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2,3-trans-3,4-cis-leucocyanidin
Leucoanthocyanidin (flavan-3,4-diols) are colorless chemical compounds related to anthocyanidins and anthocyanins. Leucoanthocyanins can be found in ''Anadenanthera peregrina'' and in several species of ''Nepenthes'' including '' N. burbidgeae'', '' N. muluensis'', '' N. rajah'', '' N. tentaculata'', and '' N. × alisaputrana''. Such compounds include: * Leucocyanidin * Leucodelphinidin * Leucofisetinidin * Leucomalvidin * Leucopelargonidin * Leucopeonidin * Leucorobinetinidin * Melacacidin * Teracacidin from ''Acacia obtusifolia'' and ''Acacia maidenii'' heartwoods Leucoanthocyanidins have been demonstrated to be intermediates in anthocyanidin biosynthesis in flowers of ''Matthiola incana''. Bate-smith recommended in 1954 the use of the Forestal solvent for the isolation of leuco-anthocyanins. Metabolism Leucoanthocyanidin dioxygenase uses flavan-3,4-diols to produce 3-hydroxyanthocyanidins. The gene encoding the enzyme (PpLDOX) has been identifi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Flavan
The flavans are benzopyran derivatives that use the 2-phenyl-3,4-dihydro-2''H''-chromene skeleton. They may be found in plants. These compounds include the flavan-3-ols, flavan-4-ols and flavan-3,4-diols (leucoanthocyanidin). A ''C''-glycosidic flavan can be isolated from cocoa liquor. ''Casuarina glauca'' is an actinorhizal plant producing root nitrogen-fixing nodules infested by ''Frankia ''Frankia'' is a genus of nitrogen-fixing bacteria that live in symbiosis with actinorhizal plants, similar to the ''Rhizobium'' bacteria found in the root nodules of legumes in the family Fabaceae. ''Frankia'' also initiate the forming of root ...''. There is a regular pattern of cell layers containing flavans. References {{Aromatic-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Leucopeonidin
Leucopeonidin is a leucoanthocyanidin. A leucopeonidin glycoside is found in the bark of ''Ficus bengalensis ''Ficus benghalensis'', commonly known as the banyan, banyan fig and Indian banyan, is a tree native to the Indian Subcontinent. Specimens in India are among the largest trees in the world by canopy coverage. It also known as the " strangler fig" ...''. References Leucoanthocyanidins Phenol ethers Resorcinols {{phenol-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vitis Vinifera
''Vitis vinifera'', the common grape vine, is a species of flowering plant, native to the Mediterranean region, Central Europe, and southwestern Asia, from Morocco and Portugal north to southern Germany and east to northern Iran. There are currently between 5,000 and 10,000 varieties of ''Vitis vinifera'' grapes though only a few are of commercial significance for wine and table grape production. The wild grape is often classified as ''Vitis vinifera'' ''sylvestris'' (in some classifications considered ''Vitis sylvestris''), with ''Vitis vinifera'' ''vinifera'' restricted to cultivated forms. Domesticated vines have hermaphrodite flowers, but ''sylvestris'' is dioecious (male and female flowers on separate plants) and pollination is required for fruit to develop. Grapes can be eaten fresh or dried to produce raisins, sultanas, and currants. Grape leaves are used in the cuisine of many cultures. The fresh grapes can also be processed into juice that is fermented to make wine ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Peach
The peach (''Prunus persica'') is a deciduous tree first domesticated and cultivated in Zhejiang province of Eastern China. It bears edible juicy fruits with various characteristics, most called peaches and others (the glossy-skinned, non-fuzzy varieties), nectarines. The specific name ''persica'' refers to its widespread cultivation in Persia (modern-day Iran), from where it was transplanted to Europe. It belongs to the genus ''Prunus'', which includes the cherry, apricot, almond, and plum, in the rose family. The peach is classified with the almond in the subgenus '' Amygdalus'', distinguished from the other subgenera by the corrugated seed shell (endocarp). Due to their close relatedness, the kernel of a peach stone tastes remarkably similar to almond, and peach stones are often used to make a cheap version of marzipan, known as persipan. Peaches and nectarines are the same species, though they are regarded commercially as different fruits. The skin of nectarines lac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
3-hydroxyanthocyanidins
Anthocyanidins are common plant pigments, the sugar-free counterparts of anthocyanins. They are based on the flavylium cation, an oxonium ion, with various groups substituent, substituted for its hydrogen atoms. They generally change color from red through purple, blue, and bluish green as a function of pH. Anthocyanidins are an important subclass of the polymethine dyes and flavonoids. The flavylium cation is a chromenylium cation with a phenyl group substituted in position 2; and chromenylium (also called benzopyrylium) is a bicyclic version of pyrylium. The positive charge can move around the molecule. At least 31 monomeric anthocyanidins have been properly identified in living organisms, mostly as the core components of anthocyanins. The latter are responsible for the red, purple, blue, or black color of many fruits (like grapes and blueberry, blueberries), flowers (like roses), leaves (like purple cabbage), and even tubers (like radishes and purple yams). They are also ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Leucoanthocyanidin Dioxygenase
In enzymology, a leucocyanidin oxygenase () is an enzyme that catalyzes the chemical reaction :leucocyanidin + 2-oxoglutarate + O2 \rightleftharpoons cis- and trans-dihydroquercetins + succinate + CO2 + 2 H2O The 3 substrates of this enzyme are leucocyanidin, 2-oxoglutarate, and O2, whereas its 5 products are cis-dihydroquercetin, trans-dihydroquercetin, succinate, CO2, and H2O. This enzyme belongs to the family of oxidoreductases, specifically those acting on paired donors, with O2 as oxidant and incorporation or reduction of oxygen. The oxygen incorporated need not be derived from O2 with 2-oxoglutarate as one donor, and incorporation of one atom o oxygen into each donor. The systematic name of this enzyme class is leucocyanidin,2-oxoglutarate:oxygen oxidoreductase. This enzyme is also called leucoanthocyanidin dioxygenase (LDOX) or anthocyanidin synthase (ANS). This enzyme participates in flavonoid biosynthesis. In a broader way, leucocyanidin oxygenase uses flavan- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Forestal
Forestal is a solvent used in chromatography, composed of acetic acid, water, and hydrochloric acid Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid Acid strength is the tendency of an acid, symbol ... in a 30:10:3 ratio by volume. It is useful for isolating anthocyanins in room-temperature chromatography using standard filter paper. References * * Pecket, R.C. Constituents of Leaf Extracts ... , New Phytologist 1959 Oct; 58(2) (retrieved 27 sept 2010 http://onlinelibrary.wiley.com/doi/10.1111/j.1469-8137.1959.tb05350.x/pdf ) * Stecher, G. and Bonn, G. K., Phytochemical Analysis, Chromatography, Elsevier Science, E. Heftmann (ed), Amsterdam, pp. 1050. {{ISBN, 0-444-51108-3 (2004) (retrieved via google books 9/27/2010) Solvents Chromatography Anthocyanins ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Edgar Charles Bate-Smith
Edgar Charles Bate-Smith (1900-1989Practical Polyphenolics, Edwin Haslam, 1998, ) was an English chemist and phytochemist specialising in food chemistry. He worked in the Low Temperature Research Station in Cambridge where his main fields of research were meat and polyphenols. The discovery in 1943 by Martin and Synge of paper chromatography provided for the first time the means of surveying the phenolic constituents of plants and for their separation and identification. There was an explosion of activity in this field after 1945, none more so than that of Bate-Smith and Tony Swain (chemist), Tony Swain. In 1951, Bate-Smith developed and first described a coloration method to detect the presence of condensed tannins (also called proanthocyanidins) in plant materials. This reaction is based on heating in acidic conditions and gives rise to anthocyanidin pigments. Bate-smith recommended the use of the Forestal solvent for the isolation of leuco-anthocyanins in 1954. In 1973, he ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Matthiola Incana
''Matthiola incana'' is a species of flowering plant in the cabbage family Brassicaceae. Common names include Brompton stock, common stock, hoary stock, ten-week stock, and gilly-flower. The common name stock usually refers to this species, though it may also be applied to the whole genus ''Matthiola''. The common name "night-scented stock" or "evening-scented stock" is applied to ''Matthiola longipetala''. ''Matthiola incana'' is a common garden flower, available in a variety of colours, many of which are heavily scented and also used in floristry. Description Some stocks are grown as annuals (the "ten-week stocks") that reach heights of growth of 20 to 28 centimeters thick, woody at the base and with numerous foliar scars and branches with terminal rosettes of leaves. The plants are starry, with whitish hairs. The leaves are rounded and ash-coloured. The fragrant flowers are white, cream yellow, pink, red, purple or blue. The scar flaps on the back are swollen. The pods are ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acacia Maidenii
''Acacia maidenii'', also known as Maiden's wattle, is a tree native to Australia (New South Wales, Queensland and Victoria). It has been introduced into India, (Tamil Nadu) and Argentina, and it grows on plantations in South Africa. Description and habitat It prefers full sun to partial shade and it is often found on the edge of the rainforest. It grows up to 20 m height in an erect or spreading habit. The phyllodes are dark green, alternate along the stem and reach 20 cm in length and 1 to 3 cm in width. It is very fast growing, reaching 1.5 m tall in as little as five months. Its flowers have pale yellow spikes up to 6 cm long that often occur in clusters of two to three. The fruit is hairy, about 15 cm long and narrow, often becoming coiled. In the Australian state of Victoria it is listed as being an endangered species, however it is a common species through much of the rest of its range. The tree has a lifespan of more than 30 years. It grow ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acacia Obtusifolia
''Acacia obtusifolia'', commonly known as stiff-leaf wattle or blunt-leaf wattle, is a perennial tree in subfamily Mimosoideae of family Fabaceae. Description ''Acacia obtusifolia'' is an upright or spreading perennial tree which grows from 1.5m to 8m in height and it is native to Australia. It is closely related to '' Acacia longifolia''. ''Acacia obtusifolia'' can be distinguished by it having phyllode margins which are resinous, it usually blooms later in the year and it has paler flowers than ''Acacia longifolia.'' It flowers usually from December through February. Some populations of ''Acacia obtusifolia'' can survive winters to −6 °C and possibly a light snow, however plants from populations in areas that are frost free such as the coastal ranges of Northern NSW are susceptible to cold and will be killed by frosts lower than −3 °C. These populations avoid the valley floors and occur mainly on sandstone ridges well above the frost line. Phytochemicals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
