyl triol) of the papaya plant * 2,3,5-trihydroxytoluene, a product of orcinol catalysis See also * Hydroxytoluene * Dihydroxytoluene * Trinitrotoluene Trinitrotoluene (), ...
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Caloboletus Calopus
''Caloboletus calopus'', common name, commonly known as the bitter beech bolete or scarlet-stemmed bolete, is a fungus of the Boletaceae, bolete family, found in Asia, Northern Europe and North America. Appearing in coniferous forest, coniferous and deciduous forest, deciduous woodland in summer and autumn, the stout basidiocarp, fruit bodies are attractively coloured, with a beige to olive pileus (mycology), cap up to 15 cm (6 in) across, yellow pores, and a reddish stipe (mycology), stipe up to long and wide. The pale yellow trama (mycology), flesh stains blue when broken or bruised. Christiaan Hendrik Persoon, Christiaan Persoon first species description, described ''Boletus calopus'' in 1801. Modern molecular phylogenetics showed that it was only distantly related to the type species of ''Boletus'' and required placement in a new genus; ''Caloboletus'' was erected in 2014, with ''C. calopus'' designated as the type species. Although ''Caloboletus calopus'' ...
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1,2-dihydroxy-6-methylcyclohexa-3,5-dienecarboxylate
Onekama ( ) is a village in Manistee County in the U.S. state of Michigan. The population was 411 at the 2010 census. The village is located on the shores of Portage Lake and is surrounded by Onekama Township. The town's name is derived from "Ona-ga-maa," an Anishinaabe word which means "singing water." Geography According to the United States Census Bureau, the village has a total area of , all land. The M-22 highway runs through downtown Onekama. History The predecessor of the village of Onekama was the settlement of Portage at Portage Point, first established in 1845, at the western end of Portage, at the outlet of Portage Creek. In 1871, when landowners around the land-locked lake became exasperated with the practices of the Portage Sawmill, they took the solution into their own hands and dug a channel through the narrow isthmus, opening a waterway that lowered the lake by 12 to 14 feet and brought it to the same level as Lake Michigan. When this action dried out Port ...
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Brevibacterium
''Brevibacterium'' is a genus of bacteria of the order Micrococcales. They are Gram-positive soil Soil, also commonly referred to as earth or dirt, is a mixture of organic matter, minerals, gases, liquids, and organisms that together support life. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former te ... organisms. Species ''Brevibacterium'' comprises the following species: * '' B. album'' Tang et al. 2008 * '' B. ammoniilyticum'' Kim et al. 2013 * '' B. anseongense'' Jung et al. 2019 * '' B. antiquum'' Gavrish et al. 2005 * '' B. atlanticum'' Pei et al. 2022 * '' B. aurantiacum'' Gavrish et al. 2005 * "'' B. aureum''" Seghal Kiran et al. 2010 * '' B. avium'' Pascual and Collins 1999 * '' B. casei'' Collins et al. 1983 * '' B. celere'' Ivanova et al. 2004 * '' B. daeguense'' Cui et al. 2013 * '' B. epidermidis'' Collins et al. 1983 * '' B. hankyongi'' Choi et al. 2018 * "'' B. ihuae''" Valles et al. 2018 * '' B. iodin ...
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Lactone
Lactones are cyclic carboxylic esters, containing a 1-oxacycloalkan-2-one structure (), or analogues having unsaturation or heteroatoms replacing one or more carbon atoms of the ring. Lactones are formed by intramolecular esterification of the corresponding hydroxycarboxylic acids, which takes place spontaneously when the ring that is formed is five- or six-membered. Lactones with three- or four-membered rings (α-lactones and β-lactones) are very reactive, making their isolation difficult. Special methods are normally required for the laboratory synthesis of small-ring lactones as well as those that contain rings larger than six-membered. Nomenclature Lactones are usually named according to the precursor acid molecule (''aceto'' = 2 carbon atoms, ''propio'' = 3, ''butyro'' = 4, ''valero'' = 5, ''capro'' = 6, etc.), with a ''-lactone'' suffix and a Greek letter prefix that specifies the number of carbon atoms in the heterocycle — that is, the distance between the relevant -OH ...
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Natural Product
A natural product is a natural compound or substance produced by a living organism—that is, found in nature. In the broadest sense, natural products include any substance produced by life. Natural products can also be prepared by chemical synthesis (both semisynthesis and total synthesis) and have played a central role in the development of the field of organic chemistry by providing challenging synthetic targets. The term natural product has also been extended for commercial purposes to refer to cosmetics, dietary supplements, and foods produced from natural sources without added artificial ingredients. Within the field of organic chemistry, the definition of natural products is usually restricted to organic compounds isolated from natural sources that are produced by the pathways of primary or secondary metabolism. Within the field of medicinal chemistry, the definition is often further restricted to secondary metabolites. Secondary metabolites (or specialized metabolites ...
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Structural Motif
In a polymer, chain-like biological molecule, such as a protein or nucleic acid, a structural motif is a common Biomolecular structure#Tertiary structure, three-dimensional structure that appears in a variety of different, evolutionarily unrelated molecules. A structural motif does not have to be associated with a sequence motif; it can be represented by different and completely unrelated sequences in different proteins or RNA. In nucleic acids Depending upon the sequence and other conditions, nucleic acids can form a variety of structural motifs which is thought to have biological significance. ;Stem-loop: Stem-loop intramolecular base pairing is a pattern that can occur in single-stranded DNA or, more commonly, in RNA. The structure is also known as a hairpin or hairpin loop. It occurs when two regions of the same strand, usually complementary in nucleotide sequence when read in opposite directions, base-pair to form a double helix that ends in an unpaired loop. The re ...
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Arthrobacter
''Arthrobacter'' (from the Greek, "jointed small stick”) is a genus of bacteria that is commonly found in soil. All species in this genus are Gram-positive obligate aerobes that are rods during exponential growth and cocci in their stationary phase. ''Arthrobacter'' have a distinctive method of cell division called "snapping division" or reversion in which the outer bacterial cell wall ruptures at a joint. Description ''Arthrobacter'' can be grown on mineral salts pyridone broth, where colonies have a greenish metallic center on incubated at . Under the microscope, ''Arthrobacter'' appear as rods when rapidly dividing, and cocci when in stationary phase. Dividing cells may also appear as chevrons ("V" shapes). Other notable characteristics are that it can use pyridone as its sole carbon source, and that its cocci are resistant to desiccation and starvation. Use in industry ''Arthrobacter'', like other bacterial genera including ''Brevibacterium'', ''Microbacterium'', and '' ...
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Catechol 1,2-dioxygenase
Catechol 1,2- dioxygenase (, ''1,2-CTD'', ''catechol-oxygen 1,2-oxidoreductase'', ''1,2-pyrocatechase'', ''catechase'', ''catechol 1,2-oxygenase'', '' catechol dioxygenase'', ''pyrocatechase'', ''pyrocatechol 1,2-dioxygenase'', ''CD I'', ''CD II'') is an enzyme that catalyzes the oxidative ring cleavage of catechol to form ''cis,cis''-muconic acid: More specifically, 1,2-CTD is an intradiol dioxygenase, a family of catechol dioxygenases that cleaves the bond between the phenolic hydroxyl groups of catechol using an Fe3+ cofactor. Thus far, 1,2-CTD has been observed to exist in the following species of soil bacteria and fungi: '' Pseudomonas sp.'', ''Pseudomonas fluorescens'', '' Aspergillus niger'', ''Brevibacterium fuscum'', '' Acinetobacter calcoaceticus'', '' Trichosporon cutaneum'', '' Rhodococcus erythropolis'', ''Frateuria sp.'', ''Rhizobium trifolii'', '' Pseudomonas putida'', ''Candida tropicalis'', ''Candida maltose'', ''Rhizobium leguminosarum'', and '' Nocardia s ...
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